Sterically congested boronate and silane synthesis via electronically controlled protoboration and protosilylation

• Published in: Cell reports physical science Vol. 2; no. 6; p. 100461
• Main Authors: Wang, Cheng-Qiang, Li, Yi, Feng, Chao
• Format: Journal Article
• Language: English
• Published: Elsevier Inc 01.06.2021; Elsevier
• Subjects: fluorine effects; gem-difluoroallenes; protoboration/silylation; reversed regioselectivity; tertiary boronates/silanes; gem-difluoroallenes; fluorine effects; reversed regioselectivity; tertiary boronates/silanes; protoboration/silylation

Multi-functionalized tertiary/secondary boronates and silanes have found wide applications in areas spanning organic synthesis, advanced material development, and pharmaceutical research. Effective access to these versatile motifs via protoboration/silylation of allenes remains unfulfilled. Capitali...