Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2
[Display omitted] •3D porous graphene with high loading (6.9 wt%) of single atom Ni was produced.•High performance in electrochemical CO2 reduction was achieved.•Single atom and nanopores revealed by electron microscopy and X ray absorption.•DFT Simulation reveals the mechanism and confirms role of...
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| Published in | Applied catalysis. B, Environmental Vol. 243; pp. 294 - 303 |
|---|---|
| Main Authors | , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.04.2019
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0926-3373 1873-3883 |
| DOI | 10.1016/j.apcatb.2018.10.046 |
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| Abstract | [Display omitted]
•3D porous graphene with high loading (6.9 wt%) of single atom Ni was produced.•High performance in electrochemical CO2 reduction was achieved.•Single atom and nanopores revealed by electron microscopy and X ray absorption.•DFT Simulation reveals the mechanism and confirms role of edge anchored single atoms.
Supported single atom catalysts (SACs), emerging as a new class of catalytic materials, have been attracting increasing interests. Here we developed a Ni SAC on microwave exfoliated graphene oxide (Ni-N-MEGO) to achieve single atom loading of ∼6.9 wt%, significantly higher than previously reported SACs. The atomically dispersed Ni atoms, stabilized by coordination with nitrogen, were found to be predominantly anchored along the edges of nanopores ( < 6 nm) using a combination of X-ray absorption spectroscopy (XAS) and aberration-corrected scanning transmission electron microscopy (AC-STEM). The Ni-N-MEGO exhibits an onset overpotential of 0.18 V, and a current density of 53.6 mA mg−1 at overpotential of 0.59 V for CO2 reduction reaction (CO2RR), representing one of the best non-precious metal SACs reported so far in the literature. Density functional theory (DFT) calculations suggest that the electrochemical CO2-to-CO conversion occurs more readily on the edge-anchored unsaturated nitrogen coordinated Ni single atoms that lead to enhanced activity toward CO2RR. |
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| AbstractList | [Display omitted]
•3D porous graphene with high loading (6.9 wt%) of single atom Ni was produced.•High performance in electrochemical CO2 reduction was achieved.•Single atom and nanopores revealed by electron microscopy and X ray absorption.•DFT Simulation reveals the mechanism and confirms role of edge anchored single atoms.
Supported single atom catalysts (SACs), emerging as a new class of catalytic materials, have been attracting increasing interests. Here we developed a Ni SAC on microwave exfoliated graphene oxide (Ni-N-MEGO) to achieve single atom loading of ∼6.9 wt%, significantly higher than previously reported SACs. The atomically dispersed Ni atoms, stabilized by coordination with nitrogen, were found to be predominantly anchored along the edges of nanopores ( < 6 nm) using a combination of X-ray absorption spectroscopy (XAS) and aberration-corrected scanning transmission electron microscopy (AC-STEM). The Ni-N-MEGO exhibits an onset overpotential of 0.18 V, and a current density of 53.6 mA mg−1 at overpotential of 0.59 V for CO2 reduction reaction (CO2RR), representing one of the best non-precious metal SACs reported so far in the literature. Density functional theory (DFT) calculations suggest that the electrochemical CO2-to-CO conversion occurs more readily on the edge-anchored unsaturated nitrogen coordinated Ni single atoms that lead to enhanced activity toward CO2RR. |
| Author | Pan, Jian Chisholm, Mattew F. Li, Haobo Chen, Jingguang G. Jiang, San Ping Veder, Jean-Pierre Cheng, Yi Johannessen, Bernt Yang, Shi-Ze Zhao, Shiyong He, Shuai Lu, Shanfu Xiao, Jianping Liu, Chang |
| Author_xml | – sequence: 1 givenname: Yi surname: Cheng fullname: Cheng, Yi organization: Department of Environmental Engineering, School of Metallurgy and Environment, Central South University, Changsha, 410083, China – sequence: 2 givenname: Shiyong surname: Zhao fullname: Zhao, Shiyong organization: Fuels and Energy Technology Institute & Western Australia School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia – sequence: 3 givenname: Haobo surname: Li fullname: Li, Haobo organization: Institute of Natural Science, Westlake Institute for Advanced Study, Westlake University, Hangzhou 310024, Peoples Republic of China – sequence: 4 givenname: Shuai surname: He fullname: He, Shuai organization: Fuels and Energy Technology Institute & Western Australia School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia – sequence: 5 givenname: Jean-Pierre surname: Veder fullname: Veder, Jean-Pierre organization: John de Laeter Centre, Curtin University, Perth, WA 6102, Australia – sequence: 6 givenname: Bernt surname: Johannessen fullname: Johannessen, Bernt organization: Australian Synchrotron, Clayton, VIC 3168, Australia – sequence: 7 givenname: Jianping surname: Xiao fullname: Xiao, Jianping organization: Institute of Natural Science, Westlake Institute for Advanced Study, Westlake University, Hangzhou 310024, Peoples Republic of China – sequence: 8 givenname: Shanfu orcidid: 0000-0001-9873-6654 surname: Lu fullname: Lu, Shanfu organization: Beijing Key Laboratory of Bio-inspired Energy Materials and Devices,School of Space and Environment, Beihang University, Beijing, China – sequence: 9 givenname: Jian surname: Pan fullname: Pan, Jian organization: Fuels and Energy Technology Institute & Western Australia School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia – sequence: 10 givenname: Mattew F. surname: Chisholm fullname: Chisholm, Mattew F. organization: Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, United States – sequence: 11 givenname: Shi-Ze orcidid: 0000-0002-0421-006X surname: Yang fullname: Yang, Shi-Ze email: shize@bnl.gov organization: Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, United States – sequence: 12 givenname: Chang surname: Liu fullname: Liu, Chang email: cliu@imr.ac.cn organization: Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning 110016, China – sequence: 13 givenname: Jingguang G. surname: Chen fullname: Chen, Jingguang G. organization: Department of Chemical Engineering, Columbia University, New York, NY 10027, USA – sequence: 14 givenname: San Ping orcidid: 0000-0002-7042-2976 surname: Jiang fullname: Jiang, San Ping email: S.Jiang@curtin.edu.au organization: Fuels and Energy Technology Institute & Western Australia School of Mines: Minerals, Energy and Chemical Engineering, Curtin University, Perth, WA 6102, Australia |
