Noble Gases Influence the Conductance of Cetineite-Type Nanoporous Semiconductors

Recognizing nobility: The photoconduction of cetineites, crystalline nanoporous oxoselenoantimonates, is suppressed by the adsorption of noble gases. The gas uptake decreases with increasing atomic radius of the noble gas, leading to a smaller change in resistance upon adsorption. Thus, cetineites c...

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Published inAngewandte Chemie (International ed.) Vol. 46; no. 33; pp. 6372 - 6375
Main Authors Sendor, Dorota, Fokwa, Boniface P.T, Dronskowski, Richard, Simon, Ulrich
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 01.01.2007
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
electrical conductance
nanoporous materials
noble gases
semiconductors
X-ray diffraction
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Abstract Recognizing nobility: The photoconduction of cetineites, crystalline nanoporous oxoselenoantimonates, is suppressed by the adsorption of noble gases. The gas uptake decreases with increasing atomic radius of the noble gas, leading to a smaller change in resistance upon adsorption. Thus, cetineites can be applied in noble‐gas detection.
AbstractList Recognizing nobility: The photoconduction of cetineites, crystalline nanoporous oxoselenoantimonates, is suppressed by the adsorption of noble gases. The gas uptake decreases with increasing atomic radius of the noble gas, leading to a smaller change in resistance upon adsorption. Thus, cetineites can be applied in noble‐gas detection.
Author Sendor, Dorota
Dronskowski, Richard
Simon, Ulrich
Fokwa, Boniface P. T.
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10.1107/S0021889887086965
10.1126/science.1113247
10.1002/ange.200603075
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10.1002/ange.19971091018
10.1002/anie.199711211
10.1103/PhysRevB.61.15697
10.1002/anie.200351284
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We thank Claudia Klöser for the synthesis of the cetineites, Manfred Speldrich for help with the vacuum equipment, and Klaus Kruse for collecting the single-crystal diffraction data. D.S. gratefully acknowledges the Alexander von Humboldt Foundation (Roman Herzog-Forschungsstipendium) for the financial support of this work.
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We thank Claudia Klöser for the synthesis of the cetineites, Manfred Speldrich for help with the vacuum equipment, and Klaus Kruse for collecting the single‐crystal diffraction data. D.S. gratefully acknowledges the Alexander von Humboldt Foundation (Roman Herzog‐Forschungsstipendium) for the financial support of this work.
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Snippet Recognizing nobility: The photoconduction of cetineites, crystalline nanoporous oxoselenoantimonates, is suppressed by the adsorption of noble gases. The gas...
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SubjectTerms electrical conductance
nanoporous materials
noble gases
semiconductors
X-ray diffraction
Title Noble Gases Influence the Conductance of Cetineite-Type Nanoporous Semiconductors
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