Theoretical consideration on composite oxide scales and coatings
The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings w...
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Published in | Journal of rare earths Vol. 31; no. 5; pp. 435 - 440 |
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Format | Journal Article |
Language | English |
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Elsevier B.V
01.05.2013
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Abstract | The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the A1203 scales or coatings doped with 3(203 and ZrO2 (or YSZ)-A1203 composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and A1203 phase could seal the alloy substrate well In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived. |
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AbstractList | The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the Al2O3 scales or coatings doped with Y2O3 and ZrO2 (or YSZ)-Al2O3 composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and Al2O3 phase could seal the alloy substrate well. In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived.
Schematic diagrams of two types of ZrO2 (or YSZ)-Al2O3 composite coatings The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the Al2O3 scales or coatings doped with Y2O3 and ZrO2 (or YSZ)-Al2O3 composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and Al2O3 phase could seal the alloy substrate well. In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived. The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the Al(2)O(3) scales or coatings doped with Y(2)O(3) and ZrO(2) (or YSZ)-Al(2)O(3) composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and Al(2)O(3) phase could seal the alloy substrate well. In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived. The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the A1203 scales or coatings doped with 3(203 and ZrO2 (or YSZ)-A1203 composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and A1203 phase could seal the alloy substrate well In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived. |
Author | 何业东 高唯 |
AuthorAffiliation | Beijing Key Laboratory for Corrosion-Erosion and Surface Technology, University of Science and Technology Beijing, Beijing 100083, China Engineering School The University of Auckland, Auckland P.B. 92019, New Zealand |
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Cites_doi | 10.1016/j.matchemphys.2010.05.047 10.1016/j.apsusc.2011.03.010 10.1016/j.surfcoat.2009.08.034 10.1016/S0167-577X(02)00842-X 10.4028/www.scientific.net/MSF.522-523.393 10.1007/s11085-011-9236-8 10.1016/0921-5093(95)09798-8 10.1016/j.apsusc.2012.02.081 10.1016/j.jeurceramsoc.2010.08.010 10.1016/0921-5093(89)90731-4 10.1364/JOSA.11.000233 10.1016/S0142-9612(01)00206-X 10.1016/0921-5093(89)90730-2 10.1016/S0955-2219(02)00043-2 10.1007/s11085-010-9210-x 10.1111/j.1151-2916.1997.tb02919.x 10.1016/0010-938X(84)90051-9 10.1016/S0042-207X(00)00269-4 10.1016/j.jeurceramsoc.2005.12.008 10.1016/j.apsusc.2013.04.039 10.1016/S0266-3538(01)00159-2 10.1016/j.surfcoat.2005.11.111 |
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Notes | 11-2788/TF The present paper discussed some fundamental aspects on composite oxide scales and coatings for protection of alloys from high temperature oxidation, the related thermodynamic conditions, special mechanical characteristics and a sealing mechanism. It was proposed that the oxide scales and coatings with a composite structure should possess superior mechanical properties than that with a single phase oxide. It also showed that the A1203 scales or coatings doped with 3(203 and ZrO2 (or YSZ)-A1203 composite coatings possessed superior properties at high temperatures. In such composite oxide scales and coatings, the fracture resistance of the scales was increased by the toughening effect, the thermal stress was decreased owing to the increase of thermal-expansion coefficients, and A1203 phase could seal the alloy substrate well In addition, the kinetic equation of thermal growth oxide on alloy covered with composite oxide coatings was derived. rare earth oxides; composite oxide scales; composite oxide coatings; high-temperature oxidation of alloys HE Yedong, GAO Wei(1. Beijing Key Laboratory for Corrosion-Erosion and Surface Technology, University of Science and Technology Beijing, Beijing 100083, China; 2. Engineering School The University of Auckland, Auckland P.B. 92019, New Zealand) ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 ObjectType-Article-1 ObjectType-Feature-2 |
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SubjectTerms | Alloys Aluminum oxide Coatings composite oxide coatings composite oxide scales high-temperature oxidation of alloys Oxides Rare earth metals rare earth oxides Scale (corrosion) Sealing Seals Zirconium dioxide 复合氧化膜 复合涂层 密封机构 机械特性 涂料保护 热力学条件 热膨胀系数 高温氧化 |
Title | Theoretical consideration on composite oxide scales and coatings |
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