Effect of Al Content on the Microstructural and Grain Growth Kinetics of Magnesium Alloys

• Published in: Metals (Basel ) Vol. 12; no. 11; p. 1955
• Main Authors: Chen, Ruinan, Chen, Qinghua, Huang, Xu, He, Qingsong, Su, Jian, Tan, Bin, Xu, Chao, Deng, Huahong, Dai, Qingwei
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.11.2022
• Subjects: Acids; Al content; Annealing; Experiments; Grain boundaries; Grain boundary migration; Grain growth; Grain refinement; Grain size; Growth; Hot pressing; Hot rolling; Isothermal annealing; Magnesium alloys; Magnesium base alloys; Microstructure; Morphology; Pinning; second phase; solute; Specialty metals industry; Thermomechanical treatment; United States > US
• ISSN: 2075-4701; 2075-4701
• DOI: 10.3390/met12111955

In order to control the grain size in thermomechanical processing, the grain growth behavior of hot extruded Mg–xAl–1Zn (x = 3, 6, 9) alloys and their relationship with second phase particles and solutes were investigated. The growth rate of AZ61 is greater than that of AZ31 and AZ91 at 300 °C, 350 °C, 400 °C, and 450 °C under isothermal annealing. The average grain growth exponents n of Mg–xAl–1Zn (x = 3, 6, 9) alloys were 2.26, 2.33, and 2.53 at 300–400 °C, respectively. The deviation from the theoretical value of 2 was attributed to the hindrance of grain boundary migration of Al-rich second phase particles and solute Al. Microscopic observations show that the grain size of the annealed samples is closely related to the shape, volume fraction, size, and distribution position of the second phase particles. Significantly, the pinning effect is stronger for lamellar and network-like second phase particles. In addition, the pinning effect of Al-rich second phase particles plays a more important role in grain refinement than the dragging of solute Al. The growth of abnormal grains in the microstructure is attributed to the high energy difference between the preferentially oriented <112¯0> grains and the surrounding grains, which drives the grain boundaries to overcome the same pinning force of the second phase particles.