Preparation of a novel cellulose-based immobilized heteropoly acid system and its application on the biodiesel production

[Display omitted] •Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized he...

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Published inFuel (Guildford) Vol. 172; pp. 293 - 300
Main Authors Zhang, Dong-Yang, Duan, Ming-Hui, Yao, Xiao-Hui, Fu, Yu-Jie, Zu, Yuan-Gang
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 15.05.2016
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Abstract [Display omitted] •Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized heteropoly acid can be reused more than 7 times. Porous cellulose beads (CBs) were prepared using ionic liquid as solvent and then further modified using different reagents which were ethylenediamine (EDA), diethylenetriamine (DETA), triethylene tetramine (TETA) and 4-aminostyrene (AST). These CBs were used as carrier for immobilization of H3PW12O40 (HPW). The immobilized catalysts were characterized by FT-IR, scanning electron microscopy, XRD, ICP atomic emission spectrophotometer. The results indicated that CB-(AST-HPW)n possessed higher amounts of HPW and stronger catalytic activity for biodiesel production. After using CB-(AST-HPW)n for yellow horn oil esterification, the conversion yield reached 96.22% under optimal conditions. The final product of biodiesel prepared with CB-(AST-HPW)n was of high quality. We conclude that cellulose-based immobilized HPW is a novel catalyst potentially suited for biodiesel production.
AbstractList [Display omitted] •Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized amount.•The cellulose-based immobilized heteropoly acid can be successfully used on the biodiesel production.•The cellulose-based immobilized heteropoly acid can be reused more than 7 times. Porous cellulose beads (CBs) were prepared using ionic liquid as solvent and then further modified using different reagents which were ethylenediamine (EDA), diethylenetriamine (DETA), triethylene tetramine (TETA) and 4-aminostyrene (AST). These CBs were used as carrier for immobilization of H3PW12O40 (HPW). The immobilized catalysts were characterized by FT-IR, scanning electron microscopy, XRD, ICP atomic emission spectrophotometer. The results indicated that CB-(AST-HPW)n possessed higher amounts of HPW and stronger catalytic activity for biodiesel production. After using CB-(AST-HPW)n for yellow horn oil esterification, the conversion yield reached 96.22% under optimal conditions. The final product of biodiesel prepared with CB-(AST-HPW)n was of high quality. We conclude that cellulose-based immobilized HPW is a novel catalyst potentially suited for biodiesel production.
Author Yao, Xiao-Hui
Duan, Ming-Hui
Fu, Yu-Jie
Zhang, Dong-Yang
Zu, Yuan-Gang
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Keywords Yellow horn seed oil
Immobilization
Cellulose beads
Heteropoly acid
Biodiesel
Language English
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Snippet [Display omitted] •Cellulose beads were prepared using environmental friendly ILs.•HPWs were first immobilized on the cellulose beads with high immobilized...
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StartPage 293
SubjectTerms Biodiesel
Cellulose beads
Heteropoly acid
Immobilization
Yellow horn seed oil
Title Preparation of a novel cellulose-based immobilized heteropoly acid system and its application on the biodiesel production
URI https://dx.doi.org/10.1016/j.fuel.2015.12.020
Volume 172
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