Rechargeable nickel–iron batteries for large-scale energy storage

This study reports the effect of iron sulphide and copper composites on the electrochemical performance of nickel–iron batteries. Nickel stripes were coated with an iron-rich electroactive paste and were cycled against commercial nickel electrodes. The electrodes electrochemical and physical charact...

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Published inIET renewable power generation Vol. 10; no. 10; pp. 1529 - 1534
Main Authors Abdalla, Abdallah H, Oseghale, Charles I, Gil Posada, Jorge O, Hall, Peter J
Format Journal Article
LanguageEnglish
Published The Institution of Engineering and Technology 01.11.2016
Subjects
atomic force microscopy
atomic force microscopy techniques
commercial nickel electrodes
composite materials
Copper
copper composites
cyclic voltammetry
Electric batteries
electrochemical electrodes
electrochemical performance
electrode electrochemical characterisation
Electrodes
Energy storage
FeS2
galvanostatic charge‐discharge
grid energy storage
Iron
iron compounds
iron sulphide effect
iron‐based electrodes
iron‐rich electroactive paste
large‐scale energy storage
Nickel
nickel stripes
Ni‐Fe
Rechargeable batteries
rechargeable nickel‐iron batteries
secondary cells
Special Issue: Selected Papers from the Offshore Energy & Storage Symposium (OSES 2015)
Sulfides
voltammetry (chemical analysis)
X‐ray diffraction
copper composites
X-ray diffraction
iron compounds
Cu
voltammetry (chemical analysis)
nickel stripes
secondary cells
copper
electrode electrochemical characterisation
rechargeable nickel-iron batteries
iron sulphide effect
iron-based electrodes
composite materials
nickel
electrochemical electrodes
atomic force microscopy techniques
Ni-Fe
atomic force microscopy
commercial nickel electrodes
grid energy storage
large-scale energy storage
cyclic voltammetry
galvanostatic charge-discharge
iron
iron-rich electroactive paste
electrochemical performance
FeS2
Online AccessGet full text

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Abstract This study reports the effect of iron sulphide and copper composites on the electrochemical performance of nickel–iron batteries. Nickel stripes were coated with an iron-rich electroactive paste and were cycled against commercial nickel electrodes. The electrodes electrochemical and physical characterisation were carried out by using galvanostatic charge/discharge, cyclic voltammetry, X-ray diffraction, and atomic force microscopy techniques. The authors’ experimental results would indicate that the addition of iron sulphide and copper (II) sulphate significantly enhances the performance of the battery. Their in-house made iron-based electrodes exhibit good performance, with great potential for grid energy storage applications.
AbstractList This study reports the effect of iron sulphide and copper composites on the electrochemical performance of nickel-iron batteries. Nickel stripes were coated with an iron-rich electroactive paste and were cycled against commercial nickel electrodes. The electrodes electrochemical and physical characterisation were carried out by using galvanostatic charge/discharge, cyclic voltammetry, X-ray diffraction, and atomic force microscopy techniques. The authors' experimental results would indicate that the addition of iron sulphide and copper (II) sulphate significantly enhances the performance of the battery. Their in-house made iron-based electrodes exhibit good performance, with great potential for grid energy storage applications.
Author Oseghale, Charles I
Abdalla, Abdallah H
Gil Posada, Jorge O
Hall, Peter J
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  givenname: Peter J
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  fullname: Hall, Peter J
  email: peter.hall@sheffield.ac.uk
  organization: Department of Chemical and Biological Engineering, Faculty of Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
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Issue 10
Keywords copper composites
X-ray diffraction
iron compounds
Cu
voltammetry (chemical analysis)
nickel stripes
secondary cells
copper
electrode electrochemical characterisation
rechargeable nickel-iron batteries
iron sulphide effect
iron-based electrodes
composite materials
nickel
electrochemical electrodes
atomic force microscopy techniques
Ni-Fe
atomic force microscopy
commercial nickel electrodes
grid energy storage
large-scale energy storage
cyclic voltammetry
galvanostatic charge-discharge
iron
iron-rich electroactive paste
electrochemical performance
FeS2
Language English
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Snippet This study reports the effect of iron sulphide and copper composites on the electrochemical performance of nickel–iron batteries. Nickel stripes were coated...
This study reports the effect of iron sulphide and copper composites on the electrochemical performance of nickel-iron batteries. Nickel stripes were coated...
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SubjectTerms atomic force microscopy
atomic force microscopy techniques
commercial nickel electrodes
composite materials
Copper
copper composites
cyclic voltammetry
Electric batteries
electrochemical electrodes
electrochemical performance
electrode electrochemical characterisation
Electrodes
Energy storage
FeS2
galvanostatic charge‐discharge
grid energy storage
Iron
iron compounds
iron sulphide effect
iron‐based electrodes
iron‐rich electroactive paste
large‐scale energy storage
Nickel
nickel stripes
Ni‐Fe
Rechargeable batteries
rechargeable nickel‐iron batteries
secondary cells
Special Issue: Selected Papers from the Offshore Energy & Storage Symposium (OSES 2015)
Sulfides
voltammetry (chemical analysis)
X‐ray diffraction
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Title Rechargeable nickel–iron batteries for large-scale energy storage
URI http://digital-library.theiet.org/content/journals/10.1049/iet-rpg.2016.0051
https://onlinelibrary.wiley.com/doi/abs/10.1049%2Fiet-rpg.2016.0051
https://www.proquest.com/docview/1868317717
https://www.proquest.com/docview/1879986318
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