Structural comparison in a series of 3,5-bis(2-pyridyl)pyrazolato bridged Ln(III)–Cr(III) dinuclear complexes

• Published in: Journal of alloys and compounds Vol. 408; pp. 976 - 980
• Main Authors: Kawahata, Ryouji, Tsukuda, Toshiaki, Yagi, Takashi, Fuyuhiro, Akira, Kaizaki, Sumio
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 09.02.2006
• Subjects: Ln–Cr dinuclear complexes; Structural parameters; X-ray structures; Ln–Cr dinuclear complexes; X-ray structures; Structural parameters

The novel Ln III ion size dependent structural transformation round Ln III in a series of discrete [(hfac) 3Ln(μ-bpypz)Cr(acac) 2] dinuclear complexes is examined in comparison with the structural parameters in relation to the lanthanide(III) ion radius.