Photochemistry of nitrite and nitrate in aqueous solution: a review

It has long been known that the photolysis of nitrite and nitrate solutions results in the formation of OH radicals. The mechanism of NO3− photolysis has been the subject of considerable controversy in the literature, however. This review summarizes the experimental work on NO2− and NO3− photolysis...

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Published in	Journal of photochemistry and photobiology. A, Chemistry. Vol. 128; no. 1-3; pp. 1 - 13
Main Authors	Mack, John, Bolton, James R.
Format	Journal Article
Language	English
Published	Lausanne Elsevier B.V 01.11.1999 Elsevier Science
Subjects	AOT Chemistry Exact sciences and technology General and physical chemistry Hydroxyl radical Nitrate ion Nitrite ion Peroxynitrite Photochemistry Photolysis Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Peroxynitrite Photolysis Nitrate ion AOT Hydroxyl radical Nitrite ion Reaction intermediate Inorganic anion Near ultraviolet radiation Inorganic free radical Nitrites Nitrates Review Kinetics Aqueous solution
Online Access	Get full text
ISSN	1010-6030 1873-2666
DOI	10.1016/S1010-6030(99)00155-0

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Abstract	It has long been known that the photolysis of nitrite and nitrate solutions results in the formation of OH radicals. The mechanism of NO3− photolysis has been the subject of considerable controversy in the literature, however. This review summarizes the experimental work on NO2− and NO3− photolysis in the context of recent advances in the understanding of the chemistry of the peroxynitrite anion (ONOO−) in biological experiments. ONOO− has been found to play a far more significant role in the overall reaction mechanism of NO3− photolysis than had previously been suspected. Research on NO2− and NO3− photolysis, as a pathway to the destruction of organic contaminants in natural waters, is summarized. The possible impact of NO2− and NO3− on Advanced Oxidation Technologies (AOTs), in which OH radicals are used to initiate the destruction of hazardous organic pollutants in drinking water and industrial waste streams, is explored.
AbstractList	It has long been known that the photolysis of nitrite and nitrate solutions results in the formation of OH radicals. The mechanism of NO3− photolysis has been the subject of considerable controversy in the literature, however. This review summarizes the experimental work on NO2− and NO3− photolysis in the context of recent advances in the understanding of the chemistry of the peroxynitrite anion (ONOO−) in biological experiments. ONOO− has been found to play a far more significant role in the overall reaction mechanism of NO3− photolysis than had previously been suspected. Research on NO2− and NO3− photolysis, as a pathway to the destruction of organic contaminants in natural waters, is summarized. The possible impact of NO2− and NO3− on Advanced Oxidation Technologies (AOTs), in which OH radicals are used to initiate the destruction of hazardous organic pollutants in drinking water and industrial waste streams, is explored.
Author	Mack, John Bolton, James R.
Author_xml	– sequence: 1 givenname: John surname: Mack fullname: Mack, John – sequence: 2 givenname: James R. surname: Bolton fullname: Bolton, James R. email: jbolton@julian.uwo.ca
BackLink	http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1220721$$DView record in Pascal Francis
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Keywords	Peroxynitrite Photolysis Nitrate ion AOT Hydroxyl radical Nitrite ion Reaction intermediate Inorganic anion Near ultraviolet radiation Inorganic free radical Nitrites Nitrates Review Kinetics Aqueous solution
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Snippet	It has long been known that the photolysis of nitrite and nitrate solutions results in the formation of OH radicals. The mechanism of NO3− photolysis has been...
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SubjectTerms	AOT Chemistry Exact sciences and technology General and physical chemistry Hydroxyl radical Nitrate ion Nitrite ion Peroxynitrite Photochemistry Photolysis Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Title	Photochemistry of nitrite and nitrate in aqueous solution: a review
URI	https://dx.doi.org/10.1016/S1010-6030(99)00155-0
Volume	128
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