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| Cites_doi | 10.1021/ja508879j 10.1002/anie.201602888 10.1021/acscatal.6b01297 10.1021/ar300361m 10.1021/jacs.7b02736 10.1002/ange.201507381 10.1021/ja5095099 10.1002/anie.201607885 10.1038/nchem.1095 10.1126/science.1200770 10.1126/sciadv.1500462 10.1021/ja403822d 10.1002/anie.201604654 10.1016/j.nanoen.2016.06.035 10.1021/acscatal.5b00922 10.1021/acsnano.5b01079 10.1016/j.nanoen.2016.05.025 10.1021/ja5121088 10.1039/C6SC03911A 10.1021/jacs.6b09470 10.1021/acscatal.6b01534 10.1016/j.cattod.2016.02.006 10.1021/ja409445p 10.1002/smll.201800136 10.1039/C7EE00071E 10.1038/ncomms4242 10.1038/ncomms5695 10.1038/ncomms13638 10.1038/ncomms14036 10.1103/PhysRevB.54.11169 10.1021/jacs.6b13100 10.1002/anie.201602801 10.1002/anie.201610119 10.1002/adma.201706287 10.1103/PhysRevB.13.5188 10.1021/jacs.6b00757 10.1103/PhysRevLett.77.3865 10.1016/j.carbon.2011.08.046 10.1021/jacs.5b00046 10.1021/ja309317u 10.1126/sciadv.1501122 10.1039/C7EE03245E 10.1002/anie.201509241 10.1021/jacs.5b06485 10.1134/S0030400X1303003X 10.1038/s41560-017-0078-8 10.1016/S0378-3820(01)00140-0 10.1039/C7CP00915A 10.1021/jacs.7b09074 10.1002/adfm.201800499 10.1016/j.chempr.2017.12.005 10.1103/PhysRevB.50.17953 10.1016/j.physrep.2009.02.003 10.1016/j.chempr.2017.09.014 10.1002/adma.201705850 10.1126/science.1224581 10.1002/smll.201602158 10.1039/C8EE00133B 10.1002/cctc.201600875 10.1021/jacs.6b03339 10.1149/2.026303jes |
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| References | Hall, Bock, MacDougall (bib0280) 2013; 160 Kumar, Brian, Atla, Kumari, Bertram, White, Spurgeon (bib0005) 2016; 270 Blöchl (bib0210) 1994; 50 Malard, Pimenta, Dresselhaus, Dresselhaus (bib0225) 2009; 473 Yang, Miao, Hung, Chen, Tao, Wang, Zhang, Chen, Gao, Chen, Dai, Liu (bib0230) 2016; 2 Lu, Rosen, Zhou, Hutchings, Kimmel, Chen, Jiao (bib0030) 2014; 5 X. Li, Bi, Chen, Sun, Ju, Yan, Zhu, Wu, Chu, Wu (bib0185) 2017; 139 Holby, Zelenay (bib0300) 2016; 29 Avakyan, Manukyan, Mirzakhanyan, Sharoyan, Zubavichus, Trigub, Kolpacheva, Bugaev (bib0240) 2013; 114 Deng, Chen, Yu, Wu, Liu, Liu, Yang, Tian, Hu, Du, Si, Wang, Cui, Li, Xiao, Xu, Deng, Yang, Duchesne, Zhang, Zhou, Sun, Li, Pan, Bao (bib0170) 2015; 1 Liu (bib0135) 2017; 7 Liu, Lucci, Yang, Lee, Marcinkowski, Therrien, Williams, Sykes, Flytzani-Stephanopoulos (bib0075) 2016; 138 Chen, Zhou, Xing, Xu, Tong, Xie, Zhang, Yan, Chu, Wu, Xie (bib0085) 2017; 56 Lang, Li, Matsumura, Miao, Ren, Cui, Tan, Qiao, Li, Wang, Wang, Zhang (bib0110) 2016; 55 Sa, Seo, Woo, Lim, Cheon, Yang, Lee, Kang, Shin, Shin, Jeong, Kim, Kim, Kim, Joo (bib0165) 2016; 138 Monkhorst, Pack (bib0220) 1976; 13 Perdew, Burke, Ernzerhof (bib0215) 1996; 77 He, Jagvaral (bib0120) 2017; 19 Jiang, Siahrostami, Akey, Li, Lu, Lattimer, Hu, Stokes, Gangishetty, Chen, Zhou, Hill, Cai, Bell, Chan, Norskov, Cui, Wang (bib0125) 2017; 3 Sheng, Kattel, Yao, Yan, Liang, Hawxhurst, Wu, Chen (bib0040) 2017; 10 Costentin, Drouet, Robert, Savéant (bib0265) 2012; 338 Qiao, Wang, Yang, Allard, Jiang, Cui, Liu, Li, Zhang (bib0070) 2011; 3 Back, Lim, Kim, Kim, Jung (bib0115) 2017; 8 Wu, Yadav, Liu, Sharma, Tiwary, Ma, Zou, Zhou, Yakobson, Lou, Ajayan (bib0270) 2015; 9 Zhao, Dai, Yao, Chen, Wang, Wang, Yang, Wei, Wu, Li (bib0130) 2017; 139 Zhu, Murali, Stoller, Ganesh, Cai, Ferreira, Pirkle, Wallace, Cychosz, Thommes, Su, Stach, Ruoff (bib0195) 2011; 332 Cheng, Zhao, Johannessen, Veder, Saunders, Rowles, Cheng, Liu, Chisholm, De Marco, Cheng, Yang, Jiang (bib0190) 2018; 30 Pander, Fogg, Bocarsly (bib0260) 2016; 8 Gao, Zhou, Wang, Miao, Yang, Wang, Wang, Bao (bib0035) 2015; 137 Zhang, Jia, Gao, Yan, Chen, Chen, Soo, Wood, Yang, Du, Yao (bib0155) 2018; 4 Qiu, Ito, Cong, Tan, Liu, Hirata, Fujita, Tang, Chen (bib0090) 2015; 127 Dou, Tao, Wang, El Hankari, Chen, Wang (bib0150) 2018; 30 Liu, Yang, Huang, Liu, Cai, Gao, Li, Zhang, Huang, Liu (bib0275) 2018; 28 Yan, Cheng, Yi, Lin, Yao, Wang, Li, Wei, Lu (bib0175) 2015; 137 Wang, Zhao, Wei, Wang, Cho, Cho, Terasaki, Wan (bib0290) 2013; 135 Ma, Trześniewski, Xie, Smith (bib0025) 2016; 55 Holby, Wu, Zelenay, Taylor (bib0295) 2018 Rosen, Hutchings, Lu, Forest, Moore, Jiao (bib0050) 2015; 5 Medina-Ramos, Pupillo, Keane, DiMeglio, Rosenthal (bib0060) 2015; 137 Zhao, Cheng, Veder, Johannessen, Saunders, Zhang, Liu, Chisholm, De Marco, Liu, Yang, Jiang (bib0200) 2018 Yang, Wang, Qiao, Li, Liu, Zhang (bib0140) 2013; 46 Won, Shin, Koh, Chung, Lee, Kim, Woo (bib0045) 2016; 55 Wang, Zhang, Wang, Gao, Luo, Wang, Zeng, Li, Li, Wang, Zheng, Zhu, Zhang, Ma, Si, Zeng (bib0105) 2016; 7 Cheng, Zhao, Johannessen, Veder, Saunders, Rowles, Cheng, Liu, Chisholm, De Marco, Cheng, Yang, Jiang (bib0305) 2018; 30 Zhang, Asakura, Zhang, Zhang, De, Yan (bib0100) 2016; 55 Wang, Qiao, Li, Wang (bib0145) 2018; 14 Zhang, Chi, Veith, Zhang, Lutterman, Rosenthal, Overbury, Dai, Zhu (bib0055) 2016; 6 Yang, Kim, Tak, Soon, Lee (bib0080) 2016; 55 