The Chemical-Mineralogical Characterization of Recycled Concrete Aggregates from Different Sources and Their Potential Reactions in Asphalt Mixtures

The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product’s properties, such as chemical stability. This stu...

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Published inMaterials Vol. 13; no. 24; p. 5592
Main Authors Sánchez-Cotte, Edgar H., Pacheco-Bustos, Carlos Albeiro, Fonseca, Ana, Triana, Yaneth Pineda, Mercado, Ronald, Yepes-Martínez, Julián, Lagares Espinoza, Ricardo Gabriel
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 08.12.2020
MDPI
Subjects
Aggregates
Aging
Aluminum oxide
Asphalt mixes
Asphalt pavements
Atomic absorption analysis
Atomic beam spectroscopy
Calcite
Calcium carbonate
Cement
Chemical potential
Chemical properties
Concrete aggregates
Concrete construction
Concrete pavements
Corrosion resistance
Demolition
Laboratories
Mineralogy
Nitration
Nitrogen dioxide
Organic compounds
Portland cements
Potassium
Recycled materials
Rehabilitation
Road construction
Scientific imaging
Silicon dioxide
Stability analysis
X-ray fluorescence
chemical characterization
natural aggregates (NA)
recycled concrete aggregate (RCA)
Online AccessGet full text
ISSN1996-1944
1996-1944
DOI10.3390/ma13245592

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Abstract The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product’s properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building—RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement—RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs’ coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO2) and calcite (CaCO3) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al2O3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO2, (–SO3H), (–SO2Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.
AbstractList The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product’s properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building—RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement—RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs’ coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO2) and calcite (CaCO3) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al2O3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO2, (–SO3H), (–SO2Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.
The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product's properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building-RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement-RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs' coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO ) and calcite (CaCO ) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al O concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO , (-SO H), (-SO Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.
The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product's properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building-RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement-RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs' coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO2) and calcite (CaCO3) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al2O3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO2, (-SO3H), (-SO2Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product's properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building-RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement-RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs' coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO2) and calcite (CaCO3) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al2O3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO2, (-SO3H), (-SO2Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.
The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent research. This tendency promotes sustainability, but its use depends mainly on the final product’s properties, such as chemical stability. This study evaluates the physical and chemical properties of RCAs from two different sources in comparison with the performance of NA. One RCA was obtained from the demolition of a building (recycled concrete aggregate of a building—RCAB) and another RCA from the rehabilitation of a Portland cement concrete pavement (recycled concrete aggregate from a pavement—RCAP). Characterization techniques such as X-ray fluorescence (XRF), X-ray diffraction (XRD), UV spectroscopy, and atomic absorption spectrometry were used to evaluate the RCAs’ coarse fractions for chemical potential effects on asphalt mixtures. NA was replaced with RCA at 15%, 30%, and 45% for each size of the coarse fractions (retained 19.0, 12.5, 9.5, and 4.75 sieves in mm). The mineralogical characterization results indicated the presence of quartz (SiO 2 ) and calcite (CaCO 3 ) as the most significant constituents of the aggregates. XFR showed that RCAs have lower levels of CaO and Al 2 O 3 concerning NA. Potential reactions in asphalt mixtures by nitration, sulfonation, amination of organic compounds, and reactions by alkaline activation in the aggregates were discarded due to the minimum concentration of components such as NO 2 , (–SO 3 H), (–SO 2 Cl), and (Na) in the aggregates. Finally, this research concludes that studied RCAs might be used as replacements of coarse aggregate in asphalt mixtures since chemical properties do not affect the overall chemical stability of the asphalt mixture.
Author Pacheco-Bustos, Carlos Albeiro
Sánchez-Cotte, Edgar H.
Fonseca, Ana
Lagares Espinoza, Ricardo Gabriel
Triana, Yaneth Pineda
Mercado, Ronald
Yepes-Martínez, Julián
AuthorAffiliation 3 Facultad de Ingeniería, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte 39-115, Tunja 150003, Colombia; yaneth.pineda@uptc.edu.co
2 División de Ingeniería, Universidad del Norte-km 5 Vía Puerto Colombia, Barranquilla, Colombia; cbustosa@uninorte.edu.co (C.A.P.-B.); fonsecama@uninorte.edu.co (A.F.); lagaresr@uninorte.edu.co (R.G.L.E.)
4 Grupo de Investigación en Fenómenos Interfaciales, Reología y Simulación de Transporte (FIRST), Universidad Industrial de Santander, Cl. 9 Bucaramanga, Cra 27 Santander, Bucaramanga, Colombia; ramerca@uis.edu.co
1 Facultad Tecnológica, Universidad Distrital Francisco José de Caldas, Cl. 68D Bis A Sur, Bogotá 49F-70, Colombia; esanchez@udistrital.edu.co
AuthorAffiliation_xml – name: 3 Facultad de Ingeniería, Universidad Pedagógica y Tecnológica de Colombia, Avenida Central del Norte 39-115, Tunja 150003, Colombia; yaneth.pineda@uptc.edu.co
– name: 4 Grupo de Investigación en Fenómenos Interfaciales, Reología y Simulación de Transporte (FIRST), Universidad Industrial de Santander, Cl. 9 Bucaramanga, Cra 27 Santander, Bucaramanga, Colombia; ramerca@uis.edu.co
– name: 2 División de Ingeniería, Universidad del Norte-km 5 Vía Puerto Colombia, Barranquilla, Colombia; cbustosa@uninorte.edu.co (C.A.P.-B.); fonsecama@uninorte.edu.co (A.F.); lagaresr@uninorte.edu.co (R.G.L.E.)
– name: 1 Facultad Tecnológica, Universidad Distrital Francisco José de Caldas, Cl. 68D Bis A Sur, Bogotá 49F-70, Colombia; esanchez@udistrital.edu.co
Author_xml – sequence: 1
  givenname: Edgar H.
  surname: Sánchez-Cotte
  fullname: Sánchez-Cotte, Edgar H.
– sequence: 2
  givenname: Carlos Albeiro
  surname: Pacheco-Bustos
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  givenname: Ana
  surname: Fonseca
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  surname: Yepes-Martínez
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  givenname: Ricardo Gabriel
  surname: Lagares Espinoza
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/33302415$$D View this record in MEDLINE/PubMed
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Keywords chemical characterization
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Snippet The incorporation of a recycled concrete aggregate (RCA) as a replacement of natural aggregates (NA) in road construction has been the subject of recent...
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StartPage 5592
SubjectTerms Aggregates
Aging
Aluminum oxide
Asphalt mixes
Asphalt pavements
Atomic absorption analysis
Atomic beam spectroscopy
Calcite
Calcium carbonate
Cement
Chemical potential
Chemical properties
Concrete aggregates
Concrete construction
Concrete pavements
Corrosion resistance
Demolition
Laboratories
Mineralogy
Nitration
Nitrogen dioxide
Organic compounds
Portland cements
Potassium
Recycled materials
Rehabilitation
Road construction
Scientific imaging
Silicon dioxide
Stability analysis
X-ray fluorescence
Title The Chemical-Mineralogical Characterization of Recycled Concrete Aggregates from Different Sources and Their Potential Reactions in Asphalt Mixtures
URI https://www.ncbi.nlm.nih.gov/pubmed/33302415
https://www.proquest.com/docview/2469688637
https://www.proquest.com/docview/2473404461
https://pubmed.ncbi.nlm.nih.gov/PMC7762571
Volume 13
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