Unprecedented Charge Transfer Induced Spin Transition in an Fe-Os Cluster

High 'n low: The novel {[Fe(tmphen)2]3[Os(CN)6]2} complex (see structure) is the first example of a cluster in which a high‐spin FeIII ion is in a coordination environment of four imine nitrogen atoms and two N‐coordinated cyanides. Magnetic studies reveal an unprecedented type of reversible ch...

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Published in	Angewandte Chemie (International ed.) Vol. 49; no. 8; pp. 1410 - 1413
Main Authors	Hilfiger, Matthew G, Chen, Meimei, Brinzari, Tatiana V, Nocera, Tanya M, Shatruk, Michael, Petasis, Doros T, Musfeldt, Janice L, Achim, Catalina, Dunbar, Kim R
Format	Journal Article
Language	English
Published	Weinheim Wiley-VCH Verlag 15.02.2010 WILEY-VCH Verlag WILEY‐VCH Verlag
Subjects	charge transfer cyanide ligand iron complexes spin crossover spin transition
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Abstract	High 'n low: The novel {[Fe(tmphen)2]3[Os(CN)6]2} complex (see structure) is the first example of a cluster in which a high‐spin FeIII ion is in a coordination environment of four imine nitrogen atoms and two N‐coordinated cyanides. Magnetic studies reveal an unprecedented type of reversible charge transfer induced spin transition (CTIST) between the low‐spin FeIINCOsIII and high‐spin FeIIINCOsII systems.
AbstractList	High 'n low: The novel {[Fe(tmphen)2]3[Os(CN)6]2} complex (see structure) is the first example of a cluster in which a high‐spin FeIII ion is in a coordination environment of four imine nitrogen atoms and two N‐coordinated cyanides. Magnetic studies reveal an unprecedented type of reversible charge transfer induced spin transition (CTIST) between the low‐spin FeIINCOsIII and high‐spin FeIIINCOsII systems.
Author	Shatruk, Michael Hilfiger, Matthew G. Chen, Meimei Brinzari, Tatiana V. Petasis, Doros T. Nocera, Tanya M. Dunbar, Kim R. Musfeldt, Janice L. Achim, Catalina
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BackLink	https://www.ncbi.nlm.nih.gov/pubmed/20084656$$D View this record in MEDLINE/PubMed
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Notes	http://dx.doi.org/10.1002/anie.200906264 istex:DFACD71225C8AFB41040B219DD7A74CBA7499B15 ACS-PRF - No. AC3-44200 ArticleID:ANIE200906264 ark:/67375/WNG-7G6K46KZ-S The authors acknowledge Carolina Avendaño for useful discussions. This research was supported by the National Science Foundation (CHE-0610019 to K.R.D., DMR-0600089 to J.L.M.), the Department of Energy (DE-FG03-02ER45999 to K.R.D.) and the ACS-PRF Fund (AC3-44200 to C.A.). Crystallographic parameters can be found in the Supporting Information (Table S4) and cif files under CSD numbers 753301 and 753302. Department of Energy - No. DE-FG03-02ER45999 National Science Foundation - No. CHE-0610019; No. DMR-0600089 The authors acknowledge Carolina Avendaño for useful discussions. This research was supported by the National Science Foundation (CHE‐0610019 to K.R.D., DMR‐0600089 to J.L.M.), the Department of Energy (DE‐FG03‐02ER45999 to K.R.D.) and the ACS‐PRF Fund (AC3‐44200 to C.A.). Crystallographic parameters can be found in the Supporting Information (Table S4) and cif files under CSD numbers 753301 and 753302. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
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Snippet	High 'n low: The novel {[Fe(tmphen)2]3[Os(CN)6]2} complex (see structure) is the first example of a cluster in which a high‐spin FeIII ion is in a coordination...
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SubjectTerms	charge transfer cyanide ligand iron complexes spin crossover spin transition
Title	Unprecedented Charge Transfer Induced Spin Transition in an Fe-Os Cluster
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