Synthesis and distribution of structural units-Thermal property relationship of random and block butadiene-styrene copolymers with high trans 1,4 units content produced using an initiator composed of alkyl aluminum, n-butyl lithium, and barium alkoxide
Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n‐butyl lithium, and barium alkoxide. The thermal properties of t...
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| Published in | Journal of applied polymer science Vol. 116; no. 5; pp. 3103 - 3110 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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05.06.2010
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| Abstract | Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n‐butyl lithium, and barium alkoxide. The thermal properties of the block copolymers obtained by sequential addition of monomers were basically determined by the 1,4‐trans units of the polybutadiene block. Kinetic data and 1H‐nuclear magnetic resonance analyses showed that simultaneous polymerization of butadiene and styrene provided copolymers with a predominantly random distribution. By increasing the styrene content, the thermal properties of these copolymers were modified; polymers with 80% content of 1,4‐trans units and 5% of styrene presented an endothermic transition at or slightly below room temperature (20°C), corresponding to the crystalline monoclinic form of high 1,4‐trans polybutadiene, whereas copolymers with 25–50% styrene content were amorphous. The glass transition temperature of these copolymers increased significantly as the styrene content was increased. Both the block and random copolymers have a sufficient number of 1,4‐trans units to display a regular distribution of structural units that makes them susceptible to strain‐induced crystallization, which is important for the manufacture of products such as high‐performance tires. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 |
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| AbstractList | Random, diblock, and triblock copolymers of butadiene and styrene, with a well-defined, high number of 1,4-trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n-butyl lithium, and barium alkoxide. The thermal properties of the block copolymers obtained by sequential addition of monomers were basically determined by the 1,4-trans units of the polybutadiene block. Kinetic data and super(1)H-nuclear magnetic resonance analyses showed that simultaneous polymerization of butadiene and styrene provided copolymers with a predominantly random distribution. By increasing the styrene content, the thermal properties of these copolymers were modified; polymers with 80% content of 1,4-trans units and 5% of styrene presented an endothermic transition at or slightly below room temperature (20[deg]C), corresponding to the crystalline monoclinic form of high 1,4-trans polybutadiene, whereas copolymers with 25-50% styrene content were amorphous. The glass transition temperature of these copolymers increased significantly as the styrene content was increased. Both the block and random copolymers have a sufficient number of 1,4-trans units to display a regular distribution of structural units that makes them susceptible to strain-induced crystallization, which is important for the manufacture of products such as high-performance tires. 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 Random, diblock, and triblock copolymers of butadiene and styrene, with a well-defined, high number of 1,4-trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n-butyl lithium, and barium alkoxide. The thermal properties of the block copolymers obtained by sequential addition of monomers were basically determined by the 1,4-trans units of the polybutadiene block. Kinetic data and 1H-nuclear magnetic resonance analyses showed that simultaneous polymerization of butadiene and styrene provided copolymers with a predominantly random distribution. By increasing the styrene content, the thermal properties of these copolymers were modified; polymers with 80% content of 1,4-trans units and 5% of styrene presented an endothermic transition at or slightly below room temperature (20 degree C), corresponding to the crystalline monoclinic form of high 1,4-trans polybutadiene, whereas copolymers with 25-50% styrene content were amorphous. The glass transition temperature of these copolymers increased significantly as the styrene content was increased. Both the block and random copolymers have a sufficient number of 1,4-trans units to display a regular distribution of structural units that makes them susceptible to strain-induced crystallization, which is important for the manufacture of products such as high-performance tires. [copy 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 Abstract Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n ‐butyl lithium, and barium alkoxide. The thermal properties of the block copolymers obtained by sequential addition