Rooting out faulty adsorption models. Comment on “Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water”

This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory–Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-o...

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Published inThe Science of the total environment Vol. 921; p. 171118
Main Authors Chu, Khim Hoong, Hashim, Mohd Ali, Hayder, Gasim, Bollinger, Jean-Claude
Format Journal Article
LanguageEnglish
Published Netherlands Elsevier B.V 15.04.2024
Subjects
adsorption
Adsorption isotherm
Adsorption kinetics
cesium radioisotopes
Defective model
environment
Erroneous model
kinetics
magnetism
molybdenum disulfide
nanoparticles
nanosheets
sorption isotherms
Thermodynamic calculation
thermodynamics
Adsorption kinetics
Erroneous model
Defective model
Thermodynamic calculation
Adsorption isotherm
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Abstract This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory–Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper.
AbstractList This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory–Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper.
This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory-Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper.This correspondence critically examines and rectifies modeling deficiencies identified in a recent article published in this journal. Our analysis covers a range of models and issues, including the Temkin isotherm, the Flory-Huggins isotherm, the pseudo-first-order kinetic model, the pseudo-second-order kinetic model, the intraparticle diffusion model, the Elovich kinetic model, and the computation of thermodynamic parameters. The elucidation and correction of these modeling issues contribute to a more accurate and reliable understanding of the studied phenomena, thereby enhancing the scientific rigor of the subject paper.
ArticleNumber 171118
Author Bollinger, Jean-Claude
Hayder, Gasim
Hashim, Mohd Ali
Chu, Khim Hoong
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Cites_doi 10.1021/acs.iecr.2c03799
10.1006/jcht.1995.0001
10.1016/j.jclepro.2022.133632
10.1080/01496395.2016.1274327
10.1061/JSEDAI.0000430
10.1021/acs.iecr.1c01788
10.1038/134935a0
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10.1016/j.molliq.2020.113315
10.1016/j.scitotenv.2023.169365
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Keywords Adsorption kinetics
Erroneous model
Defective model
Thermodynamic calculation
Adsorption isotherm
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SubjectTerms adsorption
Adsorption isotherm
Adsorption kinetics
cesium radioisotopes
Defective model
environment
Erroneous model
kinetics
magnetism
molybdenum disulfide
nanoparticles
nanosheets
sorption isotherms
Thermodynamic calculation
thermodynamics
Title Rooting out faulty adsorption models. Comment on “Magnetic Prussian blue nanoshells are controllable (sic) anchored on the surface of molybdenum disulfide nanosheets for efficient separation of radioactive cesium from water”
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