Enhancing polyurethane properties via soft segment crystallization

Semi-crystalline polyester diols with relatively high melting points and enthalpies of crystallization are shown to form nearly co-continuous lamellar structures in thermoplastic polyurethanes using polyether soft segments. This high aspect ratio crystalline structure results in materials with excep...

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Published inPolymer (Guilford) Vol. 46; no. 23; pp. 10158 - 10166
Main Authors Sonnenschein, Mark F., Lysenko, Zenon, Brune, Douglas A., Wendt, Benjamin L., Schrock, Alan K.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 14.11.2005
Elsevier
Subjects
Applied sciences
Crystallization
Elastomer
Exact sciences and technology
Mechanical properties
Organic polymers
Physicochemistry of polymers
Polyurethane
Properties and characterization
Polyurethane
Elastomer
Crystallization
Elastic modulus
Polyurethune
Mechanical properties
Composition effect
Experimental study
Polyurethane elastomer
Compressive stress
Lamellar structure
Esterurethane polymer
Morphology
Supramolecular structure
Foam(plastics)
Property structure relationship
Tear strength
Etherurethane polymer
Mechanical hysteresis
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Abstract Semi-crystalline polyester diols with relatively high melting points and enthalpies of crystallization are shown to form nearly co-continuous lamellar structures in thermoplastic polyurethanes using polyether soft segments. This high aspect ratio crystalline structure results in materials with exceptional tensile and elastic properties compared to materials made with conventional semi-crystalline soft segments such as polycaprolactone or polybutylene adipate. Additions of semi-crystalline soft segment to foam formulations also result in increased hardness measured by standard foam hardness tests. Halpin–Tsai and percolation model analyses of the results suggest that the crystalline regions exert a global influence on the elastomer structure.
AbstractList Semi-crystalline polyester diols with relatively high melting points and enthalpies of crystallization are shown to form nearly co-continuous lamellar structures in thermoplastic polyurethanes using polyether soft segments. This high aspect ratio crystalline structure results in materials with exceptional tensile and elastic properties compared to materials made with conventional semi-crystalline soft segments such as polycaprolactone or polybutylene adipate. Additions of semi-crystalline soft segment to foam formulations also result in increased hardness measured by standard foam hardness tests. Halpin-Tsai and percolation model analyses of the results suggest that the crystalline regions exert a global influence on the elastomer structure.
Author Lysenko, Zenon
Wendt, Benjamin L.
Brune, Douglas A.
Sonnenschein, Mark F.
Schrock, Alan K.
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  givenname: Alan K.
  surname: Schrock
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Issue 23
Keywords Polyurethane
Elastomer
Crystallization
Elastic modulus
Polyurethune
Mechanical properties
Composition effect
Experimental study
Polyurethane elastomer
Compressive stress
Lamellar structure
Esterurethane polymer
Morphology
Supramolecular structure
Foam(plastics)
Property structure relationship
Tear strength
Etherurethane polymer
Mechanical hysteresis
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Snippet Semi-crystalline polyester diols with relatively high melting points and enthalpies of crystallization are shown to form nearly co-continuous lamellar...
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SubjectTerms Applied sciences
Crystallization
Elastomer
Exact sciences and technology
Mechanical properties
Organic polymers
Physicochemistry of polymers
Polyurethane
Properties and characterization
Title Enhancing polyurethane properties via soft segment crystallization
URI https://dx.doi.org/10.1016/j.polymer.2005.08.006
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