Yang, Hung, Liu, Yuan, Miao, Zhang, Huang, Wang, Cai, Chen, Gao, Yang, Chen, Huang, Chen, Li, Zhang, Liu (bib0245) 2018; 3 Kresse, Furthmüller (bib0205) 1996; 54 Mistry, Reske, Zeng, Zhao, Greeley, Strasser, Cuenya (bib0015) 2014; 136 Zheng, Jiao, Zhu, Cai, Vasileff, Li, Han, Chen, Qiao (bib0160) 2017; 139 Cheng, Stambula, Wang, Banis, Liu, Riese, Xiao, Li, Sham, Liu, Botton, Sun (bib0095) 2016; 7 Zhu, Michalsky, Metin, Lv, Guo, Wright, Sun, Peterson, Sun (bib0020) 2013; 135 Yin, Gao, Yao, Zhao, Cai, Lin, Tang, Zhai, Wang, Ma, Bao (bib0065) 2016; 27 Wilhelm, Simbeck, Karp, Dickenson (bib0010) 2001; 71 Jiang, Siahrostami, Zheng, Hu, Hwang, Stavitski, Peng, Dynes, Gangisetty, Su, Attenkofer, Wang (bib0315) 2018; 11 Su, Iwase, Nakanishi, Hashimoto, Kamiya (bib0310) 2016; 12 C. Yan, Li, Ye, Wu, Cai, Si, Xiao, Miao, Xie, Yang, Li, Wang (bib0320) 2018; 11 Chen, Li, Kanan (bib0250) 2012; 134 Zhu, Zhang, Zhang, Lv, Li, Michalsky, Peterson, Sun (bib0255) 2014; 136 Jiang, Gu, Li, Zhang, Zhang, Zhang, Wang, Hu, Wei, Wan (bib0180) 2016; 138 Gong, Zhou, Tsai, Zhou, Guan, Lin, Zhang, Hu, Wang, Yang, Pennycook, Hwang, Dai (bib0285) 2014; 5 Zhong, Deng, Mao, Xie, Sun, Mou, Hong, Yang, Wang (bib0235) 2012; 50 Yang (10.1016/j.apcatb.2018.10.046_bib0080) 2016; 55 Won (10.1016/j.apcatb.2018.10.046_bib0045) 2016; 55 Wang (10.1016/j.apcatb.2018.10.046_bib0290) 2013; 135 Jiang (10.1016/j.apcatb.2018.10.046_bib0180) 2016; 138 Wang (10.1016/j.apcatb.2018.10.046_bib0105) 2016; 7 C. Yan (10.1016/j.apcatb.2018.10.046_bib0320) 2018; 11 Back (10.1016/j.apcatb.2018.10.046_bib0115) 2017; 8 Wang (10.1016/j.apcatb.2018.10.046_bib0145) 2018; 14 He (10.1016/j.apcatb.2018.10.046_bib0120) 2017; 19 Zhao (10.1016/j.apcatb.2018.10.046_bib0130) 2017; 139 Zheng (10.1016/j.apcatb.2018.10.046_bib0160) 2017; 139 Lang (10.1016/j.apcatb.2018.10.046_bib0110) 2016; 55 Wilhelm (10.1016/j.apcatb.2018.10.046_bib0010) 2001; 71 Hall (10.1016/j.apcatb.2018.10.046_bib0280) 2013; 160 Holby (10.1016/j.apcatb.2018.10.046_bib0295) 2018 Chen (10.1016/j.apcatb.2018.10.046_bib0250) 2012; 134 Zhang (10.1016/j.apcatb.2018.10.046_bib0055) 2016; 6 Yin (10.1016/j.apcatb.2018.10.046_bib0065) 2016; 27 Pander (10.1016/j.apcatb.2018.10.046_bib0260) 2016; 8 Chen (10.1016/j.apcatb.2018.10.046_bib0085) 2017; 56 Zhu (10.1016/j.apcatb.2018.10.046_bib0020) 2013; 135 Qiu (10.1016/j.apcatb.2018.10.046_bib0090) 2015; 127 Qiao (10.1016/j.apcatb.2018.10.046_bib0070) 2011; 3 Su (10.1016/j.apcatb.2018.10.046_bib0310) 2016; 12 Dou (10.1016/j.apcatb.2018.10.046_bib0150) 2018; 30 Liu (10.1016/j.apcatb.2018.10.046_bib0275) 2018; 28 Mistry (10.1016/j.apcatb.2018.10.046_bib0015) 2014; 136 Sheng (10.1016/j.apcatb.2018.10.046_bib0040) 2017; 10 Rosen (10.1016/j.apcatb.2018.10.046_bib0050) 2015; 5 Deng (10.1016/j.apcatb.2018.10.046_bib0170) 2015; 1 Holby (10.1016/j.apcatb.2018.10.046_bib0300) 2016; 29 Yang (10.1016/j.apcatb.2018.10.046_bib0245) 2018; 3 Wu (10.1016/j.apcatb.2018.10.046_bib0270) 2015; 9 Gong (10.1016/j.apcatb.2018.10.046_bib0285) 2014; 5 Yang (10.1016/j.apcatb.2018.10.046_bib0140) 2013; 46 Sa (10.1016/j.apcatb.2018.10.046_bib0165) 2016; 138 Zhang (10.1016/j.apcatb.2018.10.046_bib0100) 2016; 55 Jiang (10.1016/j.apcatb.2018.10.046_bib0315) 2018; 11 Gao (10.1016/j.apcatb.2018.10.046_bib0035) 2015; 137 Monkhorst (10.1016/j.apcatb.2018.10.046_bib0220) 1976; 13 Medina-Ramos (10.1016/j.apcatb.2018.10.046_bib0060) 2015; 137 Kumar (10.1016/j.apcatb.2018.10.046_bib0005) 2016; 270 Avakyan (10.1016/j.apcatb.2018.10.046_bib0240) 2013; 114 Liu (10.1016/j.apcatb.2018.10.046_bib0075) 2016; 138 Zhong (10.1016/j.apcatb.2018.10.046_bib0235) 2012; 50 Cheng (10.1016/j.apcatb.2018.10.046_bib0305) 2018; 30 Yan (10.1016/j.apcatb.2018.10.046_bib0175) 2015; 137 Zhu (10.1016/j.apcatb.2018.10.046_bib0195) 2011; 332 Cheng (10.1016/j.apcatb.2018.10.046_bib0095) 2016; 7 Kresse (10.1016/j.apcatb.2018.10.046_bib0205) 1996; 54 Cheng (10.1016/j.apcatb.2018.10.046_bib0190) 2018; 30 Malard (10.1016/j.apcatb.2018.10.046_bib0225) 2009; 473 Blöchl (10.1016/j.apcatb.2018.10.046_bib0210) 1994; 50 Yang (10.1016/j.apcatb.2018.10.046_bib0230) 2016; 2 Zhu (10.1016/j.apcatb.2018.10.046_bib0255) 2014; 136 Costentin (10.1016/j.apcatb.2018.10.046_bib0265) 2012; 338 Zhang (10.1016/j.apcatb.2018.10.046_bib0155) 2018; 4 Ma (10.1016/j.apcatb.2018.10.046_bib0025) 2016; 55 Zhao (10.1016/j.apcatb.2018.10.046_bib0200) 2018 Jiang (10.1016/j.apcatb.2018.10.046_bib0125) 2017; 3 Perdew (10.1016/j.apcatb.2018.10.046_bib0215) 1996; 77 Lu (10.1016/j.apcatb.2018.10.046_bib0030) 2014; 5 Liu (10.1016/j.apcatb.2018.10.046_bib0135) 2017; 7 X. Li (10.1016/j.apcatb.2018.10.046_bib0185) 2017; 139 |
| References_xml | – volume: 137 start-page: 5021 year: 2015 end-page: 5027 ident: bib0060 article-title: Efficient conversion of CO2 to CO using tin and other inexpensive and easily prepared post-transition metal catalysts publication-title: J. Amer. Chem. Soc. – volume: 28 start-page: 1800499 year: 2018 ident: bib0275 article-title: Idenifying active sites of nitrogen-doped carbon materials for the CO2 reduction reaction publication-title: Adv. Funct. Mater. – volume: 10 start-page: 1180 year: 2017 end-page: 1185 ident: bib0040 article-title: Electrochemical reduction of CO2 to synthesis gas with controlled CO/H2 ratios publication-title: Energy Environ. Sci. – volume: 137 start-page: 4288 year: 2015 end-page: 4291 ident: bib0035 article-title: Size-Dependent electrocatalytic reduction of CO2 over Pd nanoparticles publication-title: J. Amer. Chem. Soc. – volume: 473 start-page: 51 year: 2009 end-page: 87 ident: bib0225 article-title: Raman spectroscopy in graphene publication-title: Phys. Rep. – volume: 7 start-page: 34 year: 2017 end-page: 59 ident: bib0135 article-title: Catalysis by supported single metal atoms publication-title: ACS Catal. – volume: 3 start-page: 140 year: 2018 end-page: 147 ident: bib0245 