Photocatalytic oxidative dehydrogenation of cyclohexane to cyclohexene over oxygen-deficient tungsten trioxide
A mild photocatalytic process with the use of tungsten trioxide has been demonstrated as a promising strategy to boost oxidative dehydrogenation of C6H12. Through engineering the surface defects, oxygen-deficient WO3-x showed outstanding selectivity and stability to produce cyclohexene. [Display omi...
Saved in:
| Published in | Applied catalysis. B, Environmental Vol. 298; p. 120549 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
05.12.2021
Elsevier BV |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | A mild photocatalytic process with the use of tungsten trioxide has been demonstrated as a promising strategy to boost oxidative dehydrogenation of C6H12. Through engineering the surface defects, oxygen-deficient WO3-x showed outstanding selectivity and stability to produce cyclohexene.
[Display omitted]
•Oxygen-deficient WO3-x was constructed for cyclohexane ODH to produce cyclohexene.•WO3-x showed photocatalytic ODH activity with high C6H10 selectivity and stability.•Oxygen vacancy introduction favored the adsorption of C6H12 over tungsten trioxide.•Low-coordinated W atom of WO3-x donated electrons to C6H12, weakening its CH bond.•C6H10 could easily desorb from WO3-x surface, contributing to the high selectivity.
Oxidative dehydrogenation of cyclohexane (C6H12) to cyclohexene (C6H10) suffers from low selectivity due to its over-dehydrogenation and oxidation to other products like benzene or cyclohexanol. In this study, we report that oxygen-deficient tungsten trioxide (WO3-x) can realize photocatalytic oxidative dehydrogenation of C6H12 with high C6H10 selectivity (∼99 %) and stability. Experimental results and theoretical calculations revealed that the introduction of oxygen vacancy favored the adsorption of C6H12 over tungsten trioxide and the low-coordinated W atom of WO3-x would donate electrons to the C atom of C6H12, weakening its CH bond. During the photocatalysis, the photogenerated holes acted as oxidative species for the dehydrogenation of C6H12 along with the H2O formation through the combination with adjacent O atom in WO3-x. Meanwhile, the product C6H10 could easily desorb from the surface of WO3-x to avoid the over-dehydrogenation and oxidation, contributing to the high selectivity. |
|---|---|
| AbstractList | A mild photocatalytic process with the use of tungsten trioxide has been demonstrated as a promising strategy to boost oxidative dehydrogenation of C6H12. Through engineering the surface defects, oxygen-deficient WO3-x showed outstanding selectivity and stability to produce cyclohexene.
[Display omitted]
•Oxygen-deficient WO3-x was constructed for cyclohexane ODH to produce cyclohexene.•WO3-x showed photocatalytic ODH activity with high C6H10 selectivity and stability.•Oxygen vacancy introduction favored the adsorption of C6H12 over tungsten trioxide.•Low-coordinated W atom of WO3-x donated electrons to C6H12, weakening its CH bond.•C6H10 could easily desorb from WO3-x surface, contributing to the high selectivity.
