Fundamental Chemistry of Cesium Extraction from Acidic Media by HCCD in FS-13
We previously published a model for cesium extraction from acidic media by the protonated form of the hexachlorinated derivative of the chloro-protected cobalt bis(dicarbollide), HCCD, dissolved in trifluoromethylphenyl sulfone, FS-13. The model indicated that Cs extraction proceeds through a series...
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| Published in | Solvent extraction and ion exchange Vol. 26; no. 2; pp. 163 - 174 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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United States
Taylor & Francis Group
01.03.2008
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| Abstract | We previously published a model for cesium extraction from acidic media by the protonated form of the hexachlorinated derivative of the chloro-protected cobalt bis(dicarbollide), HCCD, dissolved in trifluoromethylphenyl sulfone, FS-13. The model indicated that Cs extraction proceeds through a series of ion-paired and/or dissociated extraction equilibria. Additional Cs distribution ratio data has been obtained and the model refined and simplified. It is demonstrated that the equilibrium exclusively involving the exchange of proton for cesium by formation of ion-paired CsCCD models the Cs distribution data very well, particularly for the concentrations of HCCD greater than ∼0.0005 M (0.5 mM). Finally, activity corrections for the aqueous phase to the Cs distribution data results in good agreement to the theoretical value of −1 for slope (log-log) analysis of the data over a wide range of HNO
3
and HCCD concentrations. |
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| AbstractList | We previously published a model for cesium extraction from acidic media by the protonated form of the hexachlorinated derivative of the chloro-protected cobalt bis(dicarbollide), HCCD, dissolved in trifluoromethylphenyl sulfone, FS-13. The model indicated that Cs extraction proceeds through a series of ion-paired and/or dissociated extraction equilibria. Additional Cs distribution ratio data has been obtained and the model refined and simplified. It is demonstrated that the equilibrium exclusively involving the exchange of proton for cesium by formation of ion-paired CsCCD models the Cs distribution data very well, particularly for the concentrations of HCCD greater than ~0.0005M (0.5mM). Finally, activity corrections for the aqueous phase to the Cs distribution data results in good agreement to the theoretical value of -1 for slope (log-log) analysis of the data over a wide range of HNO3 and HCCD concentrations. We previously published a model for cesium extraction from acidic media by the protonated form of the hexachlorinated derivative of the chloro-protected cobalt bis(dicarbollide), HCCD, dissolved in trifluoromethylphenyl sulfone, FS-13. The model indicated that Cs extraction proceeds through a series of ion-paired and/or dissociated extraction equilibria. Additional Cs distribution ratio data has been obtained and the model refined and simplified. It is demonstrated that the equilibrium exclusively involving the exchange of proton for cesium by formation of ion-paired CsCCD models the Cs distribution data very well, particularly for the concentrations of HCCD greater than 0.0005 M (0.5 mM). Finally, activity corrections for the aqueous phase to the Cs distribution data results in good agreement to the theoretical value of -1 for slope (log-log) analysis of the data over a wide range of HNO3 and HCCD concentrations. We previously published a model for cesium extraction from acidic media by the protonated form of the hexachlorinated derivative of the chloro-protected cobalt bis(dicarbollide), HCCD, dissolved in trifluoromethylphenyl sulfone, FS-13. The model indicated that Cs extraction proceeds through a series of ion-paired and/or dissociated extraction equilibria. Additional Cs distribution ratio data has been obtained and the model refined and simplified. It is demonstrated that the equilibrium exclusively involving the exchange of proton for cesium by formation of ion-paired CsCCD models the Cs distribution data very well, particularly for the concentrations of HCCD greater than ∼0.0005 M (0.5 mM). Finally, activity corrections for the aqueous phase to the Cs distribution data results in good agreement to the theoretical value of −1 for slope (log-log) analysis of the data over a wide range of HNO 3 and HCCD concentrations. |
| Author | Peterman, Dean R. Delmau, Lætitia H. Tillotson, Richard D. Scott Herbst, R. |
| Author_xml | – sequence: 1 givenname: R. surname: Scott Herbst fullname: Scott Herbst, R. email: r.herbst@inl.gov organization: Idaho National Laboratory (INL) – sequence: 2 givenname: Dean R. surname: Peterman fullname: Peterman, Dean R. organization: Idaho National Laboratory (INL) – sequence: 3 givenname: Richard D. surname: Tillotson fullname: Tillotson, Richard D. organization: Idaho National Laboratory (INL) – sequence: 4 givenname: Lætitia H. surname: Delmau fullname: Delmau, Lætitia H. organization: Oak Ridge National Laboratory (ORNL) |
| BackLink | https://www.osti.gov/biblio/1081762$$D View this record in Osti.gov |
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| Cites_doi | 10.1007/s10967-006-0114-9 10.1081/SEI-100107024 10.1016/0022-1902(76)80156-X 10.1080/01496399008050416 10.1007/s11137-005-0033-6 |
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| References | Herbst R. S. (CIT0004) 2006; 56 Baes C. F. (CIT0005) 1998 CIT0010 Rais J. (CIT0002) 2004; 17 CIT0001 CIT0011 Rais J. (CIT0003) 2004; 17 CIT0007 CIT0006 CIT0009 CIT0008 |
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| SubjectTerms | cesium cesium extraction chlorinated cobalt dicarbollide Extraction slope analysis trifluoromethylphenyl sulfone |
| Title | Fundamental Chemistry of Cesium Extraction from Acidic Media by HCCD in FS-13 |
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