Low-temperature combustion synthesis of Bi2WO6 nanoparticles as a visible-light-driven photocatalyst
Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol und...
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Published in | Journal of hazardous materials Vol. 177; no. 1-3; pp. 1013 - 1018 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Kidlington
Elsevier
15.05.2010
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Abstract | Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol. |
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AbstractList | Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol.Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol. Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (lambda>420 nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10(-4)M within 75 min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi(2)WO(6). Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi(2)WO(6) powder (SSR) in the degradation of phenol. Visible-light-induced Bi2WO6 photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the fuel. The photocatalytic activities of the as-synthesized samples were evaluated by the photodegradation of rhodamine B (RhB) and phenol under visible-light irradiation (I' >420nm). The results showed that the molar ratio of fuel to oxidizer had an important influence on the photocatalytic activities of the products. When the molar ratio of fuel to oxidizer was 1, the photocatalyst exhibited the highest degradation efficiency, which can completely degrade RhB with a concentration up to 10a4 M within 75min. Besides decoloring, the markable reduction of chemical oxygen demand (COD) was also observed in the degradation of RhB, further demonstrating the photocatalytic performance of Bi2WO6. Additionally, the photocatalyst showed much enhanced visible photocatalytic efficiency, up to 94.2% in 4h, than the bulk Bi2WO6 powder (SSR) in the degradation of phenol. |
Author | Yin, Wenzong Shang, Meng Wang, Wenzhong Zhang, Zhijie |
Author_xml | – sequence: 1 givenname: Zhijie surname: Zhang fullname: Zhang, Zhijie – sequence: 2 givenname: Wenzhong surname: Wang fullname: Wang, Wenzhong – sequence: 3 givenname: Meng surname: Shang fullname: Shang, Meng – sequence: 4 givenname: Wenzong surname: Yin fullname: Yin, Wenzong |
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Keywords | Pollutant behavior Nanoparticle Photocatalysis Bi Combustion Ultrafine particle Powder Phenol Low-temperature combustion synthesis Chemical oxygen demand Fuel Water quality Visible radiation Aerosols Phenols WO Air pollution Rhodamine B Visible-light photocatalysis Catalyst Low temperature Photochemical degradation |
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Snippet | Visible-light-induced Bi(2)WO(6) photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the... Visible-light-induced Bi2WO6 photocatalyst has been successfully synthesized via a facile low-temperature combustion synthesis method, using glycine as the... |
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SubjectTerms | Applied sciences Atmospheric pollution Bismuth - chemistry Catalysis Catalytic reactions Chemical engineering Chemistry Cold Temperature Combustion synthesis Degradation Exact sciences and technology Fuels General and physical chemistry Incineration Industrial Waste - prevention & control Light Nanoparticles Nanoparticles - chemistry Oxides - chemistry Oxidizers Oxygen demand Phenol Photocatalysis Photolysis Pollution Reactors Rhodamines Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tungsten - chemistry |
Title | Low-temperature combustion synthesis of Bi2WO6 nanoparticles as a visible-light-driven photocatalyst |
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