High-capacity adsorption of aniline using surface modification of lignocellulose-biomass jute fibers
[Display omitted] •The jute fiber was modified as an innovative biosorbent for aniline removal.•The rapid modification was carried out using PMDA in microwave reactor.•Adsorption process fits Langmuir isotherm and pseudo-second-order kinetic model.•Modified jute fiber (MJF) adsorbed aniline up to 16...
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| Published in | Bioresource technology Vol. 193; pp. 507 - 512 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Elsevier Ltd
01.10.2015
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| Subjects | |
| Online Access | Get full text |
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| Abstract | [Display omitted]
•The jute fiber was modified as an innovative biosorbent for aniline removal.•The rapid modification was carried out using PMDA in microwave reactor.•Adsorption process fits Langmuir isotherm and pseudo-second-order kinetic model.•Modified jute fiber (MJF) adsorbed aniline up to 169.49mg/g.•Spent MJF can be effectively regenerated by HCl solution.
Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The characterization of the biosorbent was investigated by SEM, BET and FT-IR analysis to discuss the adsorption mechanism. The studies of various factors influencing the adsorption behavior indicated that the optimum dosage for aniline adsorption was 3g/L, the maximum adsorption capacity was observed at pH 7.0 and the adsorption process is spontaneous and endothermic. The aniline adsorption follows the pseudo second order kinetic model and Langmuir isotherm model. Moreover, the biosorbent could be regenerated through the desorption of aniline by using 0.5M HCl solution, and the adsorption capacity after regeneration is even higher than that of virgin MJF. All these results prove MJF is a promising adsorbent for aniline removal in wastewater. |
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| AbstractList | Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The characterization of the biosorbent was investigated by SEM, BET and FT-IR analysis to discuss the adsorption mechanism. The studies of various factors influencing the adsorption behavior indicated that the optimum dosage for aniline adsorption was 3g/L, the maximum adsorption capacity was observed at pH 7.0 and the adsorption process is spontaneous and endothermic. The aniline adsorption follows the pseudo second order kinetic model and Langmuir isotherm model. Moreover, the biosorbent could be regenerated through the desorption of aniline by using 0.5M HCl solution, and the adsorption capacity after regeneration is even higher than that of virgin MJF. All these results prove MJF is a promising adsorbent for aniline removal in wastewater. [Display omitted] •The jute fiber was modified as an innovative biosorbent for aniline removal.•The rapid modification was carried out using PMDA in microwave reactor.•Adsorption process fits Langmuir isotherm and pseudo-second-order kinetic model.•Modified jute fiber (MJF) adsorbed aniline up to 169.49mg/g.•Spent MJF can be effectively regenerated by HCl solution. Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The characterization of the biosorbent was investigated by SEM, BET and FT-IR analysis to discuss the adsorption mechanism. The studies of various factors influencing the adsorption behavior indicated that the optimum dosage for aniline adsorption was 3g/L, the maximum adsorption capacity was observed at pH 7.0 and the adsorption process is spontaneous and endothermic. The aniline adsorption follows the pseudo second order kinetic model and Langmuir isotherm model. Moreover, the biosorbent could be regenerated through the desorption of aniline by using 0.5M HCl solution, and the adsorption capacity after regeneration is even higher than that of virgin MJF. All these results prove MJF is a promising adsorbent for aniline removal in wastewater. Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The characterization of the biosorbent was investigated by SEM, BET and FT-IR analysis to discuss the adsorption mechanism. The studies of various factors influencing the adsorption behavior indicated that the optimum dosage for aniline adsorption was 3g/L, the maximum adsorption capacity was observed at pH 7.0 and the adsorption process is spontaneous and endothermic. The aniline adsorption follows the pseudo second order kinetic model and Langmuir isotherm model. Moreover, the biosorbent could be regenerated through the desorption of aniline by using 0.5M HCl solution, and the adsorption capacity after regeneration is even higher than that of virgin MJF. All these results prove MJF is a promising adsorbent for aniline removal in wastewater.Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The characterization of the biosorbent was investigated by SEM, BET and FT-IR analysis to discuss the adsorption mechanism. The studies of various factors influencing the adsorption behavior indicated that the optimum dosage for aniline adsorption was 3g/L, the maximum adsorption capacity was observed at pH 7.0 and the adsorption process is spontaneous and endothermic. The aniline adsorption follows the pseudo second order kinetic model and Langmuir isotherm model. Moreover, the biosorbent could be regenerated through the desorption of aniline by using 0.5M HCl solution, and the adsorption capacity after regeneration is even higher than that of virgin MJF. All these results prove MJF is a promising adsorbent for aniline removal in wastewater. |
| Author | Wang, Peng Jiang, Jiping Hu, Qi Pan, Hongyu Gao, Da-Wen |
| Author_xml | – sequence: 1 givenname: Da-Wen surname: Gao fullname: Gao, Da-Wen email: gaodw@hit.edu.cn organization: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China – sequence: 2 givenname: Qi surname: Hu fullname: Hu, Qi organization: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China – sequence: 3 givenname: Hongyu surname: Pan fullname: Pan, Hongyu organization: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China – sequence: 4 givenname: Jiping surname: Jiang fullname: Jiang, Jiping organization: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China – sequence: 5 givenname: Peng surname: Wang fullname: Wang, Peng email: pwang73@vip.sina.com organization: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26172392$$D View this record in MEDLINE/PubMed |
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•The jute fiber was modified as an innovative biosorbent for aniline removal.•The rapid modification was carried out using PMDA in microwave... Pyromellitic dianhydride (PMDA) modified jute fiber (MJF) were prepared with microwave treatment to generate a biosorbent for aniline removal. The... |
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| SubjectTerms | adsorbents Adsorption aniline Aniline adsorption Aniline Compounds - chemistry Benzoates - chemistry Biomass Biosorbent biosorbents Corchorus - chemistry desorption Fourier transform infrared spectroscopy hydrochloric acid Hydrogen-Ion Concentration Isotherms jute Jute fiber Kinetics Lignin - chemistry Microwave microwave treatment scanning electron microscopy sorption isotherms Surface Properties Temperature Time Factors wastewater |
| Title | High-capacity adsorption of aniline using surface modification of lignocellulose-biomass jute fibers |
| URI | https://dx.doi.org/10.1016/j.biortech.2015.06.138 https://www.ncbi.nlm.nih.gov/pubmed/26172392 https://www.proquest.com/docview/1698956514 https://www.proquest.com/docview/1846339316 |
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