Recent progress on synthesis of ZIF-67-based materials and their application to heterogeneous catalysis

In recent years, an increasing amount of interest has been dedicated to the synthesis and application of ZIF-67-based materials due to their exceptionally high surface area, tunable porosity, and excellent thermal and chemical stabilities. This review summarizes the latest strategies of synthesizing...

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Published inGreen energy & environment Vol. 7; no. 1; pp. 3 - 15
Main Authors Duan, Chongxiong, Yu, Yi, Hu, Han
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.02.2022
KeAi Communications Co., Ltd
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Abstract In recent years, an increasing amount of interest has been dedicated to the synthesis and application of ZIF-67-based materials due to their exceptionally high surface area, tunable porosity, and excellent thermal and chemical stabilities. This review summarizes the latest strategies of synthesizing ZIF-67-based materials by exploring the prominent examples. Then, the recent progress in the applications of ZIF-67-based materials in heterogeneous catalysis, including catalysis of the redox reactions, addition reactions, esterification reactions, Knoevenagel condensations, and hydrogenation–dehydrogenation reactions, has been elaborately discussed. Finally, we end this work by shedding some light on the large-scale industrial production of ZIF-67-based materials and their applications in the future. In this review, we discuss various strategies for the preparation of ZIF-67-based materials including the solvothermal method, surfactant-assisted method, sol–gel method, and microwave/ultrasound-assisted method. We also discuss the applications of ZIF-67-based materials in heterogeneous catalysis fields including the redox reactions, addition reactions, esterifications, Knoevenagel condensations, and hydrogenation–dehydrogenation reactions. [Display omitted]
AbstractList In recent years, an increasing amount of interest has been dedicated to the synthesis and application of ZIF-67-based materials due to their exceptionally high surface area, tunable porosity, and excellent thermal and chemical stabilities. This review summarizes the latest strategies of synthesizing ZIF-67-based materials by exploring the prominent examples. Then, the recent progress in the applications of ZIF-67-based materials in heterogeneous catalysis, including catalysis of the redox reactions, addition reactions, esterification reactions, Knoevenagel condensations, and hydrogenation–dehydrogenation reactions, has been elaborately discussed. Finally, we end this work by shedding some light on the large-scale industrial production of ZIF-67-based materials and their applications in the future. In this review, we discuss various strategies for the preparation of ZIF-67-based materials including the solvothermal method, surfactant-assisted method, sol–gel method, and microwave/ultrasound-assisted method. We also discuss the applications of ZIF-67-based materials in heterogeneous catalysis fields including the redox reactions, addition reactions, esterifications, Knoevenagel condensations, and hydrogenation–dehydrogenation reactions. [Display omitted]
In recent years, an increasing amount of interest has been dedicated to the synthesis and application of ZIF-67-based materials due to their exceptionally high surface area, tunable porosity, and excellent thermal and chemical stabilities. This review summarizes the latest strategies of synthesizing ZIF-67-based materials by exploring the prominent examples. Then, the recent progress in the applications of ZIF-67-based materials in heterogeneous catalysis, including catalysis of the redox reactions, addition reactions, esterification reactions, Knoevenagel condensations, and hydrogenation–dehydrogenation reactions, has been elaborately discussed. Finally, we end this work by shedding some light on the large-scale industrial production of ZIF-67-based materials and their applications in the future.
Author Yu, Yi
Duan, Chongxiong
Hu, Han
Author_xml – sequence: 1
  givenname: Chongxiong
  orcidid: 0000-0002-2257-190X
  surname: Duan
  fullname: Duan, Chongxiong
  organization: State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580, China
– sequence: 2
  givenname: Yi
  surname: Yu
  fullname: Yu, Yi
  email: ceyuicy526@mail.scut.edu.cn
  organization: School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, China
– sequence: 3
  givenname: Han
  surname: Hu
  fullname: Hu, Han
  email: hhu@upc.edu.cn
  organization: State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, Institute of New Energy, China University of Petroleum (East China), Qingdao, 266580, China
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Keywords Heterogeneous catalysis
Zeolitic imidazolate framework-67
Synthetic methods
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SubjectTerms Heterogeneous catalysis
Synthetic methods
Zeolitic imidazolate framework-67
Title Recent progress on synthesis of ZIF-67-based materials and their application to heterogeneous catalysis
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