A new ring-like arrangement of vanadyl(IV) groups bridged by monodentate alkoxides: cyclo-decakis(μ-cyclohexylmethanolato)pentakis[oxidovanadium(IV)]
The pentanuclear title compound, [V5(C7H13O)10O5], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V5O15]5− on the ba...
Saved in:
Published in | Acta crystallographica. Section C, Crystal structure communications Vol. 68; no. 12; pp. m353 - m355 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
5 Abbey Square, Chester, Cheshire CH1 2HU, England
International Union of Crystallography
01.12.2012
Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | The pentanuclear title compound, [V5(C7H13O)10O5], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V5O15]5− on the basis of 51V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair‐like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. |
---|---|
AbstractList | The pentanuclear title compound, [V5(C7H13O)10O5], has a metal-oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V5O15]5- on the basis of 51V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair-like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. The pentanuclear title compound, [V5(C7H13O)10O5], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V5O15]5− on the basis of 51V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair‐like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. The pentanuclear title compound, [V(5)(C(7)H(13)O)(10)O(5)], has a metal-oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V(5)O(15)](5-) on the basis of (51)V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair-like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. The pentanuclear title compound, [V5(C7H13O)10O5], has a metal-oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V5O15]5- on the basis of 51V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair-like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. [PUBLICATION ABSTRACT] The pentanuclear title compound, [V 5 (C 7 H 13 O) 10 O 5 ], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of cyclohexylmethanolate ligands. This particular ring topology is new to oxovanadium(IV) chemistry and resembles the structure proposed for [V 5 O 15 ] 5− on the basis of 51 V NMR studies in aqueous solution. The bulky cyclohexylmethanolate ligands adopt chair-like conformations and project outwards from the central cyclic core. The title compound crystallizes in a centrosymmetric triclinic unit cell, which contains four independent but chemically identical molecules in the asymmetric unit. The crystal structure is devoid of any significant intermolecular interactions. |
Author | Stinghen, Danilo Soares, Jaísa F. Nunes, Giovana G. Ferreira, Janaina G. |
