Low-temperature combustion synthesis of Bi2WO6 nanoparticles as a visible-light-driven photocatalyst

Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol und...

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Published inJournal of hazardous materials Vol. 177; no. 1-3; pp. 1013 - 1018
Main Authors Zhang, Zhijie, Wang, Wenzhong, Shang, Meng, Yin, Wenzong
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier 15.05.2010
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Abstract Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.
AbstractList Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.
Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.
Visible-light-induced Bi2WO6 photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (I' >420nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10a4 M within 75min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi2WO6. Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi2WO6 powder (SSR) in the degradation of phenol.
Author Yin, Wenzong
Shang, Meng
Wang, Wenzhong
Zhang, Zhijie
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  surname: Shang
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ISSN 0304-3894
1873-3336
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Issue 1-3
Keywords Pollutant behavior
Nanoparticle
Photocatalysis
Bi
Combustion
Ultrafine particle
Powder
Phenol
Low-temperature combustion synthesis
Chemical oxygen demand
Fuel
Water quality
Visible radiation
Aerosols
Phenols
WO
Air pollution
Rhodamine B
Visible-light photocatalysis
Catalyst
Low temperature
Photochemical degradation
Language English
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CC BY 4.0
Copyright (c) 2010 Elsevier B.V. All rights reserved.
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PublicationTitle Journal of hazardous materials
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Snippet Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the...
Visible-light-induced Bi2WO6 photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the...
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SubjectTerms Applied sciences
Atmospheric pollution
Bismuth - chemistry
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Cold Temperature
Combustion synthesis
Degradation
Exact sciences and technology
Fuels
General and physical chemistry
Incineration
Industrial Waste - prevention & control
Light
Nanoparticles
Nanoparticles - chemistry
Oxides - chemistry
Oxidizers
Oxygen demand
Phenol
Photocatalysis
Photolysis
Pollution
Reactors
Rhodamines
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Tungsten - chemistry
Title Low-temperature combustion synthesis of Bi2WO6 nanoparticles as a visible-light-driven photocatalyst
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