The role of pore size on the thermal stability of zeolite supported Cu SCR catalysts
•The pore size affects the hydrothermal stability of zeolite supported Cu catalysts.•Small pore catalysts are more stable than large or medium pore catalysts.•In situ XRD experiments were performed to understand the pore size effects.•Destructive Cu/Al2O3 interaction is minimized on the small pore z...
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Published in | Catalysis today Vol. 231; pp. 56 - 63 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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Elsevier B.V
01.08.2014
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Abstract | •The pore size affects the hydrothermal stability of zeolite supported Cu catalysts.•Small pore catalysts are more stable than large or medium pore catalysts.•In situ XRD experiments were performed to understand the pore size effects.•Destructive Cu/Al2O3 interaction is minimized on the small pore zeolite catalysts.•This is attributed to the steric restriction in the small pore zeolite structure.
A comparison study on the hydrothermal stability of Cu SCR catalysts supported on an 8-ring small pore chabazite and a 12-ring large pore beta zeolite was performed to understand why small pore zeolite supported Cu catalysts are in general hydrothermally more stable than medium pore or large pore zeolite supported Cu catalysts and how different pore sizes affect the hydrothermal stability of the catalysts. In situ XRD hydrothermal experiments show that, even though the parent chabazite and beta zeolites have comparable hydrothermal stability and both can maintain their zeolite framework structure after a 900°C hydrothermal exposure, the presence of Cu in the Cu/beta catalyst accelerates the collapse of the BEA framework structure at temperatures above 800°C whereas Cu in the Cu/chabazite catalyst has little effect on the CHA framework structure. The loss of beta zeolite framework structure is due to a detrimental Cu/Al2O3 interaction. It is proposed that the constricting dimensions of the small openings in a small pore zeolite can hinder the destructive Cu/Al2O3 interaction as well as the zeolite dealumination process, hence significantly improving the hydrothermal stability of the small pore zeolite supported Cu catalyst. |
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AbstractList | •The pore size affects the hydrothermal stability of zeolite supported Cu catalysts.•Small pore catalysts are more stable than large or medium pore catalysts.•In situ XRD experiments were performed to understand the pore size effects.•Destructive Cu/Al2O3 interaction is minimized on the small pore zeolite catalysts.•This is attributed to the steric restriction in the small pore zeolite structure.
A comparison study on the hydrothermal stability of Cu SCR catalysts supported on an 8-ring small pore chabazite and a 12-ring large pore beta zeolite was performed to understand why small pore zeolite supported Cu catalysts are in general hydrothermally more stable than medium pore or large pore zeolite supported Cu catalysts and how different pore sizes affect the hydrothermal stability of the catalysts. In situ XRD hydrothermal experiments show that, even though the parent chabazite and beta zeolites have comparable hydrothermal stability and both can maintain their zeolite framework structure after a 900°C hydrothermal exposure, the presence of Cu in the Cu/beta catalyst accelerates the collapse of the BEA framework structure at temperatures above 800°C whereas Cu in the Cu/chabazite catalyst has little effect on the CHA framework structure. The loss of beta zeolite framework structure is due to a detrimental Cu/Al2O3 interaction. It is proposed that the constricting dimensions of the small openings in a small pore zeolite can hinder the destructive Cu/Al2O3 interaction as well as the zeolite dealumination process, hence significantly improving the hydrothermal stability of the small pore zeolite supported Cu catalyst. |
Author | Collier, Jillian E. Chen, Hai-Ying Jobson, Hoi Fedeyko, Joseph M. Burkholder, Eric M. Rajaram, Raj R. Blakeman, Philip G. |
Author_xml | – sequence: 1 givenname: Philip G. surname: Blakeman fullname: Blakeman, Philip G. organization: Johnson Matthey Emission Control Technologies, Wayne, PA 19087, USA – sequence: 2 givenname: Eric M. surname: Burkholder fullname: Burkholder, Eric M. organization: Johnson Matthey Emission Control Technologies, Wayne, PA 19087, USA – sequence: 3 givenname: Hai-Ying surname: Chen fullname: Chen, Hai-Ying email: chenh@jmusa.com organization: Johnson Matthey Emission Control Technologies, Wayne, PA 19087, USA – sequence: 4 givenname: Jillian E. surname: Collier fullname: Collier, Jillian E. organization: Johnson Matthey Technology Centre, Reading, RG4 9NH, UK – sequence: 5 givenname: Joseph M. surname: Fedeyko fullname: Fedeyko, Joseph M. organization: Johnson Matthey Emission Control Technologies, Wayne, PA 19087, USA – sequence: 6 givenname: Hoi surname: Jobson fullname: Jobson, Hoi organization: Johnson Matthey Technology Centre, Reading, RG4 9NH, UK – sequence: 7 givenname: Raj R. surname: Rajaram fullname: Rajaram, Raj R. organization: Johnson Matthey Technology Centre, Reading, RG4 9NH, UK |
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Snippet | •The pore size affects the hydrothermal stability of zeolite supported Cu catalysts.•Small pore catalysts are more stable than large or medium pore... |
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SubjectTerms | Cu/Al2O3 interaction Cu/zeolite SCR catalysts Hydrothermal stability In situ XRD Zeolite pore size effect |
Title | The role of pore size on the thermal stability of zeolite supported Cu SCR catalysts |
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