Oxidative dehydrogenation of cyclohexane (C6H12) to cyclohexene (C6H10) suffers from low selectivity due to its over-dehydrogenation and oxidation to other products like benzene or cyclohexanol. In this study, we report that oxygen-deficient tungsten trioxide (WO3-x) can realize photocatalytic oxidative dehydrogenation of C6H12 with high C6H10 selectivity (∼99 %) and stability. Experimental results and theoretical calculations revealed that the introduction of oxygen vacancy favored the adsorption of C6H12 over tungsten trioxide and the low-coordinated W atom of WO3-x would donate electrons to the C atom of C6H12, weakening its CH bond. During the photocatalysis, the photogenerated holes acted as oxidative species for the dehydrogenation of C6H12 along with the H2O formation through the combination with adjacent O atom in WO3-x. Meanwhile, the product C6H10 could easily desorb from the surface of WO3-x to avoid the over-dehydrogenation and oxidation, contributing to the high selectivity. Oxidative dehydrogenation of cyclohexane (C6H12) to cyclohexene (C6H10) suffers from low selectivity due to its over-dehydrogenation and oxidation to other products like benzene or cyclohexanol. In this study, we report that oxygen-deficient tungsten trioxide (WO3-x) can realize photocatalytic oxidative dehydrogenation of C6H12 with high C6H10 selectivity (∼99 %) and stability. Experimental results and theoretical calculations revealed that the introduction of oxygen vacancy favored the adsorption of C6H12 over tungsten trioxide and the low-coordinated W atom of WO3-x would donate electrons to the C atom of C6H12, weakening its C-H bond. During the photocatalysis, the photogenerated holes acted as oxidative species for the dehydrogenation of C6H12 along with the H2O formation through the combination with adjacent O atom in WO3-x. Meanwhile, the product C6H10 could easily desorb from the surface of WO3-x to avoid the over-dehydrogenation and oxidation, contributing to the high selectivity. |
| ArticleNumber | 120549 |
| Author | Quan, Fengjiao Gu, Huayu Yu, Linghao Zhang, Lizhi Liu, Xiufan Yang, Le Zhou, Bing Zhan, Guangming Jia, Falong Liu, Xiao |
| Author_xml | – sequence: 1 givenname: Fengjiao surname: Quan fullname: Quan, Fengjiao – sequence: 2 givenname: Guangming surname: Zhan fullname: Zhan, Guangming – sequence: 3 givenname: Xiufan surname: Liu fullname: Liu, Xiufan – sequence: 4 givenname: Bing surname: Zhou fullname: Zhou, Bing – sequence: 5 givenname: Huayu surname: Gu fullname: Gu, Huayu – sequence: 6 givenname: Linghao surname: Yu fullname: Yu, Linghao – sequence: 7 givenname: Le surname: Yang fullname: Yang, Le – sequence: 8 givenname: Falong surname: Jia fullname: Jia, Falong email: fljia@mail.ccnu.edu.cn – sequence: 9 givenname: Xiao orcidid: 0000-0001-6653-1582 surname: Liu fullname: Liu, Xiao email: liuxiao71@mail.ccnu.edu.cn – sequence: 10 givenname: Lizhi orcidid: 0000-0002-6842-9167 surname: Zhang fullname: Zhang, Lizhi |
