Preparation of novel phosphor using intercalation of tobermorite
The emission intensity of phosphors is often subject to concentration quenching after doping of the activator in the host crystal rises above a certain limit. This study describes the preparation of novel phosphors based on tobermorite that do not exhibit concentration quenching. In the preparation...
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| Published in | Journal of luminescence Vol. 129; no. 7; pp. 751 - 754 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
01.07.2009
Elsevier |
| Subjects | |
| Online Access | Get full text |
| ISSN | 0022-2313 1872-7883 |
| DOI | 10.1016/j.jlumin.2009.02.008 |
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| Abstract | The emission intensity of phosphors is often subject to concentration quenching after doping of the activator in the host crystal rises above a certain limit. This study describes the preparation of novel phosphors based on tobermorite that do not exhibit concentration quenching. In the preparation of phosphors, Eu
3+ ions are exchanged with intercalated Ca
2+ ions within the tobermorite by dipping in EuCl
3 solution. The emission intensity of the Eu
3+ doped tobermorite increased with increasing Eu/Ca atomic ratio and attained a maximum value of 8.6% for a Eu/Ca atomic ratio of 0.22. Heating of the phosphor at 800
°C resulted in a three-fold improvement in emission intensity. |
|---|---|
| AbstractList | The emission intensity of phosphors is often subject to concentration quenching after doping of the activator in the host crystal rises above a certain limit. This study describes the preparation of novel phosphors based on tobermorite that do not exhibit concentration quenching. In the preparation of phosphors, Eu
3+ ions are exchanged with intercalated Ca
2+ ions within the tobermorite by dipping in EuCl
3 solution. The emission intensity of the Eu
3+ doped tobermorite increased with increasing Eu/Ca atomic ratio and attained a maximum value of 8.6% for a Eu/Ca atomic ratio of 0.22. Heating of the phosphor at 800
°C resulted in a three-fold improvement in emission intensity. |
| Author | Kojima, Yoshiyuki Kamei, Shinnosuke Toyama, Takeshi Nishimiya, Nobuyuki |
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| Cites_doi | 10.1063/1.111832 10.1016/j.jlumin.2005.01.011 10.1016/j.seppur.2005.07.021 10.1016/j.optmat.2006.09.005 10.1016/j.jallcom.2004.07.063 10.1038/177390a0 10.2109/jcersj.108.1261_836 10.1016/0008-8846(86)90067-0 10.1016/j.jlumin.2006.07.022 10.2109/jcersj.110.755 |
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| Keywords | Red-emitting Amorphous Tobermorite Intercalation Phosphor Concentration quenching Impurity density Doping Photoluminescence Heat treatments Europium additions Energy-level transitions Phosphors |
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| SubjectTerms | Amorphous Concentration quenching Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology Intercalation Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Other solid inorganic materials Phosphor Photoluminescence Physics Red-emitting Tobermorite |
| Title | Preparation of novel phosphor using intercalation of tobermorite |
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