Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review
Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO2 based photocatalysts are novel materials that exhibit excellent absorption behavior toward organic compounds in wastewater due to their outstanding properties including nontoxici...
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| Published in | Journal of cleaner production Vol. 268; p. 121725 |
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| Main Authors | , , , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
20.09.2020
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO2 based photocatalysts are novel materials that exhibit excellent absorption behavior toward organic compounds in wastewater due to their outstanding properties including nontoxicity, high photocatalytic degradation ability, and excellent thermal and chemical stabilities. However, several challenges exist regarding TiO2 applications for organic effluents such as particle aggregation, mass transfer limitation, poor affinity, high band energy, scattering conditions, and difficulty of recovery. Therefore, more design and optimization testing need to be conducted on the treatment conditions in order to reach higher removal efficiencies with lower costs. A variety of parameters of TiO2 based photocatalysts need to be studied: substrate, light intensity, dopant, particle size, structure. These parameters, which affect TiO2 photocatalytic activity on organic pollutants, are discussed in the current review. Thus, making the photocatalyst more anticipated and conducive to further research and development.
•Six unique challenges inhibit the application of TiO2 in organic effluents.•Various parameters such as TiO2 forms and substrates were discussed.•High band energy and transfer limitation are the primary limitations.•The key processing parameters are selection of TiO2 substrate and dopant. |
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| AbstractList | Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO2 based photocatalysts are novel materials that exhibit excellent absorption behavior toward organic compounds in wastewater due to their outstanding properties including nontoxicity, high photocatalytic degradation ability, and excellent thermal and chemical stabilities. However, several challenges exist regarding TiO2 applications for organic effluents such as particle aggregation, mass transfer limitation, poor affinity, high band energy, scattering conditions, and difficulty of recovery. Therefore, more design and optimization testing need to be conducted on the treatment conditions in order to reach higher removal efficiencies with lower costs. A variety of parameters of TiO2 based photocatalysts need to be studied: substrate, light intensity, dopant, particle size, structure. These parameters, which affect TiO2 photocatalytic activity on organic pollutants, are discussed in the current review. Thus, making the photocatalyst more anticipated and conducive to further research and development.
•Six unique challenges inhibit the application of TiO2 in organic effluents.•Various parameters such as TiO2 forms and substrates were discussed.•High band energy and transfer limitation are the primary limitations.•The key processing parameters are selection of TiO2 substrate and dopant. Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO₂ based photocatalysts are novel materials that exhibit excellent absorption behavior toward organic compounds in wastewater due to their outstanding properties including nontoxicity, high photocatalytic degradation ability, and excellent thermal and chemical stabilities. However, several challenges exist regarding TiO₂ applications for organic effluents such as particle aggregation, mass transfer limitation, poor affinity, high band energy, scattering conditions, and difficulty of recovery. Therefore, more design and optimization testing need to be conducted on the treatment conditions in order to reach higher removal efficiencies with lower costs. A variety of parameters of TiO₂ based photocatalysts need to be studied: substrate, light intensity, dopant, particle size, structure. These parameters, which affect TiO₂ photocatalytic activity on organic pollutants, are discussed in the current review. Thus, making the photocatalyst more anticipated and conducive to further research and development. |
| ArticleNumber | 121725 |
| Author | Peng, Peng Liu, Yuhuan Cheng, Yanling Zhou, Nan Chen, Paul Cheng, Pengfei Huo, Shuhao Li, Kun Zhang, Renchuan Ruan, Roger Chen, Dongjie Wang, Yunpu Wang, Lu Liu, Hui |
| Author_xml | – sequence: 1 givenname: Dongjie surname: Chen fullname: Chen, Dongjie organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 2 givenname: Yanling surname: Cheng fullname: Cheng, Yanling organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 3 givenname: Nan surname: Zhou fullname: Zhou, Nan organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 4 givenname: Paul surname: Chen fullname: Chen, Paul organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 5 givenname: Yunpu surname: Wang fullname: Wang, Yunpu organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 6 givenname: Kun surname: Li fullname: Li, Kun organization: College of Food Science and Engineering, Nanchang University, Jiangxi, China – sequence: 7 givenname: Shuhao surname: Huo fullname: Huo, Shuhao organization: School of Food and Biological Engineering, Jiangsu University, Zhenjiang, China – sequence: 8 givenname: Pengfei surname: Cheng fullname: Cheng, Pengfei organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 9 givenname: Peng surname: Peng fullname: Peng, Peng organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 10 givenname: Renchuan surname: Zhang fullname: Zhang, Renchuan organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 11 givenname: Lu surname: Wang fullname: Wang, Lu organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA – sequence: 12 givenname: Hui surname: Liu fullname: Liu, Hui organization: Department of Environment Science and Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou, China – sequence: 13 givenname: Yuhuan surname: Liu fullname: Liu, Yuhuan organization: College of Food Science and Engineering, Nanchang University, Jiangxi, China – sequence: 14 givenname: Roger surname: Ruan fullname: Ruan, Roger email: ruanx001@umn.edu organization: Center for Biorefining and Department of Bioproducts and Biosystems Engineering, University of Minnesota, St. Paul, MN, USA |
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| Keywords | Photocatalytic degradation TiO2 based photocatalysts Organic pollutants Processing parameters |
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| Snippet | Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO2 based photocatalysts are novel... Organic compounds, generated from different industries, produce a range of the problematic pollutants in wastewater. TiO₂ based photocatalysts are novel... |
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| SubjectTerms | absorption energy light intensity mass transfer Organic pollutants particle size photocatalysis photocatalysts Photocatalytic degradation Processing parameters research and development TiO2 based photocatalysts wastewater |
| Title | Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review |
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