Ion-Conductive Nanostructured Polymer Films Formed by Photopolymerization of Lyotropic Columnar Liquid-Crystalline Monomers, Composed of a Zwitterionic Compound and a Protic Ionic Liquid
Here, we report on a new family of columnar nanostructured polymer films forming protic nanochannels that exhibit good ionic conductivities in the order of 10−4–10−3 S cm−1 at ambient temperature. These polymer films were obtained by the in situ photopolymerization of lyotropic columnar liquid cryst...
Saved in:
Published in | Crystals (Basel) Vol. 10; no. 4; p. 276 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
MDPI AG
01.04.2020
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Here, we report on a new family of columnar nanostructured polymer films forming protic nanochannels that exhibit good ionic conductivities in the order of 10−4–10−3 S cm−1 at ambient temperature. These polymer films were obtained by the in situ photopolymerization of lyotropic columnar liquid crystals, consisting of a polymerizable taper-shaped zwitterionic compound and a protic ionic liquid (imidazolium bis(trifluoromethylsulfonyl)imide), in the presence of 15 wt% water. The composition of the protic ionic liquid in the mixture was changed from 40 to 60 mol%. The ionic conductivities were measured by an alternating current impedance method. The ionic conductivity increased with the increase of the protic ionic liquid. The conductivities of columnar nanostructured polymer films were about 2–3 orders of magnitude higher than those of amorphous polymer films prepared by photopolymerization of the corresponding monomers in an isotropic liquid state. The formation of nanochannels in the polymer matrices significantly enhanced the ion conduction. The present two-component lyotropic liquid-crystalline self-assembly followed by photopolymerization is a promising approach to the development of high ion-conductive polymer membranes. |
---|---|
AbstractList | Here, we report on a new family of columnar nanostructured polymer films forming protic nanochannels that exhibit good ionic conductivities in the order of 10−4–10−3 S cm−1 at ambient temperature. These polymer films were obtained by the in situ photopolymerization of lyotropic columnar liquid crystals, consisting of a polymerizable taper-shaped zwitterionic compound and a protic ionic liquid (imidazolium bis(trifluoromethylsulfonyl)imide), in the presence of 15 wt% water. The composition of the protic ionic liquid in the mixture was changed from 40 to 60 mol%. The ionic conductivities were measured by an alternating current impedance method. The ionic conductivity increased with the increase of the protic ionic liquid. The conductivities of columnar nanostructured polymer films were about 2–3 orders of magnitude higher than those of amorphous polymer films prepared by photopolymerization of the corresponding monomers in an isotropic liquid state. The formation of nanochannels in the polymer matrices significantly enhanced the ion conduction. The present two-component lyotropic liquid-crystalline self-assembly followed by photopolymerization is a promising approach to the development of high ion-conductive polymer membranes. |
Author | Cao, Siyu Seki, Atsushi Yoshio, Masafumi |
Author_xml | – sequence: 1 givenname: Siyu surname: Cao fullname: Cao, Siyu – sequence: 2 givenname: Masafumi orcidid: 0000-0002-1442-4352 surname: Yoshio fullname: Yoshio, Masafumi – sequence: 3 givenname: Atsushi surname: Seki fullname: Seki, Atsushi |
