On the asymmetric rh(I) catalyzed [4+2] cycloisomerization reaction. Electronic and torsional ligand control of absolute stereoselection

• Published in: Tetrahedron Vol. 50; no. 21; pp. 6145 - 6154
• Main Authors: McKinstry, Lydia, Livinghouse, Tom
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 1994; Elsevier
• Subjects: Chemistry; Chemistry, Organic; Exact sciences and technology; Heterocyclic compounds; Heterocyclic compounds with only one n hetero atom and condensed derivatives; Organic chemistry; Physical Sciences; Preparations and properties; Science & Technology; HYDROGENATION; DIELS-ALDER REACTION; COMPLEXES; ALPHA; ALDEHYDES; LEWIS-ACIDS; INDUCTION; Cyclization; Isomerization; Ditertiary phosphine; Rhodium I Complexes; Bicyclic compound; Organic ligand; Oxygen heterocycle; Asymmetric catalysis

The use of bisphosphine ligands related to DIOP as chiral modifiers in the Rh(I) catalyzed [4+2] cycloisomerization reaction results in moderate to goo The use of bisphosphine ligands related to DIOP as chiral modifiers in the Rh(I) catalyzed [4+2] cycloisomerization reaction results in moderate to...