Comparative evaluation of chemical and bio techniques for uranium leaching from low grade sandstone rock sample, Abu Thor, southwestern Sinai, Egypt
Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the lower member of Um Bogma Formation in Abu Thor area. The studied sample was characterized geologically as a sandstone rock contain 450 mg/kg o...
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Published in | Journal of radioanalytical and nuclear chemistry Vol. 331; no. 12; pp. 5675 - 5689 |
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Abstract | Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the lower member of Um Bogma Formation in Abu Thor area. The studied sample was characterized geologically as a sandstone rock contain 450 mg/kg of uranium. This work is aimed to compare between eco-friendly bioleaching and conventional leaching processe. The uranium bioleaching efficiency achieved 80% by using a native fungal strain;
Aspergillus nidulans
as a green technology with the optimimum conditions as; 3 pH value, 3% pulp density, 7 days incubation period, and 30 °C incubation temperatures. Whereas the traditional technique using alkaline and sulphuric acid leaching attained 68.5% and 95% respectively at the best condition. Finally, the shrinking core model was represented the layer diffusion process by acquiring apparent activation energy 18.28 and 16.82 kJ/mol for carbonate and sulphuric acid leaching, respectively. |
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AbstractList | Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the lower member of Um Bogma Formation in Abu Thor area. The studied sample was characterized geologically as a sandstone rock contain 450 mg/kg of uranium. This work is aimed to compare between eco-friendly bioleaching and conventional leaching processe. The uranium bioleaching efficiency achieved 80% by using a native fungal strain; Aspergillus nidulans as a green technology with the optimimum conditions as; 3 pH value, 3% pulp density, 7 days incubation period, and 30 °C incubation temperatures. Whereas the traditional technique using alkaline and sulphuric acid leaching attained 68.5% and 95% respectively at the best condition. Finally, the shrinking core model was represented the layer diffusion process by acquiring apparent activation energy 18.28 and 16.82 kJ/mol for carbonate and sulphuric acid leaching, respectively. Abstract Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the lower member of Um Bogma Formation in Abu Thor area. The studied sample was characterized geologically as a sandstone rock contain 450 mg/kg of uranium. This work is aimed to compare between eco-friendly bioleaching and conventional leaching processe. The uranium bioleaching efficiency achieved 80% by using a native fungal strain; Aspergillus nidulans as a green technology with the optimimum conditions as; 3 pH value, 3% pulp density, 7 days incubation period, and 30 °C incubation temperatures. Whereas the traditional technique using alkaline and sulphuric acid leaching attained 68.5% and 95% respectively at the best condition. Finally, the shrinking core model was represented the layer diffusion process by acquiring apparent activation energy 18.28 and 16.82 kJ/mol for carbonate and sulphuric acid leaching, respectively. Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the lower member of Um Bogma Formation in Abu Thor area. The studied sample was characterized geologically as a sandstone rock contain 450 mg/kg of uranium. This work is aimed to compare between eco-friendly bioleaching and conventional leaching processe. The uranium bioleaching efficiency achieved 80% by using a native fungal strain; Aspergillus nidulans as a green technology with the optimimum conditions as; 3 pH value, 3% pulp density, 7 days incubation period, and 30 °C incubation temperatures. Whereas the traditional technique using alkaline and sulphuric acid leaching attained 68.5% and 95% respectively at the best condition. Finally, the shrinking core model was represented the layer diffusion process by acquiring apparent activation energy 18.28 and 16.82 kJ/mol for carbonate and sulphuric acid leaching, respectively. |
Audience | Academic |
Author | Attia, Reda M. Abbas, Abd Elhadi A. Sallam, Osama R. Kawady, Nilly A. |
Author_xml | – sequence: 1 givenname: Reda M. surname: Attia fullname: Attia, Reda M. email: chredamohamed@yahoo.com organization: Nuclear Materials Authority – sequence: 2 givenname: Osama R. surname: Sallam fullname: Sallam, Osama R. organization: Nuclear Materials Authority – sequence: 3 givenname: Abd Elhadi A. surname: Abbas fullname: Abbas, Abd Elhadi A. organization: Nuclear Materials Authority – sequence: 4 givenname: Nilly A. surname: Kawady fullname: Kawady, Nilly A. email: nillykawady@yahoo.com organization: Nuclear Materials Authority |
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Cites_doi | 10.1007/s12666-020-01983-z 10.1007/978-3-030-15265-9_6 10.1111/1751-7915.12767 10.1007/978-981-10-1866-4 10.1016/j.hydromet.2016.08.016 10.1016/j.hydromet.2008.04.005 10.1016/j.jenvrad.2014.02.024 10.1021/es2002056 10.1016/j.hydromet.2019.105122 10.3923/ajbkr.2011.226.236 10.5772/intechopen.72754 10.1016/0169-1368(92)90008-9 10.1016/j.jece.2019.103335 10.1007/s41207-019-0106-0 10.3390/met10070978 10.1016/j.hydromet.2013.08.003 10.1080/08827508.2011.635731 10.1080/01496395.2018.1437182 10.1080/08929882.2017.1394061 10.1016/j.hydromet.2006.07.001 10.1016/j.jappgeo.2020.104219 10.1016/j.mineng.2013.03.030 10.1098/rsos.180403 10.1016/j.envadv.2021.100083 10.1080/16878507.2019.1594095 10.1007/s12666-015-0548-2 10.1016/j.hydromet.2018.12.021 10.1021/ie990488g 10.1306/2F919797-16CE-11D7-8645000102C1865D |
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Keywords | Bioleaching Uranium Kinetics Shrinking core Akaline and acid leaching |
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Snippet | Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located at the... Abstract Ferruginous sandstone considered as a one of the economically significant uranium mineralized areas in the southwestern part of the Sinai that located... |
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SubjectTerms | Bacterial leaching Chemistry Chemistry and Materials Science Diagnostic Radiology Diffusion layers Green technology Hadrons Heavy Ions Inorganic Chemistry Leaching Methods Nuclear Chemistry Nuclear Physics Physical Chemistry Sandstone Shrinking core model Uranium |
Title | Comparative evaluation of chemical and bio techniques for uranium leaching from low grade sandstone rock sample, Abu Thor, southwestern Sinai, Egypt |
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