| BookMark | eNqFkE1LAzEURYNUsFb_gYsB1zPmo9NJXQhS_IKCLnQd0uSlzTAmNZOWzr8344gLF5pNuOSdG945RSPnHSB0QXBBMJld1YXcKhlXBcWUFITicjo_QmPCK5YzztkIjfGcznLGKnaCTtu2xhhTRvkYuZeNjz7BsumiVZk_WC2j3UOmYdPp4NfgUvYu8yZTnWr8Bg7SQRb9T4QU_R5Cgrs0nmswVllwMYs7t24juCwG2zfDGTo2smnh_PueoLf7u9fFY758fnha3C5zNcU45pRLrZlkJVGUzHXFKcMKmAZqlC7xiksKbMYUr0yFZXotFUBZEY7nYEyl2QRdDr3b4D920EZR-11w6UtBS077k1xM0PUwpYJv2wBGKBu_to1B2kYQLHq_ohaDX9H7FYPfBE9_wdtg32Xo_sNuBgzS-nsLQbS9KwXaBlBRaG__LvgEB8ib4A |
| CitedBy_id | crossref_primary_10_1002_cctc_202300723 crossref_primary_10_1016_j_apsusc_2023_158004 crossref_primary_10_1016_j_mcat_2024_114400 crossref_primary_10_1016_j_jallcom_2023_172209 crossref_primary_10_1016_j_jece_2023_110970 crossref_primary_10_1016_j_jallcom_2022_165652 crossref_primary_10_1021_acsami_3c01260 crossref_primary_10_1002_aoc_7857 crossref_primary_10_1002_adma_202411648 crossref_primary_10_1021_acscatal_1c05788 crossref_primary_10_1021_acs_jpclett_4c00127 crossref_primary_10_1021_acsanm_2c00115 crossref_primary_10_1021_acsnano_3c05037 crossref_primary_10_1039_D3CC01512B crossref_primary_10_1002_aic_18749 crossref_primary_10_1039_D4NJ04075A crossref_primary_10_1016_j_jechem_2024_02_024 crossref_primary_10_1016_j_jcat_2023_03_015 crossref_primary_10_1021_acsaem_2c03553 crossref_primary_10_1016_j_jes_2023_08_010 crossref_primary_10_1016_j_ces_2024_119847 crossref_primary_10_1016_j_diamond_2024_111534 |
| Cites_doi | 10.1021/jacs.6b04629 10.1021/jp303472p 10.1021/acsami.7b19323 10.1016/j.apcatb.2020.119409 10.1016/j.apcatb.2017.01.022 10.1021/jacs.6b12850 10.1016/j.matlet.2006.12.055 10.1103/PhysRev.140.A1133 10.1021/acssuschemeng.7b02702 10.1016/j.jcat.2009.11.026 10.1016/S1044-5803(03)00100-1 10.1039/C1CY00331C 10.1038/nchem.1032 10.1016/0021-9517(83)90001-5 10.1016/S1872-2067(18)63050-5 10.1103/RevModPhys.64.1045 10.1021/jp408446u 10.1007/s11164-012-0931-0 10.1016/j.apcatb.2020.119350 10.1021/acscatal.8b03724 10.1021/jp077143t 10.1016/j.ijhydene.2011.08.022 10.1016/j.apcatb.2020.119447 10.1016/0920-5861(95)00221-9 10.1103/PhysRev.136.B864 10.1016/j.apcatb.2019.03.058 10.1021/acscatal.6b01657 10.1016/j.cattod.2018.06.017 10.1007/s10562-009-0064-2 10.1016/j.cattod.2008.10.020 10.1021/acscatal.6b02611 10.1103/PhysRevB.54.11169 10.1002/anie.202001701 10.1021/acs.inorgchem.0c00390 10.1103/PhysRevB.59.1758 10.1002/adfm.201002477 10.1021/jp210171f 10.1016/j.apcatb.2018.09.099 10.1007/s11164-017-3124-z 10.1016/j.apcatb.2020.119089 10.1002/adfm.201703923 10.1002/anie.201404953 10.1021/jp201057m 10.1016/j.elspec.2006.12.059 10.1039/C8CY00994E 10.1016/j.jallcom.2020.156225 10.1007/s10562-017-1974-z |
| ContentType | Journal Article |
| Copyright | 2021 Elsevier B.V. Copyright Elsevier BV Dec 5, 2021 |
| Copyright_xml | – notice: 2021 Elsevier B.V. – notice: Copyright Elsevier BV Dec 5, 2021 |
| DBID | AAYXX CITATION 7SR 7ST 7U5 8BQ 8FD C1K FR3 JG9 KR7 L7M SOI |
| DOI | 10.1016/j.apcatb.2021.120549 |
