On the possibility of simultaneously achieving sufficient oxidation resistance and creep property at high temperatures exceeding 1000 °C in Co-based superalloys

Effects of additions of γ’ (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the microstructural stability, oxidation resistance and creep properties of two-phase γ/γ′ Co-based superalloys based on the Co–Al–W systems hav...

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Published inJournal of alloys and compounds Vol. 858; p. 157724
Main Authors Chen, Zhenghao, Okamoto, Norihiko L., Chikugo, Kazuyoshi, Inui, Haruyuki
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 25.03.2021
Elsevier BV
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Abstract Effects of additions of γ’ (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the microstructural stability, oxidation resistance and creep properties of two-phase γ/γ′ Co-based superalloys based on the Co–Al–W systems have been investigated in order to see whether simultaneous achievement of sufficient oxidation resistance and creep property for the usage above 1000 °C is possible or not for Co-based superalloys. A candidate composition ((Co0.8Ni0.2)-6Al–2W–2Ta–6Ti–8Cr–1Si) that provides relatively high γ′ solvus temperature and high γ′ volume fraction is found. The alloy with the candidate composition exhibits superior oxidation resistance when compared to Cr-free alloys but the creep property is not as good as expected from the high γ′ solvus temperature and high γ’ volume fraction and is only comparable to those of Ni-based superalloys of the first generation. The reason for the modest creep properties of the candidate alloy as well as possibilities for further investigation to simultaneously achieve sufficient oxidation resistance and creep property for Co-based superalloys are discussed. [Display omitted] •A new Co-based superalloy with improved oxidation and creep properties is developed.•A large amount of Cr is successfully added to the new alloy for oxidation resistance.•The alloy exhibits oxidation resistance better than any other alloys so far developed.•Ta and Ti are also co-added to the alloy for better creep property.•The alloy exhibits creep property comparable to 1st Gen. Ni-based superalloys.
AbstractList Effects of additions of γ’ (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the microstructural stability, oxidation resistance and creep properties of two-phase γ/γ′ Co-based superalloys based on the Co–Al–W systems have been investigated in order to see whether simultaneous achievement of sufficient oxidation resistance and creep property for the usage above 1000 °C is possible or not for Co-based superalloys. A candidate composition ((Co0.8Ni0.2)-6Al–2W–2Ta–6Ti–8Cr–1Si) that provides relatively high γ′ solvus temperature and high γ′ volume fraction is found. The alloy with the candidate composition exhibits superior oxidation resistance when compared to Cr-free alloys but the creep property is not as good as expected from the high γ′ solvus temperature and high γ’ volume fraction and is only comparable to those of Ni-based superalloys of the first generation. The reason for the modest creep properties of the candidate alloy as well as possibilities for further investigation to simultaneously achieve sufficient oxidation resistance and creep property for Co-based superalloys are discussed. [Display omitted] •A new Co-based superalloy with improved oxidation and creep properties is developed.•A large amount of Cr is successfully added to the new alloy for oxidation resistance.•The alloy exhibits oxidation resistance better than any other alloys so far developed.•Ta and Ti are also co-added to the alloy for better creep property.•The alloy exhibits creep property comparable to 1st Gen. Ni-based superalloys.
Effects of additions of γ' (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the microstructural stability, oxidation resistance and creep properties of two-phase γ/γ′ Co-based superalloys based on the Co–Al–W systems have been investigated in order to see whether simultaneous achievement of sufficient oxidation resistance and creep property for the usage above 1000 °C is possible or not for Co-based superalloys. A candidate composition ((Co0.8Ni0.2)-6Al–2W–2Ta–6Ti–8Cr–1Si) that provides relatively high γ′ solvus temperature and high γ′ volume fraction is found. The alloy with the candidate composition exhibits superior oxidation resistance when compared to Cr-free alloys but the creep property is not as good as expected from the high γ′ solvus temperature and high γ' volume fraction and is only comparable to those of Ni-based superalloys of the first generation. The reason for the modest creep properties of the candidate alloy as well as possibilities for further investigation to simultaneously achieve sufficient oxidation resistance and creep property for Co-based superalloys are discussed.
ArticleNumber 157724
Author Chen, Zhenghao
Inui, Haruyuki
Chikugo, Kazuyoshi
Okamoto, Norihiko L.
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Co-based superalloy
Oxidation resistance
Creep
Scanning electron microscopy (SEM)
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Snippet Effects of additions of γ’ (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the...
Effects of additions of γ' (L12)-forming elements (Ta, Ti and Ni; for creep property) and γ (FCC)-forming elements (Cr and Si; for oxidation resistance) on the...
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SubjectTerms Alloys
Chromium
Co-based superalloy
Cobalt base alloys
Creep
Creep (materials)
Nickel base alloys
Oxidation
Oxidation resistance
Phase equilibria
Scanning electron microscopy (SEM)
Silicon
Superalloys
Title On the possibility of simultaneously achieving sufficient oxidation resistance and creep property at high temperatures exceeding 1000 °C in Co-based superalloys
URI https://dx.doi.org/10.1016/j.jallcom.2020.157724
https://www.proquest.com/docview/2492315938
Volume 858
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