Development of high-performance networked polymers based on cyclotrimerization of isocyanates: Control of properties by addition of monoisocyanates

Highly heat‐resistant networked polymers consisting of isocyanurate moieties have been developed based on cyclotrimerization of isocyanates. To the polymerization system using methylene diphenyl 4,4′‐diisocyanate (MDI) as the main component, a series of aromatic monoisocyanates (p‐tolylisocyanate, p...

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Published inJournal of polymer science. Part A, Polymer chemistry Vol. 50; no. 20; pp. 4365 - 4367
Main Authors Moritsugu, Masaki, Sudo, Atsushi, Endo, Takeshi
Format Journal Article
LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc., A Wiley Company 15.10.2012
Wiley
Subjects
Applied sciences
Copolymerization
cyclopolymerization
Exact sciences and technology
high performance polymers
isocyanurate
networks
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
Substituent effect
isocyanurate
Organic isocyanate
Fluorine containing copolymer
Cyclopolymerization
Composition effect
Experimental study
networks
Triazine derivative copolymer
Thermal stability
Crosslinked copolymer
Cyclopolymer
Organic diisocyanate
Preparation
high performance polymers
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Abstract Highly heat‐resistant networked polymers consisting of isocyanurate moieties have been developed based on cyclotrimerization of isocyanates. To the polymerization system using methylene diphenyl 4,4′‐diisocyanate (MDI) as the main component, a series of aromatic monoisocyanates (p‐tolylisocyanate, p‐trifluoromethylphenylisocyanate, p‐tert‐butylphenylisocyanate, and p‐butylphenylisocyanate) were added with varying feed ratio [MDI]0:[monoisocyanate]0 to achieve successful control of flexibility of thecorresponding networked polymers without serious deterioration of the thermal stability.
AbstractList Highly heat‐resistant networked polymers consisting of isocyanurate moieties have been developed based on cyclotrimerization of isocyanates. To the polymerization system using methylene diphenyl 4,4′‐diisocyanate (MDI) as the main component, a series of aromatic monoisocyanates (p‐tolylisocyanate, p‐trifluoromethylphenylisocyanate, p‐tert‐butylphenylisocyanate, and p‐butylphenylisocyanate) were added with varying feed ratio [MDI]0:[monoisocyanate]0 to achieve successful control of flexibility of thecorresponding networked polymers without serious deterioration of the thermal stability.
Author Endo, Takeshi
Moritsugu, Masaki
Sudo, Atsushi
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  surname: Endo
  fullname: Endo, Takeshi
  email: tendo@moleng.fuk.kindai.ac.jp
  organization: Molecular Engineering Institute, Kinki University, 11-6 Kayanomori, Iizuka, Fukuoka 820-8555, Japan
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Cites_doi 10.1177/0021955X7501100608
10.1002/app.1985.070301112
10.1021/ma00175a006
10.1021/ma00003a005
10.1021/ma50006a056
10.1063/1.481809
10.1016/0014-3057(82)90059-3
10.1002/pola.24987
10.1016/0014-3057(80)90112-3
10.1021/ja01600a027
10.1021/ma00214a008
10.1002/pat.327
10.1016/0014-3057(81)90207-X
10.1080/00222340500251139
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Issue 20
Keywords Substituent effect
isocyanurate
Organic isocyanate
Fluorine containing copolymer
Cyclopolymerization
Composition effect
Experimental study
networks
Triazine derivative copolymer
Thermal stability
Crosslinked copolymer
Cyclopolymer
Organic diisocyanate
Preparation
high performance polymers
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Snippet Highly heat‐resistant networked polymers consisting of isocyanurate moieties have been developed based on cyclotrimerization of isocyanates. To the...
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SubjectTerms Applied sciences
Copolymerization
cyclopolymerization
Exact sciences and technology
high performance polymers
isocyanurate
networks
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
Title Development of high-performance networked polymers based on cyclotrimerization of isocyanates: Control of properties by addition of monoisocyanates
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