of monomers were basically determined by the 1,4‐trans units of the polybutadiene block. Kinetic data and 1 H‐nuclear magnetic resonance analyses showed that simultaneous polymerization of butadiene and styrene provided copolymers with a predominantly random distribution. By increasing the styrene content, the thermal properties of these copolymers were modified; polymers with 80% content of 1,4‐trans units and 5% of styrene presented an endothermic transition at or slightly below room temperature (20°C), corresponding to the crystalline monoclinic form of high 1,4‐trans polybutadiene, whereas copolymers with 25–50% styrene content were amorphous. The glass transition temperature of these copolymers increased significantly as the styrene content was increased. Both the block and random copolymers have a sufficient number of 1,4‐trans units to display a regular distribution of structural units that makes them susceptible to strain‐induced crystallization, which is important for the manufacture of products such as high‐performance tires. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by anionic living polymerization using an initiator system composed of alkyl aluminum, n‐butyl lithium, and barium alkoxide. The thermal properties of the block copolymers obtained by sequential addition of monomers were basically determined by the 1,4‐trans units of the polybutadiene block. Kinetic data and 1H‐nuclear magnetic resonance analyses showed that simultaneous polymerization of butadiene and styrene provided copolymers with a predominantly random distribution. By increasing the styrene content, the thermal properties of these copolymers were modified; polymers with 80% content of 1,4‐trans units and 5% of styrene presented an endothermic transition at or slightly below room temperature (20°C), corresponding to the crystalline monoclinic form of high 1,4‐trans polybutadiene, whereas copolymers with 25–50% styrene content were amorphous. The glass transition temperature of these copolymers increased significantly as the styrene content was increased. Both the block and random copolymers have a sufficient number of 1,4‐trans units to display a regular distribution of structural units that makes them susceptible to strain‐induced crystallization, which is important for the manufacture of products such as high‐performance tires. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 |
| Author | Benvenuta-Tapia, Juan José Ríos-Guerrero, Leonardo Tenorio-López, José Alfredo Herrera-Nájera, Rafael |
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| Cites_doi | 10.1177/0095244305051505 10.1002/macp.1981.020041981105 10.1016/0032-3861(85)90070-9 10.1177/0095244306057255 10.1201/9780585139401 10.1080/00222349808220485 10.1002/mren.200700048 10.1002/pol.1961.1205416020 10.1016/0032-3861(84)90089-2 10.5254/1.3547902 10.1021/ma00007a021 10.1002/app.12216 10.1080/00222337508065878 10.1021/ja01516a021 10.1070/RC1981v050n06ABEH002653 10.1021/ma00016a002 10.1016/S0032-3861(02)00451-2 10.1002/pen.20805 10.1002/1521-3935(20010101)202:1<73::AID-MACP73>3.0.CO;2-3 10.5254/1.3538331 10.1002/047084583X 10.1002/pol.1959.1203813308 10.1016/S0065-3055(08)60306-8 10.1002/macp.1981.021820626 |
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| Keywords | Butadiene copolymer Molecular structure high trans 1,4 polybutadiene anicnic polymerization Priming activity Diene copolymer Lithium Organic compounds Barium Compounds Butadiene-1,4 copolymer Trans stereoisomer thermal 'properties Alkoxide Anionic copolymerization copolymerization Diene polymer Living polymer distribution of structural units Experimental study Thermal properties Random copolymer Triblock copolymer Preparation Anionic catalyst Diblock copolymer Property structure relationship Aluminium Organic compounds Kinetics Styrene copolymer |
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| Snippet | Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by anionic... Abstract Random, diblock, and triblock copolymers of butadiene and styrene, with a well‐defined, high number of 1,4‐trans units (c.a. 80%), were synthesized by... Random, diblock, and triblock copolymers of butadiene and styrene, with a well-defined, high number of 1,4-trans units (c.a. 80%), were synthesized by anionic... |
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| SubjectTerms | 4 polybutadiene Aluminum anionic polymerization Applied sciences Block copolymers Butadiene Copolymerization Copolymers distribution of structural units Exact sciences and technology high trans 1 high trans 1,4 polybutadiene Lithium Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts Styrenes Thermal properties |
| Title | Synthesis and distribution of structural units-Thermal property relationship of random and block butadiene-styrene copolymers with high trans 1,4 units content produced using an initiator composed of alkyl aluminum, n-butyl lithium, and barium alkoxide |
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