Solidification/Stabilization of Chromium-Contaminated Soils by Polyurethane during Freeze–Thaw Cycles: Mechanical, Leaching and Microstructure Characterization

The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze–thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil...

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Published inMaterials Vol. 17; no. 6; p. 1347
Main Authors Ma, Qiang, Zheng, Pangkun, Chen, Junjie, Lu, Xuesong
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 15.03.2024
MDPI
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ISSN1996-1944
1996-1944
DOI10.3390/ma17061347

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Abstract The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze–thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze–thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze–thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China’s regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH3 and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze–thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
AbstractList The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze–thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze–thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze–thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China’s regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH3 and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze–thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze–thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze–thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze–thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China’s regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH 3 and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze–thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze-thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze-thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze-thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China's regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze-thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze–thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze–thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze–thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China’s regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH[sub.3] and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze–thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze-thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze-thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze-thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China's regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH3 and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze-thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material with excellent freeze-thaw resistance and abrasion resistance, has the potential to solidify Chromium-Contaminated soil in seasonal frozen soil areas. However, there is a lack of research on the mechanism of PU involved in solidifying/stabilizing chromium-contaminated soil in seasonal frozen regions from the perspective of pore structure and functional group coordination bonds. In this study, the leaching behavior of PU with different contents under different freeze-thaw cycles was analyzed, and the mechanism of PU in seasonal frozen regions was explored from the perspective of pores and functional groups by combining various microscopic characterization methods. The results show that PU can effectively resist the deterioration of chromium-contaminated soil after freeze-thaw cycles and can better prevent the harm of secondary leaching. The leaching concentration of chromium ion is only 1.09 mg/L, which is below China's regulatory limits. PU is beneficial for inhibiting the expansion of ice crystals in chromium-contaminated soil in seasonal frozen soil areas. PU solidifies chromium by physical encapsulation and complexation reactions. The amide functional groups, methyl-CH3 and isocyanate groups in PU play a leading role in the complexation with chromium. Although the freeze-thaw cycle will destroy the coordination bond between the PU functional group and chromium, chromium cannot break through the bond of PU film. This study confirmed the feasibility of using PU to solidify Chromium-Contaminated soil in seasonal frozen soil areas, which can provide research support and reference for in situ engineering in the future.
Audience Academic
Author Ma, Qiang
Chen, Junjie
Zheng, Pangkun
Lu, Xuesong
AuthorAffiliation 3 Huanggang Ecological Architecture and Renewable Resources Research Center, Huanggang 438000, China
2 Hubei Provincial Ecological Road Engineering Technology Research Center, Hubei University of Technology, Wuhan 430068, China; 102110933@hbut.edu.cn (P.Z.); chenghongliang@hbut.edu.cn (J.C.)
1 School of Architectural Engineering, Huanggang Normal University, Huanggang 438000, China; 20121012@hbut.edu.cn
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Issue 6
Keywords solidification/stabilization
soil porosity
toxicity leaching ability
freeze–thaw cycle
hexavalent chromium-contaminated soil
FTIR spectroscopy
Language English
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Snippet The treatment of chromium-contaminated soil in seasonal frozen soil areas has been the subject of recent interest. Polyurethane (PU), as a polymer material...
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SubjectTerms Abrasion resistance
Cement
Chromium
Complexation
Coordination
Curing
Environmental protection
Feasibility studies
Fourier transforms
Freeze thaw cycles
Freeze-thaw durability
Frozen ground
Functional groups
Heavy metals
Hydration
Ice crystals
In situ leaching
Isocyanates
Leaching
Leather industry
Mechanical properties
NMR
Nuclear magnetic resonance
Pollution
Polyurethane resins
Polyurethanes
Soil contamination
Soil mechanics
Soils
Solidification
Spectrum analysis
Temperature
Toxicity
Title Solidification/Stabilization of Chromium-Contaminated Soils by Polyurethane during Freeze–Thaw Cycles: Mechanical, Leaching and Microstructure Characterization
URI https://www.ncbi.nlm.nih.gov/pubmed/38541501
https://www.proquest.com/docview/3003338416
https://www.proquest.com/docview/3014009212
https://pubmed.ncbi.nlm.nih.gov/PMC10972329
Volume 17
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