Author_xml | – sequence: 1 givenname: Danilo surname: Stinghen fullname: Stinghen, Danilo organization: Departamento de Química, Universidade Federal do Paraná, Centro Politécnico, Jardim das Américas, 81530-900 Curitiba PR, Brazil – sequence: 2 givenname: Janaina G. surname: Ferreira fullname: Ferreira, Janaina G. organization: Departamento de Química, Universidade Federal do Paraná, Centro Politécnico, Jardim das Américas, 81530-900 Curitiba PR, Brazil – sequence: 3 givenname: Giovana G. surname: Nunes fullname: Nunes, Giovana G. organization: Departamento de Química, Universidade Federal do Paraná, Centro Politécnico, Jardim das Américas, 81530-900 Curitiba PR, Brazil – sequence: 4 givenname: Jaísa F. surname: Soares fullname: Soares, Jaísa F. organization: Departamento de Química, Universidade Federal do Paraná, Centro Politécnico, Jardim das Américas, 81530-900 Curitiba PR, Brazil |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/23221246$$D View this record in MEDLINE/PubMed |
BookMark | eNqNkcFu1DAQhi1URLeFB-CCInHZHgJjO7ETbqsVu61U4ACUIoQsJ5ls003srZ3QzYvwNDxDn6lJt_QABzhZ8nzfPxr9B2TPWIOEPKfwilKQrz8ChYRJoJRBFEtgj8iECoAwlnG6RybjOBzn--TA-0sAYIzxJ2SfccYoi8SE_JwFBq8DV5lVWFdrDLRz2qywQdMGtgx-aKOLvp6enB0FK2e7jQ8yVxUrLIKsDxprbDGQuh3Eem23VYH-TZD3eW3DAnO9rvz05ld493GB275usL3Qxta6tUeb0RyIb6Nn7zZVXTOu-v6UPC517fHZ_XtIPi_efpofh6cflifz2WmYR0DTkPMEdQqxLmSRiRIF6DItERkIDTmnstA8iWKUkCWRFhHLkpTHZZxHSZLSLOGHZLrL3Th71aFvVVP5HOtaG7SdV5QlXDIKEfwHymUMXKRyQF_-gV7azpnhEEU5FYJBHImBojsqd9Z7h6XauKrRrlcU1Niv-qvfwXlxn9xlDRYPxu9CByDZAddVjf2_E9Xs63yx5Eymgxru1Mq3uH1QtVsrIYfb1Jf3SzU_P3-3oPRMHfNbocDCqw |
Cites_doi | 10.1088/0953-8984/21/32/323202 10.1021/ic200638f 10.1016/j.poly.2006.02.020 10.1021/ic961045x 10.1590/S0100-40422010000100011 10.1107/S0108767307043930 10.1107/S0108270102013008 10.1016/j.jinorgbio.2008.11.010 10.1107/S0021889812001124 10.1021/bk-1983-0211 10.1039/b915539b 10.1002/cctc.201100239 10.1107/S0021889897003117 10.1016/j.ccr.2009.01.031 10.3891/acta.chem.scand.48-0533 10.1039/c0dt01547d 10.1016/j.ccr.2011.02.013 10.1016/j.ccr.2011.01.041 10.1107/S0021889810022120 10.1021/ic970868z 10.1016/j.apcata.2009.05.021 10.1021/ar6000389 10.1039/c0ee00026d 10.1039/cs9962500001 10.1016/S1387-7003(00)00050-2 10.1590/S0103-50532009000400005 10.1016/j.inoche.2008.04.037 |
ContentType | Journal Article |
Copyright | International Union of Crystallography, 2012 |
Copyright_xml | – notice: International Union of Crystallography, 2012 |
DBID | BSCLL NPM AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M 7X8 |
DOI | 10.1107/S0108270112045702 |
DatabaseName | Istex PubMed CrossRef Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace MEDLINE - Academic |
DatabaseTitle | PubMed CrossRef Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX MEDLINE - Academic |
DatabaseTitleList | Materials Research Database PubMed Materials Research Database MEDLINE - Academic CrossRef |
Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry |
EISSN | 1600-5759 |
EndPage | m355 |
ExternalDocumentID | 2916098341 10_1107_S0108270112045702 23221246 AYCFG3279 ark_67375_WNG_CXXMF11V_H |
Genre | article Journal Article |
