Synthesis and selective recognition toward zinc ion of chiral poly(imine-triazole)

• Published in: Journal of polymer science. Part A, Polymer chemistry Vol. 52; no. 16; pp. 2248 - 2257
• Main Authors: Zhou, Jinting, Lu, Wei, Hu, Fangyu, Zhang, Mengyu, Jiang, Liming, Shen, Zhiquan
• Format: Journal Article
• Language: English
• Published: Hoboken, NJ Blackwell Publishing Ltd 15.08.2014; Wiley; Wiley Subscription Services, Inc
• Subjects: Applied sciences; chiral; click reaction; Complexation; Dichroism; Exact sciences and technology; Fluorescence; Fourier transforms; Infrared spectroscopy; Monomers; Organic polymers; Physicochemistry of polymers; Polymerization; Polymers with particular properties; polytriazole; Preparation, kinetics, thermodynamics, mechanism and catalysts; sensors; Spectra; zinc ion; 1,3-Dipolar cycloaddition; Circular dichroism spectrum; Optically active polymer; Propargylic compound; Fluorescence; Metal ion; Schiff base polymer; Chiral compound; polytriazole; Optical properties; Fluorescence detector; chiral; Organic azide; click reaction; Cyclopolymerization; Experimental study; Functional polymer; Organic solution; Cyclopolymer; Ionic selectivity; Triazole derivative polymer; sensors; Medium effect; Preparation; Optical activity; Phenols; Zinc ion

ABSTRACT A novel AB type of clickable monomer, (S)‐2‐[(2‐azido‐1‐phenylethylimino)methyl]‐5‐propargyloxyphenol (AMPP) was designed and polymerized to yield a class of main‐chain chiral poly(imine‐triazole)s through the metal‐free click reaction. With the thermally induced polymerization, the desired...