Confined Heteropoly Blues in Defected Zr‐MOF (Bottle Around Ship) for High‐Efficiency Oxidative Desulfurization

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 16; no. 14; pp. e1906432 - n/a
• Main Authors: Chang, Xue, Yang, Xian‐Feng, Qiao, Yang, Wang, Shuo, Zhang, Ming‐Hui, Xu, Jun, Wang, Dan‐Hong, Bu, Xian‐He
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.04.2020
• Subjects: bottle around ship; Catalysts; Catalytic activity; Composite materials; Confining; defected Zr‐MOF; Desulfurizing; Electron microscopes; Fourier transforms; imidazolium phosphomolybdate blues; Infrared analysis; Metal-organic frameworks; Nanotechnology; NMR; Nuclear magnetic resonance; oxidative desulfurization; Performance enhancement; phosphomolybdate blues; Photoelectrons; Polyoxometallates; Spectrum analysis; Thermogravimetric analysis; Thioureas; Zirconium; phosphomolybdate blues; imidazolium phosphomolybdate blues; defected Zr-MOF; bottle around ship; oxidative desulfurization

The Keggin‐type polyoxometalates (POMs) are effective catalysts for oxidative desulfurization (ODS) and confining these POMs in metal–organic frameworks (MOFs) is a promising strategy to improve their performances. Herein, postsynthetic modification of POMs confined in MOFs by adding thiourea create...