Claisen rearrangement/Baylis–Hillman reaction/ring-closing metathesis as bases for the construction of substituted cyanonaphthalenes

The present paper described how to establish a novel approach for various alkoxycyanonaphthalenes. It was started from isovanillin, and based on the Claisen rearrangement, O-alkylation, the Baylis–Hillman reaction, and ring-closing metathesis in sequence to produce the title compounds in good yield....

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Bibliographic Details
Published inTetrahedron Vol. 63; no. 13; pp. 2824 - 2828
Main Authors Chen, Po-Yuan, Chen, Hsing-Ming, Chen, Liang-Yeu, Tzeng, Jing-Yu, Tsai, Jui-Chi, Chi, Ping-Cheng, Li, Sie-Rong, Wang, Eng-Chi
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 26.03.2007
Elsevier
Subjects
Chemistry
Chemistry, Organic
Claisen rearrangement
Cyanonaphthalenes
Physical Sciences
Ring-closing metathesis
Science & Technology
Ring-closing metathesis
Cyanonaphthalenes
Claisen rearrangement
cyanonaphthalenes
CYANATION
LIGNANS
INHIBITORS
DERIVATIVES
NEOLIGNANS
ring-closing metathesis
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Summary:The present paper described how to establish a novel approach for various alkoxycyanonaphthalenes. It was started from isovanillin, and based on the Claisen rearrangement, O-alkylation, the Baylis–Hillman reaction, and ring-closing metathesis in sequence to produce the title compounds in good yield. [Display omitted]
ISSN:0040-4020
1464-5416
DOI:10.1016/j.tet.2007.01.054