| DatabaseName | CrossRef Engineered Materials Abstracts Environment Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Environmental Sciences and Pollution Management Engineering Research Database Materials Research Database Civil Engineering Abstracts Advanced Technologies Database with Aerospace Environment Abstracts |
| DatabaseTitle | CrossRef Materials Research Database Civil Engineering Abstracts Engineered Materials Abstracts Technology Research Database Solid State and Superconductivity Abstracts Engineering Research Database Environment Abstracts Advanced Technologies Database with Aerospace METADEX Environmental Sciences and Pollution Management |
| DatabaseTitleList | Materials Research Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry Environmental Sciences |
| EISSN | 1873-3883 |
| ExternalDocumentID | 10_1016_j_apcatb_2021_120549 S0926337321006755 |
| GroupedDBID | --K --M -~X .~1 0R~ 1B1 1~. 1~5 23M 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAXUO ABFNM ABMAC ABNUV ABYKQ ACDAQ ACGFS ACIWK ACRLP ADBBV ADEWK ADEZE AEBSH AEKER AFKWA AFRAH AFTJW AGHFR AGUBO AGYEJ AHPOS AIEXJ AIKHN AITUG AJOXV AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 EBS EFJIC EFLBG ENUVR EO8 EO9 EP2 EP3 F5P FDB FIRID FNPLU FYGXN G-Q GBLVA IHE J1W KOM LX7 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG ROL RPZ SDF SDG SES SPC SPD SSG SSZ T5K ~02 ~G- AAQXK AATTM AAXKI AAYWO AAYXX ABJNI ABWVN ABXDB ACRPL ACVFH ADCNI ADMUD ADNMO AEIPS AEUPX AFJKZ AFPUW AFXIZ AGCQF AGQPQ AGRNS AHHHB AI. AIGII AIIUN AKBMS AKRWK AKYEP ANKPU ASPBG AVWKF AZFZN BBWZM BNPGV CITATION EJD FEDTE FGOYB HLY HVGLF HZ~ NDZJH R2- SCE SEW SSH VH1 WUQ XPP 7SR 7ST 7U5 8BQ 8FD C1K EFKBS FR3 JG9 KR7 L7M SOI |
| ID | FETCH-LOGICAL-c400t-28add3a351c219d78230ce3de2fcd50b8a2e363c87f70a8235cee571809eff7d3 |
| IEDL.DBID | .~1 |
| ISSN | 0926-3373 |
| IngestDate | Wed Aug 13 04:19:44 EDT 2025 Tue Jul 01 04:35:14 EDT 2025 Thu Apr 24 23:04:28 EDT 2025 Sat Mar 02 16:00:52 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Photocatalytic process Selective conversion of cyclohexane Oxygen-deficient tungsten trioxide Cyclohexene Oxidative dehydrogenation |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c400t-28add3a351c219d78230ce3de2fcd50b8a2e363c87f70a8235cee571809eff7d3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 |
| ORCID | 0000-0002-6842-9167 0000-0001-6653-1582 |
| PQID | 2582222237 |
| PQPubID | 2045281 |
| ParticipantIDs | proquest_journals_2582222237 crossref_citationtrail_10_1016_j_apcatb_2021_120549 crossref_primary_10_1016_j_apcatb_2021_120549 elsevier_sciencedirect_doi_10_1016_j_apcatb_2021_120549 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2021-12-05 |
| PublicationDateYYYYMMDD | 2021-12-05 |
| PublicationDate_xml | – month: 12 year: 2021 text: 2021-12-05 day: 05 |
| PublicationDecade | 2020 |
| PublicationPlace | Amsterdam |
| PublicationPlace_xml | – name: Amsterdam |
| PublicationTitle | Applied catalysis. B, Environmental |
| PublicationYear | 2021 |
| Publisher | Elsevier B.V Elsevier BV |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier BV |
