Critical review on negative emerging contaminant removal efficiency of wastewater treatment systems: Concept, consistency and consequences

•Negative contaminant removal (NR) i.e. higher concentrations in effluent is globally prevalent.•No treatment systems avoid negative removal for pharmaceutical personal care products.•Conventional WWTPs illustrated the highest NR for Carbamazepine, and Carbadox.•Globally, NR efficiencies for emergin...

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Published inBioresource technology Vol. 352; p. 127054
Main Authors Kumar, Manish, Ngasepam, Jayalaxmi, Dhangar, Kiran, Mahlknecht, Jurgen, Manna, Suvendu
Format Journal Article
LanguageEnglish
Published England Elsevier Ltd 01.05.2022
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Abstract •Negative contaminant removal (NR) i.e. higher concentrations in effluent is globally prevalent.•No treatment systems avoid negative removal for pharmaceutical personal care products.•Conventional WWTPs illustrated the highest NR for Carbamazepine, and Carbadox.•Globally, NR efficiencies for emerging contaminants varied between −0.2 to 1174%.•Separation processes, conjugation–deconjugation, biotransformation, and leaching lead to NR. Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation–deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.
AbstractList Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation-deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.
Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation-deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation-deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.
Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation–deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.
•Negative contaminant removal (NR) i.e. higher concentrations in effluent is globally prevalent.•No treatment systems avoid negative removal for pharmaceutical personal care products.•Conventional WWTPs illustrated the highest NR for Carbamazepine, and Carbadox.•Globally, NR efficiencies for emerging contaminants varied between −0.2 to 1174%.•Separation processes, conjugation–deconjugation, biotransformation, and leaching lead to NR. Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct formation, and dynamic partitioning. Negative contaminant removal i.e., higher concentrations (up to 5731%) of these ECs in the effluent with respect to the influent sampled on the same occasions, is globally prevalent in almost all types of treatment systems. Conventional WWTPs showed the highest negative removal (NR) for Carbamazepine, and Carbadox. Conjugation–deconjugation, types of WWTPs, transformations, leaching, operational parameters, sampling schemes, and nature of substance governs the NR efficiencies. Among the various categories of micropollutants, pesticides and beta-blockers are reported to exhibit the maximum percentage of NR, posing threat to human and the environment. With > 200% of NR for beta-blockers, low blood-pressure related symptoms may likely to get more prevalent in the near future. Study red-flags this phenomenon of negative removal that needs urgent attention.
ArticleNumber 127054
Author Manna, Suvendu
Ngasepam, Jayalaxmi
Mahlknecht, Jurgen
Dhangar, Kiran
Kumar, Manish
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  givenname: Jurgen
  surname: Mahlknecht
  fullname: Mahlknecht, Jurgen
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  fullname: Manna, Suvendu
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Keywords Biodegradation
Pharmaceutical and personal care products
Negative removal
Process efficacy
Emerging pollutants
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Snippet •Negative contaminant removal (NR) i.e. higher concentrations in effluent is globally prevalent.•No treatment systems avoid negative removal for pharmaceutical...
Emerging contaminants (ECs) are not completely removed by wastewater treatment owing to their capabilities of making complexes, toxic derivatives, byproduct...
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SubjectTerms beta-adrenergic antagonists
Biodegradation
blood pressure
byproducts
carbadox
Emerging pollutants
humans
Negative removal
Pharmaceutical and personal care products
pollutants
Process efficacy
toxicity
wastewater treatment
Title Critical review on negative emerging contaminant removal efficiency of wastewater treatment systems: Concept, consistency and consequences
URI https://dx.doi.org/10.1016/j.biortech.2022.127054
https://www.ncbi.nlm.nih.gov/pubmed/35351567
https://www.proquest.com/docview/2645473413
https://www.proquest.com/docview/2648869462
Volume 352
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