Blends of new, all-aromatic liquid-crystalline polymers and poly(ethylene terephthalate)
Thermal, mechanical, dynamical mechanical and morphological investigations are reported of two series of blends of poly(ethylene terephthalate) (PET) with two nematogenic random polymers synthesized in our laboratory. The nucleant effect of low amounts of the liquid-crystalline component (LCP) is ev...
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Published in | Polymer (Guilford) Vol. 40; no. 7; pp. 1781 - 1789 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
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01.03.1999
Elsevier |
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Abstract | Thermal, mechanical, dynamical mechanical and morphological investigations are reported of two series of blends of poly(ethylene terephthalate) (PET) with two nematogenic random polymers synthesized in our laboratory. The nucleant effect of low amounts of the liquid-crystalline component (LCP) is evidenced by thermal analysis for both polymers. At higher LCP contents this effect disappears but a new influence on the melting enthalpy of PET emerges, although at contents of the random polymer that are remarkably different for the two series of blends. The coupling of mechanical tests with a morphological study allowed elucidation of the reinforcing mechanism of one of the nematogenic polymers and the explanation of the discontinuity in the rise of Young's modulus shown by these blends. |
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AbstractList | Thermal, mechanical, dynamical mechanical and morphological investigations are reported of two series of blends of poly(ethylene terephthalate) (PET) with two nematogenic random polymers synthesized in our laboratory. The nucleant effect of low amounts of the liquid-crystalline component (LCP) is evidenced by thermal analysis for both polymers. At higher LCP contents this effect disappears but a new influence on the melting enthalpy of PET emerges, although at contents of the random polymer that are remarkably different for the two series of blends. The coupling of mechanical tests with a morphological study allowed elucidation of the reinforcing mechanism of one of the nematogenic polymers and the explanation of the discontinuity in the rise of Young's modulus shown by these blends. |
Author | Pisino, R. Trefiletti, V. Carpaneto, L. Lesage, G. |
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Keywords | Aromatic liquid-crystalline polymers Blends Poly(ethylene terephthalate) Ethylene terephthalate polymer Polymer blends Property composition relationship Thermotropic state Mechanical properties Benzoate(hydroxy) copolymer Experimental study Random copolymer Ester copolymer Dynamic mechanical properties Liquid crystal polymers Morphology Aromatic copolymer |
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SubjectTerms | Applied sciences Aromatic liquid-crystalline polymers Blends Exact sciences and technology Mechanical properties Organic polymers Physicochemistry of polymers Poly(ethylene terephthalate) Properties and characterization |
Title | Blends of new, all-aromatic liquid-crystalline polymers and poly(ethylene terephthalate) |
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