article-title: Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction publication-title: Nat. Energy – volume: 139 start-page: 3336 year: 2017 end-page: 3339 ident: bib0160 article-title: Molecule-Level g-C3N4 coordinated transition metals as a new class of electrocatalysts for oxygen electrode reactions publication-title: J. Amer. Chem. Soc. – volume: 1 start-page: e1500462 year: 2015 ident: bib0170 article-title: A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature publication-title: Sci. Adv. – volume: 13 start-page: 5188 year: 1976 end-page: 5192 ident: bib0220 article-title: Special points for Brillouin-zone integrations publication-title: Phys. Rev. B – volume: 7 start-page: 13638 year: 2016 ident: bib0095 article-title: Platinum single-atom and cluster catalysis of the hydrogen evolution reaction publication-title: Nat. Commun. – volume: 30 start-page: 1706287 year: 2018 ident: bib0305 article-title: Atomically dispersed transition metals on carbon nanotubes with UltraHigh loading for selective electrochemical carbon dioxide reduction publication-title: Adv. Mater. – volume: 135 start-page: 11849 year: 2013 end-page: 11860 ident: bib0290 article-title: Aggregation-free gold nanoparticles in ordered mesoporous carbons: toward highly active and stable heterogeneous catalysts publication-title: J. Amer. Chem. Soc. – volume: 55 start-page: 9748 year: 2016 end-page: 9752 ident: bib0025 article-title: Selective and efficient reduction of carbon dioxide to carbon monoxide on oxide-Derived nanostructured silver electrocatalysts publication-title: Angew. Chem. Int. Ed. – volume: 55 start-page: 16054 year: 2016 end-page: 16058 ident: bib0110 article-title: Hydroformylation of olefins by a rhodium single-atom catalyst with activity comparable to RhCl(PPh3)3 publication-title: Angew. Chem. Int. Ed. – volume: 56 start-page: 610 year: 2017 end-page: 614 ident: bib0085 article-title: Atomically dispersed Iron–Nitrogen species as electrocatalysts for bifunctional oxygen evolution and reduction reactions publication-title: Angew. Chem. Int. Ed. – volume: 137 start-page: 10484 year: 2015 end-page: 10487 ident: bib0175 article-title: Single-atom Pd1/Graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1,3-Butadiene publication-title: J. Amer. Chem. Soc. – volume: 8 start-page: 3536 year: 2016 end-page: 3545 ident: bib0260 article-title: Utilization of electropolymerized films of cobalt porphyrin for the reduction of carbon dioxide in aqueous media publication-title: ChemCatChem – volume: 5 start-page: 3242 year: 2014 ident: bib0030 article-title: A selective and efficient electrocatalyst for carbon dioxide reduction publication-title: Nat. Commun. – volume: 71 start-page: 139 year: 2001 end-page: 148 ident: bib0010 article-title: Syngas production for gas-to-liquids applications: technologies, issues and outlook publication-title: Fuel Process. Technol. – year: 2018 ident: bib0200 article-title: One-pot pyrolysis method to fabricate carbon nanotube supported Ni single-atom catalysts with ultrahigh loading publication-title: ACS Applied Energy Materials – volume: 270 start-page: 19 year: 2016 end-page: 30 ident: bib0005 article-title: New trends in the development of heterogeneous catalysts for electrochemical CO2 reduction publication-title: Catal. Today – volume: 2 start-page: e1501122 year: 2016 ident: bib0230 article-title: Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: development of highly efficient metal-free bifunctional electrocatalyst publication-title: Sci. Adv. – volume: 4 start-page: 285 year: 2018 end-page: 297 ident: bib0155 article-title: Graphene defects trap atomic Ni species for hydrogen and oxygen evolution reactions publication-title: Chem – volume: 14 start-page: 1800136 year: 2018 ident: bib0145 article-title: Tuning surface electronic configuration of NiFe LDHs nanosheets by introducing cation vacancies (Fe or Ni) as highly efficient electrocatalysts for oxygen evolution reaction publication-title: Small – volume: 138 start-page: 6396 year: 2016 end-page: 6399 ident: bib0075 article-title: Tackling CO poisoning with single-atom alloy catalysts publication-title: J. Amer. Chem. Soc. – volume: 338 start-page: 90 year: 2012 end-page: 94 ident: bib0265 article-title: A local proton source enhances CO publication-title: Science – volume: 29 start-page: 54 year: 2016 end-page: 64 ident: bib0300 article-title: Linking structure to function: the search for active sites in non-platinum group metal oxygen reduction reaction catalysts publication-title: Nano Energy – volume: 30 start-page: e1706287 year: 2018 ident: bib0190 article-title: Atomically dispersed transition metals on carbon nanotubes with ultrahigh loading for selective electrochemical carbon dioxide reduction publication-title: Adv. Mater. – volume: 135 start-page: 16833 year: 2013 end-page: 16836 ident: bib0020 article-title: Monodisperse Au nanoparticles for selective electrocatalytic reduction of CO2 to CO publication-title: J. Amer. Chem. Soc. – volume: 46 start-page: 1740 year: 2013 end-page: 1748 ident: bib0140 article-title: Single-atom catalysts: a new frontier in heterogeneous catalysis publication-title: Acc. Chem. Res. – volume: 54 start-page: 11169 year: 1996 end-page: 11186 ident: bib0205 article-title: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set publication-title: Phys. Rev. B – volume: 77 start-page: 3865 year: 1996 end-page: 3868 ident: bib0215 article-title: Generalized gradient approximation made simple publication-title: Phys. Rev. Lett. – volume: 139 start-page: 14889 year: 2017 end-page: 14892 ident: bib0185 article-title: Exclusive Ni–N4 sites realize near-Unity CO selectivity for electrochemical CO2 reduction publication-title: J. Amer. Chem. Soc. – volume: 19 start-page: 11436 year: 2017 end-page: 