Proton storage chemistry in aqueous zinc‐organic batteries: A review

Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueo...

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Published inInfoMat Vol. 5; no. 2
Main Authors Deng, Xianming, Sarpong, James Kumankuma, Zhang, Guobin, Hao, Jing, Zhao, Xu, Li, Linyuan, Li, Hongfei, Han, Cuiping, Li, Baohua
Format Journal Article
LanguageEnglish
Published Melbourne John Wiley & Sons, Inc 01.02.2023
Wiley
Subjects
aqueous zinc‐ion batteries
Electrochemical analysis
Electrode materials
Electrodes
Electrolytes
Energy storage
H+/Zn2+ co‐storage
organic electrode materials
Organic materials
Polymers
proton storage chemistry
Protons
Rechargeable batteries
Zinc
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Abstract Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H+) storage chemistry in aqueous Zn‐organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn2+ intercalation, pure H+ storage, and H+/Zn2+ co‐storage. Moreover, the impact of H+ storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H+ storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H+ storage chemistry of organic electrode materials to advance our understanding and further its application. This review focuses on proton (H+) storage chemistry in aqueous Zn‐organic batteries and summarizes the reported electrochemical mechanisms as well as the impact of H+ storage on the electrochemical performance.
AbstractList Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H + ) storage chemistry in aqueous Zn‐organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn 2+ intercalation, pure H + storage, and H + /Zn 2+ co‐storage. Moreover, the impact of H + storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H + storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H + storage chemistry of organic electrode materials to advance our understanding and further its application. image
Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn-ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H+) storage chemistry in aqueous Zn-organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn2+ intercalation, pure H+ storage, and H+/Zn2+ co-storage. Moreover, the impact of H+ storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H+ storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H+ storage chemistry of organic electrode materials to advance our understanding and further its application.
Abstract Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H+) storage chemistry in aqueous Zn‐organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn2+ intercalation, pure H+ storage, and H+/Zn2+ co‐storage. Moreover, the impact of H+ storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H+ storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H+ storage chemistry of organic electrode materials to advance our understanding and further its application.
Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive cathode materials for aqueous Zn‐ion batteries (ZIBs). In this review, we discuss the recent developments of organic electrode materials for aqueous ZIBs. Although the proton (H+) storage chemistry in aqueous Zn‐organic batteries has triggered an overwhelming literature surge in recent years, this topic remains controversial. Therefore, our review focuses on this significant issue and summarizes the reported electrochemical mechanisms, including pure Zn2+ intercalation, pure H+ storage, and H+/Zn2+ co‐storage. Moreover, the impact of H+ storage on the electrochemical performance of aqueous ZIBs is discussed systematically. Given the significance of H+ storage, we also highlight the relevant characterization methods employed. Finally, perspectives and directions on further understanding the charge storage mechanisms of organic materials are outlined. We hope that this review will stimulate more attention on the H+ storage chemistry of organic electrode materials to advance our understanding and further its application. This review focuses on proton (H+) storage chemistry in aqueous Zn‐organic batteries and summarizes the reported electrochemical mechanisms as well as the impact of H+ storage on the electrochemical performance.
Author Li, Baohua
Hao, Jing
Li, Linyuan
Zhang, Guobin
Zhao, Xu
Sarpong, James Kumankuma
Han, Cuiping
Deng, Xianming
Li, Hongfei
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  organization: Tsinghua Shenzhen International Graduate School, Tsinghua University
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  surname: Zhang
  fullname: Zhang, Guobin
  organization: Tsinghua Shenzhen International Graduate School, Tsinghua University
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  surname: Hao
  fullname: Hao, Jing
  organization: Tsinghua Shenzhen International Graduate School, Tsinghua University
– sequence: 5
  givenname: Xu
  surname: Zhao
  fullname: Zhao, Xu
  organization: Tsinghua Shenzhen International Graduate School, Tsinghua University
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  surname: Li
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  organization: Southern University of Science and Technology
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  givenname: Cuiping
  orcidid: 0000-0003-1186-3234
  surname: Han
  fullname: Han, Cuiping
  email: cp.han@siat.ac.cn
  organization: Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences
– sequence: 9
  givenname: Baohua
  orcidid: 0000-0002-8469-0162
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  email: libh@mail.sz.tsinghua.edu.cn
  organization: Tsinghua Shenzhen International Graduate School, Tsinghua University
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Snippet Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as attractive...
Abstract Benefiting from the advantageous features of structural diversity and resource renewability, organic electroactive compounds are considered as...
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SubjectTerms aqueous zinc‐ion batteries
Electrochemical analysis
Electrode materials
Electrodes
Electrolytes
Energy storage
H+/Zn2+ co‐storage
organic electrode materials
Organic materials
Polymers
proton storage chemistry
Protons
Rechargeable batteries
Zinc
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Title Proton storage chemistry in aqueous zinc‐organic batteries: A review
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