Average and local structure analysis of metastable LixMn0.9Ti0.1O2 by synchrotron X-ray and neutron sources

• Published in: Solid state ionics Vol. 325; pp. 209 - 213
• Main Authors: Ishida, Naoya, Miyazawa, Kazuki, Kitamura, Naoto, Akimoto, Junji, Idemoto, Yasushi
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2018
• Subjects: Average structure; Cathode material; Li-ion battery; Local structure; Pair distribution function; Total scattering; Cathode material; Local structure; Total scattering; Pair distribution function; Li-ion battery; Average structure
• DOI: 10.1016/j.ssi.2018.08.015
• ISSN: 0167-2738

The layered LixMn0.9Ti0.1O2 as a cathode material for lithium-ion battery was synthesized from the precursor of Na0.7Mn0.9Ti0.1O2 via Na/Li ion exchange. The main phase of LixMn0.9Ti0.1O2 was identified as the layered rock-salt structure with space group R3¯m using the synchrotron X-ray and neutron powder diffractions. Since the change of the charge and discharge curves of the LixMn0.9Ti0.1O2 at the 4 V region was smaller than that of the unsubstituted material LixMnO2, the transformation to spinel structure was suppressed by Ti substitution. In the PDF analysis for the synchrotron X-ray and neutron total scattering data, the structure model in which a part of Mn was located at the Li site showed better fitting than the completely ordered rock-salt structure. It was suggested that the local structure of LixMn0.9Ti0.1O2 was characterized by the coordination environment locally similar to the spinel type in part of the layered rock-salt structure. The calculated bond-angle distortion (σ2 = 31(2)) of the TiO6 octahedra and the MnO6 octahedra (σ2 = 39(4)) from the local structure obtained by PDF analysis showed the effect of suppression derived from Ti on the distortion. Therefore, the cycle performance of LixMn0.9Ti0.1O2 was improved by a contribution of Ti to the structural stability. •Structure analysis of LixMn0.9Ti0.1O2 was performed using X-ray and neutron.•Locally spinel type structure was revealed by PDF analysis.•Less distortion of TiO6 octahedra leads to improved cycle performance.