11446 ident: bib0120 article-title: Electrochemical reduction of CO2 on graphene supported transition metals − towards single atom catalysts publication-title: Phys. Chem. Chem. Phys. – volume: 136 start-page: 16132 year: 2014 end-page: 16135 ident: bib0255 article-title: Active and selective conversion of CO2 to CO on ultrathin Au nanowires publication-title: J. Amer. Chem. Soc. – volume: 55 start-page: 9297 year: 2016 end-page: 9300 ident: bib0045 article-title: Highly efficient, selective, and stable CO2 electroreduction on a hexagonal Zn catalyst publication-title: Angew. Chem. Int. Ed. – volume: 8 start-page: 1090 year: 2017 end-page: 1096 ident: bib0115 article-title: Single-atom catalysts for CO2 electroreduction with significant activity and selectivity improvements publication-title: Chem. Sci. – volume: 55 start-page: 2058 year: 2016 end-page: 2062 ident: bib0080 article-title: Single-atom catalyst of platinum supported on titanium nitride for selective electrochemical reactions publication-title: Angew. Chem. Int. Ed. – volume: 114 start-page: 347 year: 2013 end-page: 352 ident: bib0240 article-title: Atomic structure of nickel phthalocyanine probed by X-ray absorption spectroscopy and density functional simulations publication-title: Opt. Spectrosc. – volume: 5 start-page: 4695 year: 2014 ident: bib0285 article-title: Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis publication-title: Nat. Commun. – year: 2018 ident: bib0295 article-title: Structure of Fe–Nx–C defects in oxygen reduction reaction catalysts from first-principles modeling publication-title: The Journal of Physical Chemistry – volume: 138 start-page: 15046 year: 2016 end-page: 15056 ident: bib0165 article-title: A general approach to preferential formation of active Fe–Nx sites in Fe–N/C electrocatalysts for efficient oxygen reduction reaction publication-title: J. Amer. Chem. Soc. – volume: 332 start-page: 1537 year: 2011 end-page: 1541 ident: bib0195 article-title: Carbon-Based supercapacitors produced by activation of graphene publication-title: Science – volume: 139 start-page: 8078 year: 2017 end-page: 8081 ident: bib0130 article-title: Ionic exchange of metal–organic frameworks to access single nickel sites for efficient electroreduction of CO2 publication-title: J. Amer. Chem. Soc. – volume: 3 start-page: 950 year: 2017 end-page: 960 ident: bib0125 article-title: Transition-metal single atoms in a graphene shell as active centers for highly efficient artificial photosynthesis publication-title: Chem – volume: 136 start-page: 16473 year: 2014 end-page: 16476 ident: bib0015 article-title: Exceptional size-dependent activity enhancement in the electroreduction of CO2 over Au nanoparticles publication-title: J. Amer. Chem. Soc. – volume: 12 start-page: 6083 year: 2016 end-page: 6089 ident: bib0310 article-title: Nickel-nitrogen-modified graphene: an efficient electrocatalyst for the reduction of carbon dioxide to carbon monoxide publication-title: Small – volume: 6 start-page: 6255 year: 2016 end-page: 6264 ident: bib0055 article-title: Rational design of Bi nanoparticles for efficient electrochemical CO2 reduction: the elucidation of size and surface condition effects publication-title: ACS Catal. – volume: 27 start-page: 35 year: 2016 end-page: 43 ident: bib0065 article-title: Highly selective palladium-copper bimetallic electrocatalysts for the electrochemical reduction of CO2 to CO publication-title: Nano Energy – volume: 5 start-page: 4586 year: 2015 end-page: 4591 ident: bib0050 article-title: Electrodeposited Zn dendrites with enhanced CO selectivity for electrocatalytic CO2 reduction publication-title: ACS Catal. – volume: 3 start-page: 634 year: 2011 end-page: 641 ident: bib0070 article-title: Single-atom catalysis of CO oxidation using Pt1/FeOx publication-title: Nat. Chem. – volume: 127 start-page: 14237 year: 2015 end-page: 14241 ident: bib0090 article-title: Nanoporous graphene with single-atom nickel dopants: an efficient and stable catalyst for electrochemical hydrogen production publication-title: Angewandte Chemie – volume: 50 start-page: 335 year: 2012 end-page: 338 ident: bib0235 article-title: Probing solid state N-doping in graphene by X-ray absorption near-edge structure spectroscopy publication-title: Carbon – volume: 7 start-page: 14036 year: 2016 ident: bib0105 article-title: Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst publication-title: Nat. Commun. – volume: 138 start-page: 3570 year: 2016 end-page: 3578 ident: bib0180 article-title: Understanding the high activity of Fe–N–C electrocatalysts in oxygen reduction: Fe/Fe3C nanoparticles boost the activity of Fe–Nx publication-title: J. Amer. Chem. Soc. – volume: 160 start-page: F235 year: 2013 end-page: F243 ident: bib0280 article-title: The electrochemistry of metallic nickel: oxides, hydroxides, hydrides and alkaline hydrogen evolution publication-title: J. Electrochem. Soc. – volume: 134 start-page: 19969 year: 2012 end-page: 19972 ident: bib0250 article-title: Aqueous CO2 reduction at very low overpotential on oxide-derived Au nanoparticles publication-title: J. Amer. Chem. Soc. – volume: 50 start-page: 17953 year: 1994 end-page: 17979 ident: bib0210 article-title: Projector augmented-wave method publication-title: Phys. Rev. B – volume: 55 start-page: 8319 year: 2016 end-page: 8323 ident: bib0100 article-title: Stabilizing a platinum1 single-atom catalyst on supported phosphomolybdic acid without compromising hydrogenation activity publication-title: Angew. Chem. Int. Ed. – volume: 9 start-page: 5364 year: 2015 end-page: 5371 ident: bib0270 article-title: Achieving highly efficient, selective, and stable CO2 reduction on nitrogen-doped carbon nanotubes publication-title: ACS Nano – volume: 11 start-page: 893 year: 2018 end-page: 903 ident: