Preparation of a novel cellulose-based immobilized heteropoly acid system and its application on the biodiesel production
[Display omitted] •Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized he...
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Published in | Fuel (Guildford) Vol. 172; pp. 293 - 300 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier Ltd
15.05.2016
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Abstract | [Display omitted]
•Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized heteropoly acid can be reused more than 7 times.
Porous cellulose beads (CBs) were prepared using ionic liquid as solvent and then further modified using different reagents which were ethylenediamine (EDA), diethylenetriamine (DETA), triethylene tetramine (TETA) and 4-aminostyrene (AST). These CBs were used as carrier for immobilization of H3PW12O40 (HPW). The immobilized catalysts were characterized by FT-IR, scanning electron microscopy, XRD, ICP atomic emission spectrophotometer. The results indicated that CB-(AST-HPW)n possessed higher amounts of HPW and stronger catalytic activity for biodiesel production. After using CB-(AST-HPW)n for yellow horn oil esterification, the conversion yield reached 96.22% under optimal conditions. The final product of biodiesel prepared with CB-(AST-HPW)n was of high quality. We conclude that cellulose-based immobilized HPW is a novel catalyst potentially suited for biodiesel production. |
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AbstractList | [Display omitted]
•Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized heteropoly acid can be reused more than 7 times.
Porous cellulose beads (CBs) were prepared using ionic liquid as solvent and then further modified using different reagents which were ethylenediamine (EDA), diethylenetriamine (DETA), triethylene tetramine (TETA) and 4-aminostyrene (AST). These CBs were used as carrier for immobilization of H3PW12O40 (HPW). The immobilized catalysts were characterized by FT-IR, scanning electron microscopy, XRD, ICP atomic emission spectrophotometer. The results indicated that CB-(AST-HPW)n possessed higher amounts of HPW and stronger catalytic activity for biodiesel production. After using CB-(AST-HPW)n for yellow horn oil esterification, the conversion yield reached 96.22% under optimal conditions. The final product of biodiesel prepared with CB-(AST-HPW)n was of high quality. We conclude that cellulose-based immobilized HPW is a novel catalyst potentially suited for biodiesel production. |
Author | Yao, Xiao-Hui Duan, Ming-Hui Fu, Yu-Jie Zhang, Dong-Yang Zu, Yuan-Gang |
Author_xml | – sequence: 1 givenname: Dong-Yang surname: Zhang fullname: Zhang, Dong-Yang organization: College of Biotechnology, Sericultural Research Institute, Jiangsu University of Science and Technology, Zhenjiang 212018, China – sequence: 2 givenname: Ming-Hui surname: Duan fullname: Duan, Ming-Hui organization: State Engineering Laboratory for Bio-Resource Eco-Utilization, Northeast Forestry University, Harbin 150040, China – sequence: 3 givenname: Xiao-Hui surname: Yao fullname: Yao, Xiao-Hui organization: College of Biotechnology, Sericultural Research Institute, Jiangsu University of Science and Technology, Zhenjiang 212018, China – sequence: 4 givenname: Yu-Jie surname: Fu fullname: Fu, Yu-Jie email: fuyujie1505@163.com organization: State Engineering Laboratory for Bio-Resource Eco-Utilization, Northeast Forestry University, Harbin 150040, China – sequence: 5 givenname: Yuan-Gang surname: Zu fullname: Zu, Yuan-Gang organization: State Engineering Laboratory for Bio-Resource Eco-Utilization, Northeast Forestry University, Harbin 150040, China |
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Keywords | Yellow horn seed oil Immobilization Cellulose beads Heteropoly acid Biodiesel |
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•Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized... |
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SubjectTerms | Biodiesel Cellulose beads Heteropoly acid Immobilization Yellow horn seed oil |
Title | Preparation of a novel cellulose-based immobilized heteropoly acid system and its application on the biodiesel production |
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