Simultaneous Modulation of Magnetic and Dielectric Transition via Spin‐Crossover‐Tuned Spin Arrangement and Charge Distribution
Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII(CN)3]− (Tp=hydrotris(pyra...
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| Published in | Angewandte Chemie International Edition Vol. 57; no. 28; pp. 8468 - 8472 |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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Wiley Subscription Services, Inc
09.07.2018
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| Edition | International ed. in English |
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| Abstract | Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII(CN)3]− (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin‐crossover (SCO) on FeII sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the FeII ions and antiferromagnetic interactions between FeIII and FeII ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)FeIII(CN)3]− units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution.
Magnetic interactions: A spin‐crossover‐actuated magnetic and dielectric transition has been observed. The sensitive response to hydrostatic pressure and large dielectric anomaly could be attributed to a cooperative effect and rotation of the negative charged building block. |
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| AbstractList | Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII (CN)3 ]- (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin-crossover (SCO) on FeII sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the FeII ions and antiferromagnetic interactions between FeIII and FeII ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)FeIII (CN)3 ]- units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution.Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII (CN)3 ]- (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin-crossover (SCO) on FeII sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the FeII ions and antiferromagnetic interactions between FeIII and FeII ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)FeIII (CN)3 ]- units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution. Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII(CN)3]− (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin‐crossover (SCO) on FeII sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the FeII ions and antiferromagnetic interactions between FeIII and FeII ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)FeIII(CN)3]− units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution. Magnetic interactions: A spin‐crossover‐actuated magnetic and dielectric transition has been observed. The sensitive response to hydrostatic pressure and large dielectric anomaly could be attributed to a cooperative effect and rotation of the negative charged building block. Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged Fe ions were linked via negative charged [(Tp)Fe (CN) ] (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin-crossover (SCO) on Fe sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the Fe ions and antiferromagnetic interactions between Fe and Fe ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)Fe (CN) ] units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution. Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged FeII ions were linked via negative charged [(Tp)FeIII(CN)3]− (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin‐crossover (SCO) on FeII sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the FeII ions and antiferromagnetic interactions between FeIII and FeII ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)FeIII(CN)3]− units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution. Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the magnetic state via capacitive measurement. Herein, positive charged Fe II ions were linked via negative charged [(Tp)Fe III (CN) 3 ] − (Tp=hydrotris(pyrazolyl)borate) units to form a neutral chain. The spin‐crossover (SCO) on Fe II sites could be sensitively triggered via thermal treatment, light irradiation, and pressure. SCO switched the spin state of the Fe II ions and antiferromagnetic interactions between Fe III and Fe II ions, resulting in significant change in magnetization. Moreover, SCO induced rotation of negative charged [(Tp)Fe III (CN) 3 ] − units, generating dielectric anomaly due to geometric change of charges distribution. This work provides a rational way to manipulate simultaneous variations in magnetic and dielectric properties utilizing SCO as an actuator to tune spin arrangement, magnetic coupling, and charge distribution. |
| Author | Duan, Chun‐Ying Sato, Osamu Hayami, Shinya Zheng, Hui Meng, Yin‐Shan Luo, Yi Zhou, Guang‐Li Liu, Tao |
| Author_xml | – sequence: 1 givenname: Hui surname: Zheng fullname: Zheng, Hui organization: Dalian University of Technology – sequence: 2 givenname: Yin‐Shan surname: Meng fullname: Meng, Yin‐Shan organization: Dalian University of Technology – sequence: 3 givenname: Guang‐Li surname: Zhou fullname: Zhou, Guang‐Li organization: Dalian University of Technology – sequence: 4 givenname: Chun‐Ying surname: Duan fullname: Duan, Chun‐Ying organization: Dalian University of Technology – sequence: 5 givenname: Osamu surname: Sato fullname: Sato, Osamu organization: Kyushu University – sequence: 6 givenname: Shinya surname: Hayami fullname: Hayami, Shinya organization: Kumamoto University – sequence: 7 givenname: Yi surname: Luo fullname: Luo, Yi organization: Dalian University of Technology – sequence: 8 givenname: Tao orcidid: 0000-0003-2891-603X surname: Liu fullname: Liu, Tao email: liutao@dlut.edu.cn organization: Dalian University of Technology |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29770545$$D View this record in MEDLINE/PubMed |
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| Copyright | 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | iron magnetic interactions multifuntional materials coordination chemistry spin-crossover complexes |
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| Snippet | Magnetic and dielectric properties have been tuned simultaneously by external stimuli with rapid and sensitive response, which is crucial to monitor the... |
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| SubjectTerms | Antiferromagnetism Charge distribution coordination chemistry Dielectric properties Electrical properties External stimuli Heat treatment Ions iron Irradiation Light irradiation magnetic interactions Magnetic properties multifuntional materials Radiation spin-crossover complexes |
| Title | Simultaneous Modulation of Magnetic and Dielectric Transition via Spin‐Crossover‐Tuned Spin Arrangement and Charge Distribution |
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