The effect of adding nano-SiO2 and nano-Al2O3 on properties of high calcium fly ash geopolymer cured at ambient temperature
•Use of nano-SiO2 and nano-Al2O3 as additive enhanced geopolymer property.•Strength increased due to formation of additional CSH/CASH and NASH gel.•Hydration products formed and filled pore to make dense and strong geopolymer. This article presents the effect of adding nano-SiO2 and nano-Al2O3 on th...
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| Published in | Materials & Design Vol. 55; pp. 58 - 65 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English Japanese |
| Published |
Elsevier Ltd
01.03.2014
Elsevier BV |
| Subjects | |
| Online Access | Get full text |
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| Abstract | •Use of nano-SiO2 and nano-Al2O3 as additive enhanced geopolymer property.•Strength increased due to formation of additional CSH/CASH and NASH gel.•Hydration products formed and filled pore to make dense and strong geopolymer.
This article presents the effect of adding nano-SiO2 and nano-Al2O3 on the properties of high calcium fly ash geopolymer pastes. Nano-particles were added to fly ash at the dosages of 0%, 1%, 2%, and 3% by weight. The sodium hydroxide concentration of 10 molars, sodium silicate to sodium hydroxide weight ratio of 2.0, the alkaline liquid/binder ratio of 0.60 and curing at ambient temperature of 23°C were used in all mixtures. The results showed that the use of nano-SiO2 as additive to fly ash results in the decrease of the setting time, while the addition of nano-Al2O3 results in only a slight reduction in setting time. Adding 1–2% nano-particles could improve compressive strength, flexural strength, and elastic modulus of pastes due to the formation of additional calcium silicate hydrate (CSH) or calcium aluminosilicate hydrate (CASH) and sodium aluminosilicate hydrate (NASH) or geopolymer gel in geopolymer matrix. In addition, the additions of both nano-SiO2 and nano-Al2O3 enhances the shear bond strength between concrete substrate and geopolymer. |
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| AbstractList | •Use of nano-SiO2 and nano-Al2O3 as additive enhanced geopolymer property.•Strength increased due to formation of additional CSH/CASH and NASH gel.•Hydration products formed and filled pore to make dense and strong geopolymer.
This article presents the effect of adding nano-SiO2 and nano-Al2O3 on the properties of high calcium fly ash geopolymer pastes. Nano-particles were added to fly ash at the dosages of 0%, 1%, 2%, and 3% by weight. The sodium hydroxide concentration of 10 molars, sodium silicate to sodium hydroxide weight ratio of 2.0, the alkaline liquid/binder ratio of 0.60 and curing at ambient temperature of 23°C were used in all mixtures. The results showed that the use of nano-SiO2 as additive to fly ash results in the decrease of the setting time, while the addition of nano-Al2O3 results in only a slight reduction in setting time. Adding 1–2% nano-particles could improve compressive strength, flexural strength, and elastic modulus of pastes due to the formation of additional calcium silicate hydrate (CSH) or calcium aluminosilicate hydrate (CASH) and sodium aluminosilicate hydrate (NASH) or geopolymer gel in geopolymer matrix. In addition, the additions of both nano-SiO2 and nano-Al2O3 enhances the shear bond strength between concrete substrate and geopolymer. |
| Author | Sata, Vanchai Chindaprasirt, Prinya Hanjitsuwan, Sakonwan Hatanaka, Shigemitsu Phoo-ngernkham, Tanakorn |
| Author_xml | – sequence: 1 givenname: Tanakorn surname: Phoo-ngernkham fullname: Phoo-ngernkham, Tanakorn organization: Sustainable Infrastructure Research and Development Center, Dept. of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002, Thailand – sequence: 2 givenname: Prinya surname: Chindaprasirt fullname: Chindaprasirt, Prinya email: prinya@kku.ac.th organization: Sustainable Infrastructure Research and Development Center, Dept. of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002, Thailand – sequence: 3 givenname: Vanchai surname: Sata fullname: Sata, Vanchai organization: Sustainable Infrastructure Research and Development Center, Dept. of Civil Engineering, Faculty of Engineering, Khon Kaen University, Khon Kaen 40002, Thailand – sequence: 4 givenname: Sakonwan surname: Hanjitsuwan fullname: Hanjitsuwan, Sakonwan organization: Program of Civil Technology, Faculty of Industrial Technology, Lampang Rajabhat University, Lampang 52100, Thailand – sequence: 5 givenname: Shigemitsu surname: Hatanaka fullname: Hatanaka, Shigemitsu organization: Dept. of Architecture, Faculty of Engineering, Mie University, Mie 514-8504, Japan |
| BackLink | https://cir.nii.ac.jp/crid/1870302167970240640$$DView record in CiNii |
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additive publication-title: Mater Des doi: 10.1016/j.matdes.2013.07.018 – volume: 15 start-page: 943 year: 1985 ident: 10.1016/j.matdes.2013.09.049_b0135 article-title: Properties of Portland cement–silica fume pastes. 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| Snippet | •Use of nano-SiO2 and nano-Al2O3 as additive enhanced geopolymer property.•Strength increased due to formation of additional CSH/CASH and NASH gel.•Hydration... |
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| SubjectTerms | Compressive strength Flexural strength Geopolymer Nano-Al2O3 Nano-SiO2 Shear bond strength |
| Title | The effect of adding nano-SiO2 and nano-Al2O3 on properties of high calcium fly ash geopolymer cured at ambient temperature |
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