Cyclodextrin Films with Fast Solvent Transport and Shape‐Selective Permeability
This study describes the molecular‐level design of a new type of filtration membrane made of crosslinked cyclodextrins—inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer t...
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Published in | Advanced materials (Weinheim) Vol. 29; no. 26 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Germany
Wiley Subscription Services, Inc
01.07.2017
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Abstract | This study describes the molecular‐level design of a new type of filtration membrane made of crosslinked cyclodextrins—inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape‐sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester‐crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents.
A filtration membrane made of crosslinked cyclodextrins is reported. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape‐sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester‐crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents. |
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AbstractList | This study describes the molecular‐level design of a new type of filtration membrane made of crosslinked cyclodextrins—inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape‐sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester‐crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents. This study describes the molecular‐level design of a new type of filtration membrane made of crosslinked cyclodextrins—inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape‐sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester‐crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents. A filtration membrane made of crosslinked cyclodextrins is reported. The channel‐like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape‐sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester‐crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents. This study describes the molecular-level design of a new type of filtration membrane made of crosslinked cyclodextrins-inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel-like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape-sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester-crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents.This study describes the molecular-level design of a new type of filtration membrane made of crosslinked cyclodextrins-inexpensive macrocycles of glucose, shaped like hollow truncated cones. The channel-like cavities of cyclodextrins spawn numerous paths of defined aperture in the separation layer that can effectively discriminate between molecules. The transport of molecules through these membranes is highly shape-sensitive. In addition, the presence of hydrophobic (cavity) and hydrophilic (ester-crosslinked outer part) domains in these films results in high permeances for both polar and nonpolar solvents. |
Author | Villalobos, Luis Francisco Huang, Tiefan Peinemann, Klaus‐Viktor |
Author_xml | – sequence: 1 givenname: Luis Francisco orcidid: 0000-0002-0745-4246 surname: Villalobos fullname: Villalobos, Luis Francisco organization: Advanced Membranes and Porous Materials Center – sequence: 2 givenname: Tiefan surname: Huang fullname: Huang, Tiefan organization: Advanced Membranes and Porous Materials Center – sequence: 3 givenname: Klaus‐Viktor surname: Peinemann fullname: Peinemann, Klaus‐Viktor email: klausviktor.peinemann@kaust.edu.sa organization: Advanced Membranes and Porous Materials Center |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/28437014$$D View this record in MEDLINE/PubMed |
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Snippet | This study describes the molecular‐level design of a new type of filtration membrane made of crosslinked cyclodextrins—inexpensive macrocycles of glucose,... This study describes the molecular-level design of a new type of filtration membrane made of crosslinked cyclodextrins-inexpensive macrocycles of glucose,... This study describes the molecular-level design of a new type of filtration membrane made of crosslinked cyclodextrins--inexpensive macrocycles of glucose,... |
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SubjectTerms | Cones Crosslinking Cyclodextrins Filtration Glucose Holes interfacial polymerization Materials science Membranes nanofiltration Permeability Separation Solvents Transport |
Title | Cyclodextrin Films with Fast Solvent Transport and Shape‐Selective Permeability |
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