Aquivion Perfluorosulfonic Superacid as an Efficient Pickering Interfacial Catalyst for the Hydrolysis of Triglycerides

Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid‐catalyzed transesterificati...

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Published inChemSusChem Vol. 10; no. 17; pp. 3363 - 3367
Main Authors Shi, Hui, Fan, Zhaoyu, Hong, Bing, Pera‐Titus, Marc
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 11.09.2017
Subjects
Alkylation
Catalysis
Catalysts
Chemical reactions
Emulsions
fatty acids
Hydrolysis
interfacial catalysis
Lauric acid
Models, Molecular
Molecular Conformation
Pickering emulsions
Pressure
Sulfonic Acids - chemistry
Surface properties
Transesterification
Triglycerides
Triglycerides - chemistry
Pickering emulsions
triglycerides
fatty acids
interfacial catalysis
hydrolysis
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Abstract Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid‐catalyzed transesterification, ester hydrolysis, acetalization, etherification, and alkylation reactions. PIC has now been applied to the efficient, solvent‐free hydrolysis of the triglyceride glyceryl trilaurate to lauric acid, catalyzed by Aquivion perfluorosulfonic superacid at mild conditions (100 °C and ambient pressure). Superacid, super catalyst: Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions, a phenomenomenon through which Aquivion perfluorosulfonic superacid catalyzes the efficient, solvent‐free hydrolysis of glyceryl trilaurate at 100 °C and ambient pressure.
AbstractList Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid-catalyzed transesterification, ester hydrolysis, acetalization, etherification, and alkylation reactions. PIC has now been applied to the efficient, solvent-free hydrolysis of the triglyceride glyceryl trilaurate to lauric acid, catalyzed by Aquivion perfluorosulfonic superacid at mild conditions (100 °C and ambient pressure).
Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid-catalyzed transesterification, ester hydrolysis, acetalization, etherification, and alkylation reactions. PIC has now been applied to the efficient, solvent-free hydrolysis of the triglyceride glyceryl trilaurate to lauric acid, catalyzed by Aquivion perfluorosulfonic superacid at mild conditions (100°C and ambient pressure).
Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid‐catalyzed transesterification, ester hydrolysis, acetalization, etherification, and alkylation reactions. PIC has now been applied to the efficient, solvent‐free hydrolysis of the triglyceride glyceryl trilaurate to lauric acid, catalyzed by Aquivion perfluorosulfonic superacid at mild conditions (100 °C and ambient pressure). Superacid, super catalyst: Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions, a phenomenomenon through which Aquivion perfluorosulfonic superacid catalyzes the efficient, solvent‐free hydrolysis of glyceryl trilaurate at 100 °C and ambient pressure.
Abstract Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of Pickering emulsions. This concept, termed Pickering interfacial catalysis (PIC), has shown promising credentials in acid‐catalyzed transesterification, ester hydrolysis, acetalization, etherification, and alkylation reactions. PIC has now been applied to the efficient, solvent‐free hydrolysis of the triglyceride glyceryl trilaurate to lauric acid, catalyzed by Aquivion perfluorosulfonic superacid at mild conditions (100 °C and ambient pressure).
Author Hong, Bing
Fan, Zhaoyu
Shi, Hui
Pera‐Titus, Marc
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Issue 17
Keywords Pickering emulsions
triglycerides
fatty acids
interfacial catalysis
hydrolysis
Language English
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Snippet Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation of...
Abstract Rational design of the surface properties of heterogeneous catalysts can boost the interfacial activity in biphasic reactions through the generation...
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SubjectTerms Alkylation
Catalysis
Catalysts
Chemical reactions
Emulsions
fatty acids
Hydrolysis
interfacial catalysis
Lauric acid
Models, Molecular
Molecular Conformation
Pickering emulsions
Pressure
Sulfonic Acids - chemistry
Surface properties
Transesterification
Triglycerides
Triglycerides - chemistry
Title Aquivion Perfluorosulfonic Superacid as an Efficient Pickering Interfacial Catalyst for the Hydrolysis of Triglycerides
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fcssc.201700663
https://www.ncbi.nlm.nih.gov/pubmed/28742246
https://www.proquest.com/docview/1937326237
https://search.proquest.com/docview/1923106160
Volume 10
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