BookMark | eNpVkc9O3DAQxq2KSqWUI3c_QFP8b2PnWEXdstICe2gvXCJvbLdGiWexnaLwaDwd3l1UgSXLM9_M_DTy9xmdBAgWoQtKvnHekMs-zilTQgRhsv6AThmRvBJ8wU7exJ_QeUr3pBxZEynpKXpeQahaCGbqs_9n8Y0OkHIs2RStwRsY5tFGvPTDmPAS4ljE7Yw3fyHD7lj0Tzp7CBgcXs-QI-x8j1sYpjHoiNf-YfKmavfr6WHwweJrCFDm0tfSNe4gFWSZ1fju0edceBAOgFKagsF6f_EmQi7q6lA7Mr-gj04PyZ6_vmfo9_LHr_aqWt_-XLXf11UviMqVooQSQa2qey41c4KUn-CEqoYptnVOi9LXGLZgRjvJhTILXXOrmaCikbTmZ2h15BrQ990u-lHHuQPtu4MA8U-nY1lusF1jyVaR2qi-GMEauzWMKSuk447JEhZWdWT1EVKK1v3nUdLtfeze-chfACsNljI |
CitedBy_id | crossref_primary_10_3390_molecules25215207 crossref_primary_10_1039_D3QM00192J |
Cites_doi | 10.1038/natrevmats.2017.1 10.1002/app.47349 10.1021/ja963837w 10.1039/C3RA45044A 10.1038/ncomms13576 10.1021/acs.langmuir.7b03504 10.1002/open.201600054 10.1021/acsmacrolett.8b00821 10.1038/pj.2017.6 10.1039/C5TA06414G 10.1557/mrs.2013.153 10.1016/j.memsci.2006.09.023 10.1021/ja407883b 10.1021/ja304124w 10.1039/b404137b 10.1039/C9CC04280F 10.1039/C9SC00131J 10.1002/adma.201200108 10.1039/b300959a 10.1002/adma.201100942 |
ContentType | Journal Article |
DBID | AAYXX CITATION DOA |
DOI | 10.3390/cryst10040276 |
DatabaseName | CrossRef DOAJ Directory of Open Access Journals |
DatabaseTitle | CrossRef |
DatabaseTitleList | CrossRef |
Database_xml | – sequence: 1 dbid: DOA name: Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering |
EISSN | 2073-4352 |
ExternalDocumentID | oai_doaj_org_article_9e0b806d8c00429ebd228e47f3f27228 10_3390_cryst10040276 |
GroupedDBID | .4S 5VS 8FE 8FG AADQD AAFWJ AAYXX ABJCF ADBBV AENEX AFKRA AFPKN AFZYC ALMA_UNASSIGNED_HOLDINGS ARCSS BCNDV BENPR BGLVJ CCPQU CITATION D1I EDO GROUPED_DOAJ HCIFZ IAO KB. KQ8 MODMG M~E OK1 PDBOC PIMPY PROAC RIG TUS |
ID | FETCH-LOGICAL-c408t-8101041e86c37a2f4043530189282bffa4c409d252daf7348d5a63ea241497163 |
IEDL.DBID | DOA |
ISSN | 2073-4352 |
IngestDate | Fri Oct 04 13:09:56 EDT 2024 Thu Sep 26 21:40:41 EDT 2024 |
IsDoiOpenAccess | true |
IsOpenAccess | true |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 4 |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c408t-8101041e86c37a2f4043530189282bffa4c409d252daf7348d5a63ea241497163 |
ORCID | 0000-0002-1442-4352 |
OpenAccessLink | https://doaj.org/article/9e0b806d8c00429ebd228e47f3f27228 |
ParticipantIDs | doaj_primary_oai_doaj_org_article_9e0b806d8c00429ebd228e47f3f27228 crossref_primary_10_3390_cryst10040276 |
PublicationCentury | 2000 |
PublicationDate | 2020-04-01 |
PublicationDateYYYYMMDD | 2020-04-01 |
PublicationDate_xml | – month: 04 year: 2020 text: 2020-04-01 day: 01 |
PublicationDecade | 2020 |
PublicationTitle | Crystals (Basel) |
PublicationYear | 2020 |
Publisher | MDPI AG |
Publisher_xml | – name: MDPI AG |
References | Yasuda (ref_17) 2013; 38 Henmi (ref_7) 2012; 24 Wu (ref_20) 2017; 33 Smith (ref_18) 1997; 119 Susan (ref_19) 2003; 8 Hamaguchi (ref_6) 2018; 8 Wang (ref_5) 2019; 136 Yamashita (ref_10) 2015; 3 Soberats (ref_11) 2013; 135 Ichikawa (ref_2) 2019; 55 Bara (ref_8) 2007; 288 Cho (ref_4) 2014; 4 Kato (ref_1) 2017; 2 Ichikawa (ref_3) 2017; 49 Kim (ref_9) 2016; 7 Ichikawa (ref_13) 2012; 134 Ueda (ref_14) 2011; 23 Ichikawa (ref_15) 2016; 5 Yoshizawa (ref_12) 2004; 16 Kobayashi (ref_16) 2019; 10 |
