Activity, selectivity and stability of Ni and bimetallic Ni–Pt supported on zeolite Y catalysts for hydrogenation of acetophenone and its substituted derivatives
The hydrogenation of acetophenone, p-hydroxy acetophenone ( p-HAP) and p-isobutyl acetophenone was studied using Ni and bimetallic Ni–Pt supported on zeolite Y catalysts. A 10% Ni-supported-on-zeolite Y catalyst showed the optimum activity when compared to other Ni-supported catalysts. The activity...
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Published in | Applied catalysis. A, General Vol. 193; no. 1; pp. 71 - 86 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Amsterdam
Elsevier B.V
28.02.2000
Elsevier |
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Abstract | The hydrogenation of acetophenone,
p-hydroxy acetophenone (
p-HAP) and
p-isobutyl acetophenone was studied using Ni and bimetallic Ni–Pt supported on zeolite Y catalysts. A 10% Ni-supported-on-zeolite Y catalyst showed the optimum activity when compared to other Ni-supported catalysts. The activity of this catalyst decreased very rapidly on recycle; however, the bimetallic Ni–Pt-supported-on-zeolite Y catalyst was highly stable and showed constant activity on recycle. The addition of Pt catalyses the reduction of Ni
2+ to Ni
0, as characterised by X-ray photoelectron spectroscopy (XPS) and other techniques. For the Ni–Pt bimetallic catalyst, the hydrogen adsorption was found to be higher than that for monometallic catalysts; the adsorbed hydrogen reacts with the activated acetophenone complex to facilitate the catalytic process. The FTIR analysis of adsorbed acetophenone on the catalyst samples indicated that, in both monometallic and bimetallic catalysts supported on zeolite Y, the CO bond of acetophenone is highly activated due to the strong interactions with the acidic sites present on the zeolite. Zeolite interactions with intermediate products and solvent moieties also influenced the selectivity behaviour. A trace amount of a base like NaOH acts as a promoter in improving the selectivity towards alcohol. A plausible reaction mechanism has been proposed for the hydrogenation of acetophenone and its derivatives using monometallic as well as bimetallic catalysts. |
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AbstractList | The hydrogenation of acetophenone,
p-hydroxy acetophenone (
p-HAP) and
p-isobutyl acetophenone was studied using Ni and bimetallic Ni–Pt supported on zeolite Y catalysts. A 10% Ni-supported-on-zeolite Y catalyst showed the optimum activity when compared to other Ni-supported catalysts. The activity of this catalyst decreased very rapidly on recycle; however, the bimetallic Ni–Pt-supported-on-zeolite Y catalyst was highly stable and showed constant activity on recycle. The addition of Pt catalyses the reduction of Ni
2+ to Ni
0, as characterised by X-ray photoelectron spectroscopy (XPS) and other techniques. For the Ni–Pt bimetallic catalyst, the hydrogen adsorption was found to be higher than that for monometallic catalysts; the adsorbed hydrogen reacts with the activated acetophenone complex to facilitate the catalytic process. The FTIR analysis of adsorbed acetophenone on the catalyst samples indicated that, in both monometallic and bimetallic catalysts supported on zeolite Y, the CO bond of acetophenone is highly activated due to the strong interactions with the acidic sites present on the zeolite. Zeolite interactions with intermediate products and solvent moieties also influenced the selectivity behaviour. A trace amount of a base like NaOH acts as a promoter in improving the selectivity towards alcohol. A plausible reaction mechanism has been proposed for the hydrogenation of acetophenone and its derivatives using monometallic as well as bimetallic catalysts. |
Author | Rode, C.V. Chaudhari, R.V. Arai, M. Malyala, R.V. Hegde, S.G. |
Author_xml | – sequence: 1 givenname: R.V. surname: Malyala fullname: Malyala, R.V. organization: CANMET Energy Technology Centre, Natural Resources Canada, 1 Haanel Drive, Nepean, Ont., Canada K1A 1M1 – sequence: 2 givenname: C.V. surname: Rode fullname: Rode, C.V. organization: Homogeneous Catalysis Division, National Chemical Laboratory, Pune 411 008, India – sequence: 3 givenname: M. surname: Arai fullname: Arai, M. organization: Institute for Chemical Reaction Science, Tohoku University, Katahira, Aoba-ku, Sendai, 980, Japan – sequence: 4 givenname: S.G. surname: Hegde fullname: Hegde, S.G. organization: Homogeneous Catalysis Division, National Chemical Laboratory, Pune 411 008, India – sequence: 5 givenname: R.V. surname: Chaudhari fullname: Chaudhari, R.V. email: rvc@ems.ncl.res.in organization: Homogeneous Catalysis Division, National Chemical Laboratory, Pune 411 008, India |
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Keywords | Nickel catalysts Bimetallic catalysts Catalytic hydrogenation Acetophenone and derivatives Mixed catalyst Catalytic reaction Transition metal Zeolite Ketone X ray diffraction Hydrogenation Supported catalyst Molecular sieve Infrared spectrometry Heterogeneous catalysis Platinum Acetophenone Benzenic compound Nickel |
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Snippet | The hydrogenation of acetophenone,
p-hydroxy acetophenone (
p-HAP) and
p-isobutyl acetophenone was studied using Ni and bimetallic Ni–Pt supported on zeolite Y... |
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SubjectTerms | Acetophenone and derivatives Bimetallic catalysts Catalysis Catalysts: preparations and properties Catalytic hydrogenation Chemistry Exact sciences and technology General and physical chemistry Nickel catalysts Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
Title | Activity, selectivity and stability of Ni and bimetallic Ni–Pt supported on zeolite Y catalysts for hydrogenation of acetophenone and its substituted derivatives |
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