Multicomponent macroporous materials with a controlled architecture

We describe the elaboration of organized macroporous electrode surfaces with a complex composition using the hard sphere template procedure. In a first approach, different metals are subsequently generated in the template leading finally to a multicomponent porous material showing interesting electr...

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Published inJournal of materials chemistry Vol. 19; no. 3; pp. 409 - 414
Main Authors SZAMOCKI, Rafael, MASSE, Pascal, RAVAINE, Serge, RAVAINE, Valerie, HEMPELMANN, Rolf, KUHN, Alexander
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 01.01.2009
Subjects
Chemical Sciences
Chemistry
Condensed Matter
Cross-disciplinary physics: materials science; rheology
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Material chemistry
Materials science
Materials synthesis; materials processing
Physics
Porous materials; granular materials
Soft Condensed Matter
Specific materials
Electrochemical properties
Porous materials
Template reaction
Electrode material
Surface composition
Sandwich structures
Defects
Hard-sphere model
Electrodes
Colloidal particles
Macroporous materials
Photonic crystal
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Abstract We describe the elaboration of organized macroporous electrode surfaces with a complex composition using the hard sphere template procedure. In a first approach, different metals are subsequently generated in the template leading finally to a multicomponent porous material showing interesting electrochemical features combining the redox properties of the different metals. In a complementary second approach, alternating porous and compact metal layers are formed, with the compact layer being introduced on purpose as a defect layer allowing the controlled destruction of the sandwich-type architecture using a chemical or electrochemical trigger.
AbstractList We describe the elaboration of organized macroporous electrode surfaces with a complex composition using the hard sphere template procedure. In a first approach, different metals are subsequently generated in the template leading finally to a multicomponent porous material showing interesting electrochemical features combining the redox properties of the different metals. In a complementary second approach, alternating porous and compact metal layers are formed, with the compact layer being introduced on purpose as a defect layer allowing the controlled destruction of the sandwich-type architecture using a chemical or electrochemical trigger.
Author SZAMOCKI, Rafael
RAVAINE, Serge
KUHN, Alexander
HEMPELMANN, Rolf
MASSE, Pascal
RAVAINE, Valerie
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  givenname: Rafael
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  givenname: Pascal
  surname: MASSE
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  givenname: Serge
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  fullname: RAVAINE, Serge
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  givenname: Valerie
  surname: RAVAINE
  fullname: RAVAINE, Valerie
  organization: University Bordeaux 1, CNRS, ISM, Ecole Nationale Supérieure de Chimie et Physique de Bordeaux, 16 avenue Pey Berland, 33607 Pessac, France
– sequence: 5
  givenname: Rolf
  surname: HEMPELMANN
  fullname: HEMPELMANN, Rolf
  organization: Physical Chemistry, Saarland University, 66123 Saarbrucken, Germany
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  givenname: Alexander
  surname: KUHN
  fullname: KUHN, Alexander
  organization: University Bordeaux 1, CNRS, ISM, Ecole Nationale Supérieure de Chimie et Physique de Bordeaux, 16 avenue Pey Berland, 33607 Pessac, France
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Issue 3
Keywords Electrochemical properties
Porous materials
Template reaction
Electrode material
Surface composition
Sandwich structures
Defects
Hard-sphere model
Electrodes
Colloidal particles
Macroporous materials
Photonic crystal
Language English
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Snippet We describe the elaboration of organized macroporous electrode surfaces with a complex composition using the hard sphere template procedure. In a first...
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SubjectTerms Chemical Sciences
Chemistry
Condensed Matter
Cross-disciplinary physics: materials science; rheology
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Material chemistry
Materials science
Materials synthesis; materials processing
Physics
Porous materials; granular materials
Soft Condensed Matter
Specific materials
Title Multicomponent macroporous materials with a controlled architecture
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