Lanthanide(III) (Eu, Gd, Tb, Dy) Complexes Derived from 4‐(Pyridin‐2‐yl)methyleneamino‐1,2,4‐triazole: Crystal Structure, Magnetic Properties, and Photoluminescence

• Published in: Chemistry, an Asian journal Vol. 13; no. 16; pp. 2060 - 2068
• Main Authors: Bazhina, Evgeniya S., Bovkunova, Anna A., Medved'ko, Alexey V., Varaksina, Evgeniya A., Taidakov, Ilya V., Efimov, Nikolay N., Kiskin, Mikhail A., Eremenko, Igor L.
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 16.08.2018
• Subjects: Antifungal agents; Chemistry; Coordination compounds; Crystal structure; Dysprosium; Gadolinium; lanthanides; luminescence; Magnetic measurement; Magnetic properties; Optical properties; Photoluminescence; triazoles; X-ray diffraction; X-ray diffraction; triazoles; luminescence; magnetic properties; lanthanides

The reaction of lanthanide(III) nitrates with 4‐(pyridin‐2‐yl)methyleneamino‐1,2,4‐triazole (L) was studied. The compounds [Ln(NO3)3(H2O)3]⋅2 L, in which Ln=Eu (1), Gd (2), Tb (3), or Dy (4), obtained in a mixture of MeCN/EtOH have the same structure, as shown by XRD. In the crystals of these compou...