Azulene in Polymers and Their Properties
Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5‐membered ring fused with a positively charged 7‐membered ring. In particular, incorporation of azulene into polymers has led to m...
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| Published in | Chemistry, an Asian journal Vol. 15; no. 13; pp. 1904 - 1915 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Germany
Wiley Subscription Services, Inc
01.07.2020
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| Abstract | Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5‐membered ring fused with a positively charged 7‐membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This minireview covers functionalization methods of azulene at its various positions of 5‐ and 7‐membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene‐containing polymers including poly(1,3‐azulene), azulene‐based copolymers with connectivity at 1,3‐positions of the 5‐membered ring, or 4,7‐positions of the 7‐membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene‐containing polymers have also been summarized.
This minireview summarizes the latest development of a range of azulene‐containing polymers, highlighting 1,3‐connected polyazulene, 1,3‐connected, 4,7‐connected and 2,6‐connected azulene‐containing copolymers with a special emphasis on the polymer synthesis as well as their electrical and optical properties. |
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| AbstractList | Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5-membered ring fused with a positively charged 7-membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This minireview covers functionalization methods of azulene at its various positions of 5- and 7-membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene-containing polymers including poly(1,3-azulene), azulene-based copolymers with connectivity at 1,3-positions of the 5-membered ring, or 4,7-positions of the 7-membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene-containing polymers have also been summarized.Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5-membered ring fused with a positively charged 7-membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This minireview covers functionalization methods of azulene at its various positions of 5- and 7-membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene-containing polymers including poly(1,3-azulene), azulene-based copolymers with connectivity at 1,3-positions of the 5-membered ring, or 4,7-positions of the 7-membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene-containing polymers have also been summarized. Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5‐membered ring fused with a positively charged 7‐membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This minireview covers functionalization methods of azulene at its various positions of 5‐ and 7‐membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene‐containing polymers including poly(1,3‐azulene), azulene‐based copolymers with connectivity at 1,3‐positions of the 5‐membered ring, or 4,7‐positions of the 7‐membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene‐containing polymers have also been summarized. Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a negatively charged 5‐membered ring fused with a positively charged 7‐membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This minireview covers functionalization methods of azulene at its various positions of 5‐ and 7‐membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene‐containing polymers including poly(1,3‐azulene), azulene‐based copolymers with connectivity at 1,3‐positions of the 5‐membered ring, or 4,7‐positions of the 7‐membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene‐containing polymers have also been summarized. This minireview summarizes the latest development of a range of azulene‐containing polymers, highlighting 1,3‐connected polyazulene, 1,3‐connected, 4,7‐connected and 2,6‐connected azulene‐containing copolymers with a special emphasis on the polymer synthesis as well as their electrical and optical properties. Azulene, a unique isomer of naphthalene, has received much interest of researchers from different fields due to its unusual chemical structure with negatively charged 5-membered ring fused with positively charged 7-membered ring. In particular, incorporation of azulene into polymers has led to many interesting properties. This mini-review covers functionalization methods of azulene at its various positions of 5- and 7-membered rings to form azulene derivatives including azulene monomers, and gives an overview of a wide range of azulene-containing polymers including poly(1,3-azulene), azulene-based copolymers with connectivity at 1,3-positions of the 5-membered ring, or 4,7-positions of the 7-membered ring, as well as copolymers with azulene units as side chains. Their chemical and physical properties together with applications of azulene-containing polymers have also been summarized. |
| Author | Xu, Jianwei Png, Zhuang Mao Zeng, Hui Ning |
| Author_xml | – sequence: 1 givenname: Hui Ning surname: Zeng fullname: Zeng, Hui Ning organization: The Agency for Science, Technology and Research (ASTAR) – sequence: 2 givenname: Zhuang Mao surname: Png fullname: Png, Zhuang Mao organization: The Agency for Science, Technology and Research (ASTAR) – sequence: 3 givenname: Jianwei orcidid: 0000-0003-3945-5443 surname: Xu fullname: Xu, Jianwei email: jw-xu@imre.a-star.edu.sg organization: National University of Singapore |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32333717$$D View this record in MEDLINE/PubMed |
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| Snippet | Azulene, a unique isomer of naphthalene, has received much interest from researchers in different fields due to its unusual chemical structure with a... Azulene, a unique isomer of naphthalene, has received much interest of researchers from different fields due to its unusual chemical structure with negatively... |
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| StartPage | 1904 |
| SubjectTerms | Azulene Chemistry Copolymers Functionalization Naphthalene Physical properties Polymers Properties Synthesis |
| Title | Azulene in Polymers and Their Properties |
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