Sorption Behavior of Selected Aldehyde-scavenging Agents in Poly(ethylene terephthalate) Blends
Poly(m-xylylene adipamide) (nylon MXD6), D-sorbitol, and a-cyclodextrin aldehyde-scavenging agents were blended with poly(ethylene terephthalate) and thermally pressed into films. Films were stored in an acidified aqueous model solution (pH 3.6) containing a 25 μM mixture of acetaldehyde, propionald...
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| Published in | Journal of food science Vol. 68; no. 6; pp. 2028 - 2033 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Oxford, UK
Blackwell Publishing Ltd
01.08.2003
Wiley Subscription Services, Inc |
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| Abstract | Poly(m-xylylene adipamide) (nylon MXD6), D-sorbitol, and a-cyclodextrin aldehyde-scavenging agents were blended with poly(ethylene terephthalate) and thermally pressed into films. Films were stored in an acidified aqueous model solution (pH 3.6) containing a 25 μM mixture of acetaldehyde, propionaldehyde, butyraldehyde, valeraldehyde, and caproaldehyde for 1, 3, 7, and 14 d. The total amount of aldehydes sorbed by films was 2 to 10 times higher for films containing aldehyde-scavenging agents than nonblended films. Aldehyde-scavenging films demonstrated selective scalping, preferring smaller molecular weight aldehydes to larger aldehydes. Partition coefficients for smaller aldehydes were 3 to 6 times greater for aldehyde-scavenging films than control film. |
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| AbstractList | Poly(m-xylylene adipamide) (nylon MXD6), D-sorbitol, and a-cyclodextrin aldehyde-scavenging agents were blended with poly(ethylene terephthalate) and thermally pressed into films. Films were stored in an acidified aqueous model solution (pH 3.6) containing a 25 mM mixture of acetaldehyde, propionaldehyde, butyraldehyde, valeraldehyde, and caproaldehyde for 1, 3, 7, and 14 d. The total amount of aldehydes sorbed by films was 2 to 10 times higher for films containing aldehyde-scavenging agents than nonblended films. Aldehyde-scavenging films demonstrated selective scalping, preferring smaller molecular weight aldehydes to larger aldehydes. Partition coefficients for smaller aldehydes were 3 to 6 times greater for aldehyde-scavenging films than control film. [PUBLICATION ABSTRACT] Poly(m‐xylylene adipamide) (nylon MXD6), D‐sorbitol, and a‐cyclodextrin aldehyde‐scavenging agents were blended with poly(ethylene terephthalate) and thermally pressed into films. Films were stored in an acidified aqueous model solution (pH 3.6) containing a 25 μM mixture of acetaldehyde, propionaldehyde, butyraldehyde, valeraldehyde, and caproaldehyde for 1, 3, 7, and 14 d. The total amount of aldehydes sorbed by films was 2 to 10 times higher for films containing aldehyde‐scavenging agents than nonblended films. Aldehyde‐scavenging films demonstrated selective scalping, preferring smaller molecular weight aldehydes to larger aldehydes. Partition coefficients for smaller aldehydes were 3 to 6 times greater for aldehyde‐scavenging films than control film. |
| Author | Long, T.E. Marcy, J.E. Duncan, S.E. Suloff, E.C. O'Keefe, S.F. Blakistone, B.A. |
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| Notes | http://dx.doi.org/10.1111/j.1365-2621.2003.tb07013.x ark:/67375/WNG-PZ6SWTTH-5 ArticleID:JFDS2028 istex:FDAA6AC0133440AE76FEA3D0C97E20ECCFA9B8C7 The authors wish to thank Micromeritics Instrument Co. for their density analysis of polymeric materials. This work was supported by Dairy Management Inc. and the Center for Advanced Processing and Packaging Studies (NSF grant nr EEC‐9900456). |
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| References_xml | – year: 2000 March 28 – volume: 49 start-page: 669 year: 2001 end-page: 74 article-title: Flavor, color, and vitamin C retention of pulsed electric field processed orange juice in different packaging materials publication-title: J Agric Food Chem – volume: 348 start-page: 22 year: 1999 end-page: 9 article-title: Porosity measurements by a gas penetration method and other techniques applied to membrane characterization publication-title: Thin Solid Films – volume: 67 start-page: 2687 year: 2002 end-page: 91 article-title: Modeling of hexanal sorption kinetic in an aldehydes scavenging film intended for food packaging applications publication-title: J Food Sci – year: 2000 Oct 24 – volume: 57 start-page: 1408 year: 1992 end-page: 11 article-title: Absorption of aroma volatiles of orange juice into laminated carton packages did not affect sensory quality publication-title: J Food Sci – year: 1989 June 6 – start-page: 263 year: 1978 end-page: 5 – year: 1993 Jan 5 – year: 2001 Jan 4 – volume: 42 start-page: 1694 year: 2002 end-page: 709 article-title: Blends of a bottle‐grade polyethylene terephthalate copolymer with a liquid crystalline polymer. 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| Snippet | Poly(m-xylylene adipamide) (nylon MXD6), D-sorbitol, and a-cyclodextrin aldehyde-scavenging agents were blended with poly(ethylene terephthalate) and thermally... Poly(m‐xylylene adipamide) (nylon MXD6), D‐sorbitol, and a‐cyclodextrin aldehyde‐scavenging agents were blended with poly(ethylene terephthalate) and thermally... |
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| SubjectTerms | active packaging aldehydes ethylene Food packaging Food science molecular weight nylon partition coefficients scalping scavenging sorbitol sorption |
| Title | Sorption Behavior of Selected Aldehyde-scavenging Agents in Poly(ethylene terephthalate) Blends |
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