References_xml | – volume: 2 start-page: 17001 year: 2017 ident: ref_1 article-title: Transport of ions and electrons in nanostructured liquid crystals publication-title: Nat. Rev. Mater. doi: 10.1038/natrevmats.2017.1 contributor: fullname: Kato – volume: 136 start-page: 47349 year: 2019 ident: ref_5 article-title: Anisotropic films photopolymerized from aligned cross-linkable gemini ammonium liquid crystals for ion conduction publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.47349 contributor: fullname: Wang – volume: 119 start-page: 4092 year: 1997 ident: ref_18 article-title: Ordered Poly(p-phenylenevinylene) Matrix Nanocomposites via Lyotropic Liquid-Crystalline Monomers publication-title: J. Am. Chem. Soc. doi: 10.1021/ja963837w contributor: fullname: Smith – volume: 4 start-page: 395 year: 2014 ident: ref_4 article-title: Nanostructured organic electrolytes publication-title: RSC Adv. doi: 10.1039/C3RA45044A contributor: fullname: Cho – volume: 7 start-page: 13576 year: 2016 ident: ref_9 article-title: One-volt-driven superfast polymer actuators based on single-ion conductors publication-title: Nat. Commun. doi: 10.1038/ncomms13576 contributor: fullname: Kim – volume: 33 start-page: 13982 year: 2017 ident: ref_20 article-title: Low-Molecular-Weight Supramolecular Ionogel Based on Host-Guest Interaction publication-title: Langmuir doi: 10.1021/acs.langmuir.7b03504 contributor: fullname: Wu – volume: 5 start-page: 439 year: 2016 ident: ref_15 article-title: Induction of an Infinite Periodic Minimal Surface by Endowing An Amphiphilic Zwitterion with Halogen-Bond Ability publication-title: ChemistryOpen doi: 10.1002/open.201600054 contributor: fullname: Ichikawa – volume: 8 start-page: 24 year: 2018 ident: ref_6 article-title: Nanostructured Virus Filtration Membranes Based on Two-Component Columnar Liquid Crystals publication-title: ACS Macro Lett. doi: 10.1021/acsmacrolett.8b00821 contributor: fullname: Hamaguchi – volume: 49 start-page: 413 year: 2017 ident: ref_3 article-title: Zwitterions as building blocks for functional liquid crystals and block copolymers publication-title: Polym. J. doi: 10.1038/pj.2017.6 contributor: fullname: Ichikawa – volume: 3 start-page: 22656 year: 2015 ident: ref_10 article-title: Use of a protic salt for the formation of liquid-crystalline proton-conductive complexes with mesomorphic diols publication-title: J. Mater. Chem. A doi: 10.1039/C5TA06414G contributor: fullname: Yamashita – volume: 38 start-page: 560 year: 2013 ident: ref_17 article-title: Protic ionic liquids: Fuel cell applications publication-title: MRS Bull. doi: 10.1557/mrs.2013.153 contributor: fullname: Yasuda – volume: 288 start-page: 13 year: 2007 ident: ref_8 article-title: Influence of nanostructure on light gas separations in cross-linked lyotropic liquid crystal membranes publication-title: J. Memb. Sci. doi: 10.1016/j.memsci.2006.09.023 contributor: fullname: Bara – volume: 135 start-page: 15286 year: 2013 ident: ref_11 article-title: 3D Anhydrous Proton-Transporting Nanochannels Formed by Self-Assembly of Liquid Crystals Composed of a Sulfobetaine and a Sulfonic Acid publication-title: J. Am. Chem. Soc. doi: 10.1021/ja407883b contributor: fullname: Soberats – volume: 134 start-page: 11354 year: 2012 ident: ref_13 article-title: 3D Continuous Water Nanosheet as a Gyroid Minimal Surface Formed by Bicontinuous Cubic Liquid-Crystalline Zwitterions publication-title: J. Am. Chem. Soc. doi: 10.1021/ja304124w contributor: fullname: Ichikawa – volume: 16 start-page: 1828 year: 2004 ident: ref_12 article-title: Anhydrous proton transport system based on zwitterionic liquid and HTFSI publication-title: Chem. Commun. doi: 10.1039/b404137b contributor: fullname: