Motional Dynamics of Halogen‐Bonded Complexes Probed by Low‐Field NMR Relaxometry and Overhauser Dynamic Nuclear Polarization

• Published in: Chemistry, an Asian journal Vol. 14; no. 16; pp. 2785 - 2789
• Main Authors: Banerjee, Abhishek, Dey, Arnab, Chandrakumar, N.
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 16.08.2019
• Subjects: Chemistry; Halogen bonds; Low-field relaxometry; Motional dynamics; NMR; NMR spectroscopy; Nuclear magnetic resonance; Organic chemistry; Overhauser DNP; Polarization; Substrates; Halogen bonds; Low-field relaxometry; Overhauser DNP; Motional dynamics; NMR spectroscopy

Halogen bonding is a subject of considerable interest owing to wide‐ranging chemical, materials and biological applications. The motional dynamics of halogen‐bonded complexes play a pivotal role in comprehending the nature of the halogen‐bonding interaction. However, not many attempts appear to have...