GroupedDBID | --- -ET -~X .3N .GA .Y3 05W 10A 1OB 1OC 23M 2WC 33P 3SF 4.4 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5HH 5LA 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABHUG ABPTK ABTOO ABWRO ACAHQ ACBWZ ACCFJ ACCZN ACFBH ACGFS ACGOD ACIWK ACNCT ACPOU ACXBN ACXME ACXQS ADAWD ADBBV ADDAD ADEOM ADIZJ ADMGS ADZOD AEEZP AEIGN AEIMD AEQDE AEUQT AEUYR AFBPY AFEBI AFFPM AFGKR AFPWT AFVGU AFZJQ AGJLS AHBTC AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ASPBG ATUGU AUFTA AVWKF AZBYB AZFZN AZVAB BAFTC BDRZF BHBCM BMNLL BNHUX BROTX BRXPI BSCLL BY8 COF CS3 D-E D-F DCZOG DPXWK DR2 DRFUL DRSTM EBS EJD F00 F01 F04 F5P FEDTE G-S G.N GODZA H.T H.X HF~ HH5 HVGLF HZI HZ~ IHE IX1 J0M K48 LATKE LC2 LC3 LEEKS LITHE LOXES LP6 LP7 LUTES LW6 LYRES MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ O66 P2W P2X P4D PQQKQ Q.N Q11 QB0 R.K RCJ RNS ROL RX1 SJN SUPJJ TN5 UB1 UPT V2E V8K W8V W99 WBFHL WBKPD WIH WIK WOHZO WQJ WRC WYISQ XG1 ZCG ~02 ~IA ~WT 0R~ 186 1Y6 31~ 8WZ A6W ABDBF ABEML ACSCC AI. AITYG BTSUX CAG ESX HGLYW I-F MVM NEJ PALCI RIWAO RJQFR TUS VH1 XOL NPM AAYXX CITATION 7SR 7U5 8BQ 8FD JG9 L7M 7X8 |
ID | FETCH-LOGICAL-c4019-338ea905ad7db6fe60af9fee206a0c317da3845e70b84a642b8935f5c48891b83 |
IEDL.DBID | DR2 |
ISSN | 0108-2701 |
IngestDate | Fri Aug 16 05:31:41 EDT 2024 Fri Aug 16 22:40:56 EDT 2024 Thu Aug 29 12:25:31 EDT 2024 Fri Aug 23 01:46:52 EDT 2024 Sat Sep 28 07:51:14 EDT 2024 Sat Aug 24 01:18:55 EDT 2024 Wed Jan 17 05:05:15 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 12 |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c4019-338ea905ad7db6fe60af9fee206a0c317da3845e70b84a642b8935f5c48891b83 |
Notes | ArticleID:AYCFG3279 ark:/67375/WNG-CXXMF11V-H istex:071DA6AB9969581D8FA7695B6004323D31155ACF ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 ObjectType-Article-2 ObjectType-Feature-1 |
PMID | 23221246 |
PQID | 1316620546 |
PQPubID | 33533 |
ParticipantIDs | proquest_miscellaneous_1283721040 proquest_miscellaneous_1237503697 proquest_journals_1316620546 crossref_primary_10_1107_S0108270112045702 pubmed_primary_23221246 wiley_primary_10_1107_S0108270112045702_AYCFG3279 istex_primary_ark_67375_WNG_CXXMF11V_H |
PublicationCentury | 2000 |
PublicationDate | December 2012 |
PublicationDateYYYYMMDD | 2012-12-01 |
PublicationDate_xml | – month: 12 year: 2012 text: December 2012 |
PublicationDecade | 2010 |
PublicationPlace | 5 Abbey Square, Chester, Cheshire CH1 2HU, England |
PublicationPlace_xml | – name: 5 Abbey Square, Chester, Cheshire CH1 2HU, England – name: United States – name: Chester |
PublicationTitle | Acta crystallographica. Section C, Crystal structure communications |
PublicationTitleAlternate | Acta Cryst. C |
PublicationYear | 2012 |
Publisher | International Union of Crystallography Wiley Subscription Services, Inc |
Publisher_xml | – name: International Union of Crystallography – name: Wiley Subscription Services, Inc |
References | Mizuno (fg3279_bb19) 2011; 255 Antiñolo (fg3279_bb1) 2012; 4 Farrugia (fg3279_bb11) 1997; 30 Wang (fg3279_bb27) 2004; 23 Mehrotra (fg3279_bb18) 1996; 25 Joniakova (fg3279_bb16) 2006; 25 fg3279_bb26 Helwani (fg3279_bb15) 2009; 363 Aureliano (fg3279_bb2) 2009; 103 Boettcher (fg3279_bb3) 2007; 40 Rosenthal (fg3279_bb24) 2008; 11 Freitas (fg3279_bb13) 2010; 33 Sheldrick (fg3279_bb25) 2008; 64 Fernandez de Luis (fg3279_bb12) 2010; 12 Evans (fg3279_bb10) 1994; 48 Zhang (fg3279_bb31) 1997; 36 Westrip (fg3279_bb28) 2010; 43 Westrup (fg3279_bb29) 2011; 40 Nakano (fg3279_bb20) 2002; 58 Crans (fg3279_bb9) 2009; 253 fg3279_bb5 Kessler (fg3279_bb17) 2000; 3 fg3279_bb7 Hayashi (fg3279_bb14) 2011; 255 Perucchi (fg3279_bb22) 2009; 21 Burla (fg3279_bb6) 2012; 45 Cornman (fg3279_bb8) 1997; 36 fg3279_bb4 Reis (fg3279_bb23) 2009; 20 Wu (fg3279_bb30) 2010; 3 Nishio (fg3279_bb21) 2011; 51 |