bib0315 article-title: Isolated Ni single atoms in graphene nanosheets for high-performance CO publication-title: Energy Environ. Sci. – volume: 11 start-page: 1204 year: 2018 end-page: 1210 ident: bib0320 article-title: Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO2 electroreduction publication-title: Energy Environ. Sci. – volume: 30 start-page: 1705850 year: 2018 ident: bib0150 article-title: Plasma-assisted synthesis and surface modification of electrode materials for renewable energy publication-title: Adv. Mater. – volume: 136 start-page: 16473 year: 2014 ident: 10.1016/j.apcatb.2018.10.046_bib0015 article-title: Exceptional size-dependent activity enhancement in the electroreduction of CO2 over Au nanoparticles publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja508879j – volume: 55 start-page: 9297 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0045 article-title: Highly efficient, selective, and stable CO2 electroreduction on a hexagonal Zn catalyst publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201602888 – volume: 6 start-page: 6255 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0055 article-title: Rational design of Bi nanoparticles for efficient electrochemical CO2 reduction: the elucidation of size and surface condition effects publication-title: ACS Catal. doi: 10.1021/acscatal.6b01297 – volume: 46 start-page: 1740 year: 2013 ident: 10.1016/j.apcatb.2018.10.046_bib0140 article-title: Single-atom catalysts: a new frontier in heterogeneous catalysis publication-title: Acc. Chem. Res. doi: 10.1021/ar300361m – volume: 139 start-page: 8078 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0130 article-title: Ionic exchange of metal–organic frameworks to access single nickel sites for efficient electroreduction of CO2 publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.7b02736 – volume: 127 start-page: 14237 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0090 article-title: Nanoporous graphene with single-atom nickel dopants: an efficient and stable catalyst for electrochemical hydrogen production publication-title: Angewandte Chemie doi: 10.1002/ange.201507381 – volume: 136 start-page: 16132 year: 2014 ident: 10.1016/j.apcatb.2018.10.046_bib0255 article-title: Active and selective conversion of CO2 to CO on ultrathin Au nanowires publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja5095099 – volume: 55 start-page: 16054 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0110 article-title: Hydroformylation of olefins by a rhodium single-atom catalyst with activity comparable to RhCl(PPh3)3 publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201607885 – volume: 3 start-page: 634 year: 2011 ident: 10.1016/j.apcatb.2018.10.046_bib0070 article-title: Single-atom catalysis of CO oxidation using Pt1/FeOx publication-title: Nat. Chem. doi: 10.1038/nchem.1095 – volume: 332 start-page: 1537 year: 2011 ident: 10.1016/j.apcatb.2018.10.046_bib0195 article-title: Carbon-Based supercapacitors produced by activation of graphene publication-title: Science doi: 10.1126/science.1200770 – volume: 1 start-page: e1500462 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0170 article-title: A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature publication-title: Sci. Adv. doi: 10.1126/sciadv.1500462 – volume: 135 start-page: 11849 year: 2013 ident: 10.1016/j.apcatb.2018.10.046_bib0290 article-title: Aggregation-free gold nanoparticles in ordered mesoporous carbons: toward highly active and stable heterogeneous catalysts publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja403822d – volume: 55 start-page: 9748 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0025 article-title: Selective and efficient reduction of carbon dioxide to carbon monoxide on oxide-Derived nanostructured silver electrocatalysts publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201604654 – volume: 27 start-page: 35 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0065 article-title: Highly selective palladium-copper bimetallic electrocatalysts for the electrochemical reduction of CO2 to CO publication-title: Nano Energy doi: 10.1016/j.nanoen.2016.06.035 – volume: 5 start-page: 4586 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0050 article-title: Electrodeposited Zn dendrites with enhanced CO selectivity for electrocatalytic CO2 reduction publication-title: ACS Catal. doi: 10.1021/acscatal.5b00922 – volume: 9 start-page: 5364 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0270 article-title: Achieving highly efficient, selective, and stable CO2 reduction on nitrogen-doped carbon nanotubes publication-title: ACS Nano doi: 10.1021/acsnano.5b01079 – volume: 29 start-page: 54 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0300 article-title: Linking structure to function: the search for active sites in non-platinum group metal oxygen reduction reaction catalysts publication-title: Nano Energy doi: 10.1016/j.nanoen.2016.05.025 – volume: 137 start-page: 5021 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0060 article-title: Efficient conversion of CO2 to CO using tin and other inexpensive and easily prepared post-transition metal catalysts publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja5121088 – volume: 8 start-page: 1090 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0115 article-title: Single-atom catalysts for CO2 electroreduction with significant activity and selectivity improvements publication-title: Chem. Sci. doi: 10.1039/C6SC03911A – volume: 138 start-page: 15046 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0165 article-title: A general approach to preferential formation of active Fe–Nx sites in Fe–N/C electrocatalysts for efficient oxygen reduction reaction publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.6b09470 – volume: 7 start-page: 34 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0135 article-title: Catalysis by supported single metal atoms publication-title: ACS Catal. doi: 10.1021/acscatal.6b01534 – volume: 270 start-page: 19 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0005 article-title: New trends in the development of heterogeneous catalysts for electrochemical CO2 reduction publication-title: Catal. Today doi: 10.1016/j.cattod.2016.02.006 – volume: 135 start-page: 16833 year: 2013 ident: 10.1016/j.apcatb.2018.10.046_bib0020 article-title: Monodisperse Au nanoparticles for selective electrocatalytic reduction of CO2 to CO publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja409445p – volume: 14 start-page: 1800136 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0145 article-title: Tuning surface electronic configuration of NiFe LDHs nanosheets by introducing cation vacancies (Fe or Ni) as highly efficient electrocatalysts for oxygen evolution reaction publication-title: Small doi: 10.1002/smll.201800136 – volume: 10 start-page: 1180 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0040 article-title: Electrochemical reduction of CO2 to synthesis gas with controlled CO/H2 ratios publication-title: Energy Environ. Sci. doi: 10.1039/C7EE00071E – year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0295 article-title: Structure of Fe–Nx–C defects in oxygen reduction reaction catalysts from first-principles modeling publication-title: The Journal of Physical Chemistry – volume: 5 start-page: 3242 year: 2014 ident: 10.1016/j.apcatb.2018.10.046_bib0030 article-title: A selective and efficient electrocatalyst for carbon dioxide reduction publication-title: Nat. Commun. doi: 10.1038/ncomms4242 – volume: 5 start-page: 4695 year: 2014 ident: 10.1016/j.apcatb.2018.10.046_bib0285 article-title: Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis publication-title: Nat. Commun. doi: 10.1038/ncomms5695 – volume: 7 start-page: 13638 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0095 article-title: Platinum single-atom and cluster catalysis of the hydrogen evolution reaction publication-title: Nat. Commun. doi: 10.1038/ncomms13638 – volume: 7 start-page: 14036 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0105 article-title: Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst publication-title: Nat. Commun. doi: 10.1038/ncomms14036 – volume: 54 start-page: 11169 year: 1996 ident: 10.1016/j.apcatb.2018.10.046_bib0205 article-title: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.54.11169 – volume: 139 start-page: 3336 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0160 article-title: Molecule-Level g-C3N4 coordinated transition metals as a new class of electrocatalysts for oxygen electrode reactions publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.6b13100 – volume: 55 start-page: 8319 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0100 article-title: Stabilizing a platinum1 single-atom catalyst on supported phosphomolybdic acid without compromising hydrogenation activity publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201602801 – volume: 56 start-page: 610 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0085 article-title: Atomically dispersed Iron–Nitrogen species as electrocatalysts for bifunctional oxygen evolution and reduction reactions publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201610119 – volume: 30 start-page: 1706287 issue: 13 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0305 article-title: Atomically dispersed transition metals on carbon nanotubes with UltraHigh loading for selective electrochemical carbon dioxide reduction publication-title: Adv. Mater. doi: 10.1002/adma.201706287 – volume: 13 start-page: 5188 year: 1976 ident: 10.1016/j.apcatb.2018.10.046_bib0220 article-title: Special points for Brillouin-zone integrations publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.13.5188 – volume: 138 start-page: 3570 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0180 article-title: Understanding the high activity of Fe–N–C electrocatalysts in oxygen reduction: Fe/Fe3C nanoparticles boost the activity of Fe–Nx publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.6b00757 – volume: 77 start-page: 3865 year: 1996 ident: 10.1016/j.apcatb.2018.10.046_bib0215 article-title: Generalized gradient approximation made simple publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.77.3865 – volume: 50 start-page: 335 year: 2012 ident: 10.1016/j.apcatb.2018.10.046_bib0235 article-title: Probing solid state N-doping in graphene by X-ray absorption near-edge structure spectroscopy publication-title: Carbon doi: 10.1016/j.carbon.2011.08.046 – volume: 137 start-page: 4288 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0035 article-title: Size-Dependent electrocatalytic reduction of CO2 over Pd nanoparticles publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.5b00046 – volume: 30 start-page: e1706287 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0190 article-title: Atomically dispersed transition metals on carbon nanotubes with ultrahigh loading for selective electrochemical carbon dioxide reduction publication-title: Adv. Mater. doi: 10.1002/adma.201706287 – year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0200 article-title: One-pot pyrolysis method to fabricate carbon nanotube supported Ni single-atom catalysts with ultrahigh loading publication-title: ACS Applied Energy Materials – volume: 134 start-page: 19969 year: 2012 ident: 10.1016/j.apcatb.2018.10.046_bib0250 article-title: Aqueous CO2 reduction at very low overpotential on oxide-derived Au nanoparticles publication-title: J. Amer. Chem. Soc. doi: 10.1021/ja309317u – volume: 2 start-page: e1501122 