Yoshizawa – volume: 55 start-page: 8205 year: 2019 ident: ref_2 article-title: Dimension control of ionic liquids publication-title: Chem. Commun. doi: 10.1039/C9CC04280F contributor: fullname: Ichikawa – volume: 10 start-page: 6245 year: 2019 ident: ref_16 article-title: Gyroid structured aqua-sheets with sub-nanometer thickness enabling 3D fast proton relay conduction publication-title: Chem. Sci. doi: 10.1039/C9SC00131J contributor: fullname: Kobayashi – volume: 24 start-page: 2238 year: 2012 ident: ref_7 article-title: Self-organized Liquid-Crystalline Nanostructured Membranes for Water Treatment: Selective Permeation of Ions publication-title: Adv. Mater. doi: 10.1002/adma.201200108 contributor: fullname: Henmi – volume: 8 start-page: 938 year: 2003 ident: ref_19 article-title: Brønsted Acid–Base Ionic Liquids and Their Use as New Materials for Anhydrous Proton Conductors publication-title: Chem. Commun. doi: 10.1039/b300959a contributor: fullname: Susan – volume: 23 start-page: 3071 year: 2011 ident: ref_14 article-title: Anisotropic proton-conductive materials formed by the self-organization of phosphonium-type zwitterions publication-title: Adv. Mater. doi: 10.1002/adma.201100942 contributor: fullname: Ueda |
SSID | ssj0000760771 |
Score | 2.2073126 |
Snippet | Here, we report on a new family of columnar nanostructured polymer films forming protic nanochannels that exhibit good ionic conductivities in the order of... |
SourceID | doaj crossref |
SourceType | Open Website Aggregation Database |
StartPage | 276 |
SubjectTerms | ion-conductive materials ionic liquids lyotropic liquid crystals nanochannels zwitterionic compounds |
Title | Ion-Conductive Nanostructured Polymer Films Formed by Photopolymerization of Lyotropic Columnar Liquid-Crystalline Monomers, Composed of a Zwitterionic Compound and a Protic Ionic Liquid |
URI | https://doaj.org/article/9e0b806d8c00429ebd228e47f3f27228 |
Volume | 10 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrZ1La9wwEMdFyak9lD5p-kKH0lNFZFkvH9OlS1KSsocGQi9GT2pIrMTrpexXy6frjL0tm1MvPRiM9UD2DH_NGOknQj4Yz1Ny3rIssmFSZs5s0pqpXDXKNyaJgPudz7_pkwv59VJd7h31hWvCZjzw_OGOmsS95TraMGln8lEIm6TJdRYGbif1rdReMjVpsNHcmGqGataQ1x-FYbseEY8GeZi-NwntsfqnSWX5hDzeRYP0eB7FU_Ig9c_Ioz1G4HNyd1p6tig9cllBmSjIYZmhr5shRboqV9vrNNBld3W9pkuIQOGh39LVzzLi-QdYuNtqSUumZ9syDuWmC3SBstS7gZ51t5susgWO3CGhO9Fz3OkAceEninJR1tAltHX0x68ON__gL9wwF236SB1edDUUeAl6OpXNfb4gF8sv3xcnbHfgAguS25Eh7IvLKlkdauNERvKOAgWwDSRmPmcnoV4ThRLRZcTiROV0nRxEARJRVPVLctCXPr0iVOnGc1-bZHMFrWqvfJJQMyjpeAz2kHz8Y4H2ZuZqtJCPoKnae6Y6JJ_RPn8rIQ57egBO0u6cpP2Xk7z-H528IQ8FJtvTsp235ABMnd5BRDL695Pz_QZHL-LO |
link.rule.ids | 315,786,790,870,2115,27955,27956 |
linkProvider | Directory of Open Access Journals |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Ion-Conductive+Nanostructured+Polymer+Films+Formed+by+Photopolymerization+of+Lyotropic+Columnar+Liquid-Crystalline+Monomers%2C+Composed+of+a+Zwitterionic+Compound+and+a+Protic+Ionic+Liquid&rft.jtitle=Crystals+%28Basel%29&rft.au=Siyu+Cao&rft.au=Masafumi+Yoshio&rft.au=Atsushi+Seki&rft.date=2020-04-01&rft.pub=MDPI+AG&rft.eissn=2073-4352&rft.volume=10&rft.issue=4&rft.spage=276&rft_id=info:doi/10.3390%2Fcryst10040276&rft.externalDBID=DOA&rft.externalDocID=oai_doaj_org_article_9e0b806d8c00429ebd228e47f3f27228 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2073-4352&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2073-4352&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2073-4352&client=summon |