References_xml | – volume: 21 start-page: 323202 year: 2009 ident: fg3279_bb22 publication-title: J. Phys. Condens. Matter doi: 10.1088/0953-8984/21/32/323202 contributor: fullname: Perucchi – volume: 51 start-page: 784 year: 2011 ident: fg3279_bb21 publication-title: Inorg. Chem. doi: 10.1021/ic200638f contributor: fullname: Nishio – volume: 25 start-page: 2491 year: 2006 ident: fg3279_bb16 publication-title: Polyhedron doi: 10.1016/j.poly.2006.02.020 contributor: fullname: Joniakova – volume: 36 start-page: 2159 year: 1997 ident: fg3279_bb31 publication-title: Inorg. Chem. doi: 10.1021/ic961045x contributor: fullname: Zhang – ident: fg3279_bb5 – volume: 33 start-page: 52 year: 2010 ident: fg3279_bb13 publication-title: Quim. Nova doi: 10.1590/S0100-40422010000100011 contributor: fullname: Freitas – volume: 64 start-page: 112 year: 2008 ident: fg3279_bb25 publication-title: Acta Cryst. A doi: 10.1107/S0108767307043930 contributor: fullname: Sheldrick – volume: 58 start-page: m464 year: 2002 ident: fg3279_bb20 publication-title: Acta Cryst. C doi: 10.1107/S0108270102013008 contributor: fullname: Nakano – volume: 103 start-page: 536 year: 2009 ident: fg3279_bb2 publication-title: J. Inorg. Biochem. doi: 10.1016/j.jinorgbio.2008.11.010 contributor: fullname: Aureliano – volume: 23 start-page: 655 year: 2004 ident: fg3279_bb27 publication-title: Chin. J. Struct. Chem. contributor: fullname: Wang – volume: 45 start-page: 357 year: 2012 ident: fg3279_bb6 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889812001124 contributor: fullname: Burla – ident: fg3279_bb7 doi: 10.1021/bk-1983-0211 – volume: 12 start-page: 1880 year: 2010 ident: fg3279_bb12 publication-title: CrystEngComm doi: 10.1039/b915539b contributor: fullname: Fernandez de Luis – volume: 4 start-page: 123 year: 2012 ident: fg3279_bb1 publication-title: ChemCatChem doi: 10.1002/cctc.201100239 contributor: fullname: Antiñolo – volume: 30 start-page: 565 year: 1997 ident: fg3279_bb11 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889897003117 contributor: fullname: Farrugia – ident: fg3279_bb4 – volume: 253 start-page: 2178 year: 2009 ident: fg3279_bb9 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2009.01.031 contributor: fullname: Crans – volume: 48 start-page: 533 year: 1994 ident: fg3279_bb10 publication-title: Acta Chem. Scand. doi: 10.3891/acta.chem.scand.48-0533 contributor: fullname: Evans – volume: 40 start-page: 3198 year: 2011 ident: fg3279_bb29 publication-title: Dalton Trans. doi: 10.1039/c0dt01547d contributor: fullname: Westrup – volume: 255 start-page: 2270 year: 2011 ident: fg3279_bb14 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2011.02.013 contributor: fullname: Hayashi – volume: 255 start-page: 2358 year: 2011 ident: fg3279_bb19 publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2011.01.041 