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0230 article-title: Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: development of highly efficient metal-free bifunctional electrocatalyst publication-title: Sci. Adv. doi: 10.1126/sciadv.1501122 – volume: 11 start-page: 893 issue: 4 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0315 article-title: Isolated Ni single atoms in graphene nanosheets for high-performance CO2 reduction publication-title: Energy Environ. Sci. doi: 10.1039/C7EE03245E – volume: 55 start-page: 2058 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0080 article-title: Single-atom catalyst of platinum supported on titanium nitride for selective electrochemical reactions publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201509241 – volume: 137 start-page: 10484 year: 2015 ident: 10.1016/j.apcatb.2018.10.046_bib0175 article-title: Single-atom Pd1/Graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1,3-Butadiene publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.5b06485 – volume: 114 start-page: 347 year: 2013 ident: 10.1016/j.apcatb.2018.10.046_bib0240 article-title: Atomic structure of nickel phthalocyanine probed by X-ray absorption spectroscopy and density functional simulations publication-title: Opt. Spectrosc. doi: 10.1134/S0030400X1303003X – volume: 3 start-page: 140 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0245 article-title: Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction publication-title: Nat. Energy doi: 10.1038/s41560-017-0078-8 – volume: 71 start-page: 139 year: 2001 ident: 10.1016/j.apcatb.2018.10.046_bib0010 article-title: Syngas production for gas-to-liquids applications: technologies, issues and outlook publication-title: Fuel Process. Technol. doi: 10.1016/S0378-3820(01)00140-0 – volume: 19 start-page: 11436 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0120 article-title: Electrochemical reduction of CO2 on graphene supported transition metals − towards single atom catalysts publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C7CP00915A – volume: 139 start-page: 14889 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0185 article-title: Exclusive Ni–N4 sites realize near-Unity CO selectivity for electrochemical CO2 reduction publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.7b09074 – volume: 28 start-page: 1800499 issue: 21 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0275 article-title: Idenifying active sites of nitrogen-doped carbon materials for the CO2 reduction reaction publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201800499 – volume: 4 start-page: 285 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0155 article-title: Graphene defects trap atomic Ni species for hydrogen and oxygen evolution reactions publication-title: Chem doi: 10.1016/j.chempr.2017.12.005 – volume: 50 start-page: 17953 year: 1994 ident: 10.1016/j.apcatb.2018.10.046_bib0210 article-title: Projector augmented-wave method publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.50.17953 – volume: 473 start-page: 51 year: 2009 ident: 10.1016/j.apcatb.2018.10.046_bib0225 article-title: Raman spectroscopy in graphene publication-title: Phys. Rep. doi: 10.1016/j.physrep.2009.02.003 – volume: 3 start-page: 950 year: 2017 ident: 10.1016/j.apcatb.2018.10.046_bib0125 article-title: Transition-metal single atoms in a graphene shell as active centers for highly efficient artificial photosynthesis publication-title: Chem doi: 10.1016/j.chempr.2017.09.014 – volume: 30 start-page: 1705850 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0150 article-title: Plasma-assisted synthesis and surface modification of electrode materials for renewable energy publication-title: Adv. Mater. doi: 10.1002/adma.201705850 – volume: 338 start-page: 90 year: 2012 ident: 10.1016/j.apcatb.2018.10.046_bib0265 article-title: A local proton source enhances CO2 electroreduction to CO by a molecular Fe catalyst publication-title: Science doi: 10.1126/science.1224581 – volume: 12 start-page: 6083 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0310 article-title: Nickel-nitrogen-modified graphene: an efficient electrocatalyst for the reduction of carbon dioxide to carbon monoxide publication-title: Small doi: 10.1002/smll.201602158 – volume: 11 start-page: 1204 year: 2018 ident: 10.1016/j.apcatb.2018.10.046_bib0320 article-title: Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO2 electroreduction publication-title: Energy Environ. Sci. doi: 10.1039/C8EE00133B – volume: 8 start-page: 3536 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0260 article-title: Utilization of electropolymerized films of cobalt porphyrin for the reduction of carbon dioxide in aqueous media publication-title: ChemCatChem doi: 10.1002/cctc.201600875 – volume: 138 start-page: 6396 year: 2016 ident: 10.1016/j.apcatb.2018.10.046_bib0075 article-title: Tackling CO poisoning with single-atom alloy catalysts publication-title: J. Amer. Chem. Soc. doi: 10.1021/jacs.6b03339 – volume: 160 start-page: F235 year: 2013 ident: 10.1016/j.apcatb.2018.10.046_bib0280 article-title: The electrochemistry of metallic nickel: oxides, hydroxides, hydrides and alkaline hydrogen evolution publication-title: J. Electrochem. Soc. doi: 10.1149/2.026303jes |
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•3D porous graphene with high loading (6.9 wt%) of single atom Ni was produced.•High performance in electrochemical CO2 reduction was... |
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| SubjectTerms | Defects Density functional simulation Edge-anchored Electrochemical CO2 reduction Ni single-atom catalysts |
| Title | Unsaturated edge-anchored Ni single atoms on porous microwave exfoliated graphene oxide for electrochemical CO2 |
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