Reversible phase transition and switchable dielectric behaviors triggered by rotation and order-disorder motions of crowns
Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6) 1.5 ] + [PF 6 ] − (Habf = p -ammonium benzene formamide) wh...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 47; no. 11; pp. 3851 - 3856 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
2018
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1477-9226 1477-9234 1477-9234 |
| DOI | 10.1039/c8dt00003d |
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| Abstract | Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6)
1.5
]
+
[PF
6
]
−
(Habf =
p
-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order-disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches.
Compound
1
shows apparent step-like dielectric changes near the phase transition, which are triggered by the synergetic rotation motion of 18-C-6 crown ether cycles and hexafluorophosphate anions. |
|---|---|
| AbstractList | Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6)
1.5
]
+
[PF
6
]
−
(Habf =
p
-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order–disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches. Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6) 1.5 ] + [PF 6 ] − (Habf = p -ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order-disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches. Compound 1 shows apparent step-like dielectric changes near the phase transition, which are triggered by the synergetic rotation motion of 18-C-6 crown ether cycles and hexafluorophosphate anions. Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6)1.5]+ [PF6]- (Habf = p-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order-disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches.Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6)1.5]+ [PF6]- (Habf = p-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order-disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches. Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6)1.5]+ [PF6]− (Habf = p-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order–disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches. Solid-to solid-state reversible phase transitions are widely used in switchable dielectrics, ferroelectrics, piezoelectrics, and pyroelectric and non-linear optical materials. Herein we report a new crown ether clathrate, [Habf-(18-crown-6) ] [PF ] (Habf = p-ammonium benzene formamide) which shows an interesting reversible phase transition near room temperature (263 K). X-ray single crystal diffraction analysis shows that the synergetic rotation motion between the 18-crown-6 crown ethers and the order-disorder motions of both hexafluorophosphate guest anions and 18-crown-6 crown ether host molecules lead to the phase transition. This reversible phase transition is confirmed by an evident thermal anomaly behavior around 263 K. The apparent step-like dielectric change around the phase transition indicates that it has potential application in dielectric switches. |
| Author | Tan, Yu-Hui Liu, Yi Yang, Chang-Shan Wang, Chang-Feng Tang, Yun-Zhi Chen, Shao-Peng Wen, He-Rui Zhou, Hai-Tao |
| AuthorAffiliation | Jiangxi University of Science and Technology School of Metallurgy and Chemical Engineering |
| AuthorAffiliation_xml | – sequence: 0 name: School of Metallurgy and Chemical Engineering – sequence: 0 name: Jiangxi University of Science and Technology |
| Author_xml | – sequence: 1 givenname: Yi surname: Liu fullname: Liu, Yi – sequence: 2 givenname: Hai-Tao surname: Zhou fullname: Zhou, Hai-Tao – sequence: 3 givenname: Shao-Peng surname: Chen fullname: Chen, Shao-Peng – sequence: 4 givenname: Yu-Hui surname: Tan fullname: Tan, Yu-Hui – sequence: 5 givenname: Chang-Feng surname: Wang fullname: Wang, Chang-Feng – sequence: 6 givenname: Chang-Shan surname: Yang fullname: Yang, Chang-Shan – sequence: 7 givenname: He-Rui surname: Wen fullname: Wen, He-Rui – sequence: 8 givenname: Yun-Zhi surname: Tang fullname: Tang, Yun-Zhi |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29450435$$D View this record in MEDLINE/PubMed |
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| SubjectTerms | Benzene Crown ethers Dielectrics Diffraction Ethers Ferroelectric materials Ferroelectricity Optical materials Order disorder Phase transitions Single crystals Switches |
| Title | Reversible phase transition and switchable dielectric behaviors triggered by rotation and order-disorder motions of crowns |
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