Structural and optical properties of zinc nitride films prepared by rf magnetron sputtering

Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2–Ar plasma. X-ray diffraction (XRD) analysis indicates that the films just after deposition are polycrystalline with a cubic structure and a preferred orientation of (400). X-ray photoelectro...

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Published inApplied surface science Vol. 255; no. 6; pp. 3544 - 3547
Main Authors Yang, Tianlin, Zhang, Zhisheng, Li, Yanhui, Lv, MaoShui, Song, Shumei, Wu, Zhongchen, Yan, Jincheng, Han, Shenghao
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.2009
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Abstract Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2–Ar plasma. X-ray diffraction (XRD) analysis indicates that the films just after deposition are polycrystalline with a cubic structure and a preferred orientation of (400). X-ray photoelectron spectroscopy (XPS) analysis also confirms the formation of N–Zn bonds and the substitution incorporation of oxygen for nitrogen on the surface of the films. The optical band gap is calculated from the transmittance spectra of films just after deposition, and a direct band gap of 1.01±0.02eV is obtained. Room temperature PL measurement is also performed to investigate the effect of defect on the band gap and quality of the zinc nitride films.
AbstractList Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2-Ar plasma. X-ray diffraction (XRD) analysis indicates that the films just after deposition are polycrystalline with a cubic structure and a preferred orientation of (4 0 0). X-ray photoelectron spectroscopy (XPS) analysis also confirms the formation of N-Zn bonds and the substitution incorporation of oxygen for nitrogen on the surface of the films. The optical band gap is calculated from the transmittance spectra of films just after deposition, and a direct band gap of 1.01 +/- 0.02 eV is obtained. Room temperature PL measurement is also performed to investigate the effect of defect on the band gap and quality of the zinc nitride films.
Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2–Ar plasma. X-ray diffraction (XRD) analysis indicates that the films just after deposition are polycrystalline with a cubic structure and a preferred orientation of (400). X-ray photoelectron spectroscopy (XPS) analysis also confirms the formation of N–Zn bonds and the substitution incorporation of oxygen for nitrogen on the surface of the films. The optical band gap is calculated from the transmittance spectra of films just after deposition, and a direct band gap of 1.01±0.02eV is obtained. Room temperature PL measurement is also performed to investigate the effect of defect on the band gap and quality of the zinc nitride films.
Author Yang, Tianlin
Zhang, Zhisheng
Li, Yanhui
Wu, Zhongchen
Lv, MaoShui
Yan, Jincheng
Han, Shenghao
Song, Shumei
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Zinc nitride
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rf magnetron sputtering
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Snippet Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2–Ar plasma. X-ray diffraction (XRD) analysis...
Zinc nitride films were prepared on quartz substrates by rf magnetron sputtering using pure zinc target in N2-Ar plasma. X-ray diffraction (XRD) analysis...
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SubjectTerms Optical band gap
rf magnetron sputtering
Zinc nitride
Title Structural and optical properties of zinc nitride films prepared by rf magnetron sputtering
URI https://dx.doi.org/10.1016/j.apsusc.2008.07.210
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