contributor: fullname: Mizuno – volume: 43 start-page: 920 year: 2010 ident: fg3279_bb28 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889810022120 contributor: fullname: Westrip – volume: 36 start-page: 6401 year: 1997 ident: fg3279_bb8 publication-title: Inorg. Chem. doi: 10.1021/ic970868z contributor: fullname: Cornman – volume: 363 start-page: 1 year: 2009 ident: fg3279_bb15 publication-title: Appl. Catal. Gen. doi: 10.1016/j.apcata.2009.05.021 contributor: fullname: Helwani – volume: 40 start-page: 784 year: 2007 ident: fg3279_bb3 publication-title: Acc. Chem. Res. doi: 10.1021/ar6000389 contributor: fullname: Boettcher – volume: 3 start-page: 1191 year: 2010 ident: fg3279_bb30 publication-title: Energy Environ. Sci. doi: 10.1039/c0ee00026d contributor: fullname: Wu – volume: 25 start-page: 1 year: 1996 ident: fg3279_bb18 publication-title: Chem. Soc. Rev. doi: 10.1039/cs9962500001 contributor: fullname: Mehrotra – volume: 3 start-page: 203 year: 2000 ident: fg3279_bb17 publication-title: Inorg. Chem. Commun. doi: 10.1016/S1387-7003(00)00050-2 contributor: fullname: Kessler – volume: 20 start-page: 613 year: 2009 ident: fg3279_bb23 publication-title: J. Braz. Chem. Soc. doi: 10.1590/S0103-50532009000400005 contributor: fullname: Reis – volume: 11 start-page: 918 year: 2008 ident: fg3279_bb24 publication-title: Inorg. Chem. Commun. doi: 10.1016/j.inoche.2008.04.037 contributor: fullname: Rosenthal – ident: fg3279_bb26 |
SSID | ssj0002223 |
Score | 1.9664271 |
Snippet | The pentanuclear title compound, [V5(C7H13O)10O5], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of... The pentanuclear title compound, [V(5)(C(7)H(13)O)(10)O(5)], has a metal-oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of... The pentanuclear title compound, [V 5 (C 7 H 13 O) 10 O 5 ], has a metal–oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of... The pentanuclear title compound, [V5(C7H13O)10O5], has a metal-oxygen core that consists of five vanadyl(IV) centres bridged by the O atoms of... |
SourceID | proquest crossref pubmed wiley istex |
SourceType | Aggregation Database Index Database Publisher |
StartPage | m353 |
SubjectTerms | Alkoxides Aqueous solutions Asymmetry Crystal structure Crystallization Ligands Positioning Unit cell |
Title | A new ring-like arrangement of vanadyl(IV) groups bridged by monodentate alkoxides: cyclo-decakis(μ-cyclohexylmethanolato)pentakis[oxidovanadium(IV)] |
URI | https://api.istex.fr/ark:/67375/WNG-CXXMF11V-H/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1107%2FS0108270112045702 https://www.ncbi.nlm.nih.gov/pubmed/23221246 https://www.proquest.com/docview/1316620546/abstract/ https://search.proquest.com/docview/1237503697 https://search.proquest.com/docview/1283721040 |
Volume | 68 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3bbtQwELWq8gA8cCm3QEFGQqhFSnEujhPeViu2C1L7gGhZhFDkW8RqQ1LtRdrliU_gA_gUvoGP4EuYcZKFUgQSPCaZsWN77Dlje2YIecDjwoLmTn0jGffjUGtfRSLyJdgS2ppAc41bAweHyfAofj7iow3S73xhmvgQ6w03nBluvcYJLlWbhYQ1x4wBqC8B8okR1YULKIkB9RAYvfgRQgr1n7vGyFL0vQrak00o4_GZEk7ppnPYzcvfAc_TONYposFlYromNPdPJnuLudrTH36J7vifbbxCLrVAlfYaybpKNmy1Rc73u_xwW-TiT6EMr5HPPQoAneLDt4-fyvHEUjmdoucCbj_SuqCYvdmsyp1nx7vU-ZLMaOMtZqhaUZgNtXF-UMBYTurl2NjZE6pXuqyhQGM1Qt2dr1_gwb18Z5erEvNfywqs83m9e4LcQPMGeWtX23jxHqt7e50cDZ6-7A_9NvODr8Hey3ywm63MGJdGoJugTZgsssLakCWSaYA8RkZpzK1gKo0lmFAKYBcvuIblKAtUGt0gm1Vd2VuEmgSKEhJxkwK5tDJN0gK4VcHjxDDhkUfdmOcnTYCP3BlGTORnut8jD51UrCnldII34wTPXx3u5_3R6GAQBMf50CPbndjk7aIwy4MoSJIQMHLikfvrzzBqeEYjK1svgCaM8GQ5ycSfaNIIDHdYfj1ysxHJ9Q8BQAYwgjUETrD-3qa897o_2I9Ckd3-B5475AJAyLC54LNNNufThb0LMG2u7rl5-B3nojQ- |
link.rule.ids | 315,786,790,1382,27957,27958,46329,46753 |
linkProvider | Wiley-Blackwell |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3NbtQwELaq9lA4FCg_DRQwEkItUorz4zjhtlrYbqG7B9SWrRCKHNsRqw1JtT_SLicegQfgUXgGHoInYcbZXShFIMExyYwd2zOeb2zPmJCHPMwNWO7Y1ZJxN_SVcrNABK4EX0IZ7SmucGmg043ax-GLHu-tkGeLWJg6P8RywQ01w87XqOC4IF1rOav3GT2wXwIEFFOqC8wouQZqz61j9epHEim0gPYgI4sx-sqb721CIU8uFHHOOq1hR09_Bz3PI1lrilpXiFk0oj6BMtibjLM99eGX_I7_28qrZGOOVWmjFq5rZMWUm2S9ubgibpNc_imb4XXyuUEBo1N8-PbxU9EfGCqHQwxewBVIWuUUL3DWs2Ln4GSX2nCSEa0DxjTNZhQUotI2FAoYi0E17WszekrVTBUVFKiNQrS78_ULPNiX78x0VuAV2LIEB31c7Z4hN9C8Qd7K1tafvMfq3t4gx63nR822O7_8wVXg8iUuuM5GJoxLLTBS0ERM5klujM8iyRSgHi2DOORGsCwOJXhRGSAvnnMFM1LiZXFwk6yWVWm2CNURFCUkQqcMRNPIOIpz4M5yHkaaCYc8Xgx6elbn-Eitb8REeqH7HfLIisWSUg4HeDhO8PR1dz9t9nqdluedpG2HbC_kJp3PC6PUC7wo8gEmRw55sPwMo4bbNLI01QRo_AA3l6NE_IkmDsB3hxnYIbdqmVz-EGBkwCNYg2cl6-9tShunzdZ-4Ivk9j_w3Cfr7aPOYXp40H15h1wCROnX5322yep4ODF3AbWNs3tWKb8DK2g4YA |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1rbtQwELaqVuLxg0d5BQoYCaEWKW2edsK_Vcp2C3SFEG0XoSpybEesNiSrfUi7_OIIHICjcAYOwUmYcTYLpQgk-Jlkxo7tGc83tmdMyMMwyDVY7shWwgntwJPSznzu2wJ8CamVK0OJSwMHXdY5DJ71wt4KSZpYmDo_xHLBDTXDzNeo4EOV10ru1NuMLpgvDvKJGdU5JpRcC5jvoWjvvvqRQwoNoDnH6EQYfOUutjahkJ0zRZwyTmvYz7PfIc_TQNZYovZlopo21AdQBtvTSbYtP_yS3vE_G3mFXFogVdqqResqWdHlOjmfNBfErZOLP-UyvEY-tyggdIoP3z5-KvoDTcVohKELuP5Iq5zi9c1qXmzuH21RE0wypnW4mKLZnII6VMoEQgFjMahmfaXHT6icy6KCApWWiHU3v36BB_PynZ7NC7wAW5Tgnk-qrSFyA81b5K1Mbf3pe6zu5Do5bD99nXTsxdUPtgSHL7bBcdYidkKhOMYJauaIPM619hwmHAmYRwk_CkLNnSwKBPhQGeCuMA8lzEexm0X-DbJaVqW-RahiUBQXCJwyEEwtIhblwJ3lYcCUwy3yuBnzdFhn-EiNZ-Tw9Ez3W-SRkYolpRgN8GgcD9Pj7l6a9HoHbdc9SjsW2WjEJl3MCuPU9V3GPADJzCIPlp9h1HCTRpS6mgKN5-PWMov5n2giHzx3mH8tcrMWyeUPAUIGNII1uEaw_t6mtPUmae_5Ho9v_wPPfXLu5W47fbHffX6HXAA46dWHfTbI6mQ01XcBsk2ye0YlvwNReDcP |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+new+ring-like+arrangement+of+vanadyl%28IV%29+groups+bridged+by+monodentate+alkoxides%3A+cyclo-decakis%28%5Bmu%5D-cyclohexylmethanolato%29pentakis%5Boxidovanadium%28IV%29%5D&rft.jtitle=Acta+crystallographica.+Section+C%2C+Crystal+structure+communications&rft.au=Stinghen%2C+Danilo&rft.au=Ferreira%2C+Janaina+G&rft.au=Nunes%2C+Giovana+G&rft.au=Soares%2C+Ja%C3%ADsa+F&rft.date=2012-12-01&rft.pub=Wiley+Subscription+Services%2C+Inc&rft.issn=0108-2701&rft.eissn=1600-5759&rft.volume=68&rft.issue=12&rft.spage=m353&rft_id=info:doi/10.1107%2FS0108270112045702&rft.externalDBID=NO_FULL_TEXT&rft.externalDocID=2916098341 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0108-2701&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0108-2701&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0108-2701&client=summon |