| References | Sola, Ramírez de la Piscina, Homs (bib0065) 2020; 341 Payne, Teter, Allan, Arias, Joannopoulos (bib0155) 1992; 64 Henríquez, Mansilla, Martínez-de la Cruz, Freer, Contreras (bib0035) 2017; 206 Thomas, van Oers, de Beer, Moulijn (bib0120) 1983; 84 Amano, Ishinaga, Yamakata (bib0125) 2013; 117 Zhou, Doronkin, Zhao, Plessow, Jelic, Detlefs, Pruessmann, Studt, Grunwaldt (bib0060) 2018; 8 Wang, Di Valentin, Pacchioni (bib0170) 2011; 115 Shpak, Korduban, Medvedskij, Kandyba (bib0190) 2007; 156-158 Contreras, Melin, Márquez, Pérez-González, Mansilla, Pecchi, Henríquez (bib0030) 2019; 251 Jin, Cheng (bib0015) 2009; 131 Fang, Yao, Guo, Xu, Zhou, Zhuo, Shi, Liu, Wang, Li, Chen (bib0130) 2017; 5 Lv, Xu, Kobayashi, Nakane (bib0070) 2020; 845 Kohn, Sham (bib0160) 1965; 140 Christopher, Xin, Linic (bib0055) 2011; 3 Ciambelli, Sannino, Palma, Vaiano (bib0100) 2005; Vol. 155 Song, Zheng, Yang, Wang (bib0180) 2007; 61 Zhang, Hu, Han, Zhai, Zheng (bib0010) 2018; 10 Almeida, And, Mul (bib0240) 2008; 112 Gu, Liu, Yang, Ma, Zhao, Xing, Wu, Liu, Mintova, Bai, Yan (bib0235) 2020; 274 Shiraishi, Shiota, Hirakawa, Tanaka, Ichikawa, Hirai (bib0230) 2017; 7 Geng, Chen, Li, Xu, Li, He, Lu (bib0045) 2021; 280 Feng, Elam, Libera, Pellin, Stair (bib0025) 2010; 269 Su, Chen, Fu, Yang, She, Wan, Zhang, Liu (bib0090) 2020; 59 Lü, Zhan, Chen, Liu, Wu (bib0050) 2020; 279 Dong, Yang, Wang, Zang, Wang (bib0140) 2016; 6 Guo, Wen, Li, An (bib0040) 2021; 281 Ciambelli, Sannino, Palma, Vaiano, Mazzei, Eloy, Gaigneaux (bib0105) 2009; 141 Srinivasan, Miyauchi (bib0220) 2012; 116 Vaiano, Sannino, Almeida, Mul, Ciambelli (bib0245) 2013; 3 Li, Qin, Yang, Cui, Wang, Zhang (bib0135) 2017; 139 Sutthiumporn, Kawi (bib0195) 2011; 36 Watling, Deo, Seshan, Wachs, Lercher (bib0110) 1996; 28 Zhang, Li, Ye, Chen, Ju, Liu, Lin, Ye, Wang, Xu, Zhu, Song, Jiang, Xiong (bib0200) 2016; 138 Sannino, Vaiano, Ciambelli (bib0075) 2013; 39 Kresse, Joubert (bib0165) 1999; 59 Anisimov, Aryasetiawan, Lichtenstein (bib0175) 1997; 9 Yang, Fu, Su, She, Chen, Tang, Hu, Zhang, Liu (bib0085) 2019; 242 Wang, Ding, Zhang, Pang, Hai, Zhan, Zhou, Song, Zhang, Chen, Ye (bib0225) 2017; 27 Zheng, Ou, Strano, Kaner, Mitchell, Kalantar-zadeh (bib0185) 2011; 21 Hoffmann, Galindo, Zambrano, Rincón, Prieto (bib0250) 2003; 50 Cao, Zhu, Yang, Xu, Yu, Xu (bib0005) 2018; 39 Kang, Liu, Wang, Li, Ren, Li, Pan, Li, Zong, Liu, Frenkel, Zhang (bib0115) 2020; 59 Ueyama, Hatta, Okemoto, Taniya, Ichihashi, Nishiyama (bib0080) 2018; 44 Liu, Wang, Lin, Xie, Tong, Lin, Zhang, Zhang, Wang (bib0210) 2018; 8 Kresse, Furthmüller (bib0150) 1996; 54 Hohenberg, Kohn (bib0145) 1964; 136 Jin, Zhu, Chen, Fang, Li, Zhang, Huang, Ding, Ning, Chen (bib0205) 2012; 116 Wang, Gao, Chabal, Balkus (bib0020) 2017; 147 Shiraishi, Sugano, Ichikawa, Hirai (bib0095) 2012; 2 Meng, Wang, Liu, Ouyang, Li, Hu, Kako, Iwai, Tanaka, Ye (bib0215) 2014; 53 Anisimov (10.1016/j.apcatb.2021.120549_bib0175) 1997; 9 Christopher (10.1016/j.apcatb.2021.120549_bib0055) 2011; 3 Lv (10.1016/j.apcatb.2021.120549_bib0070) 2020; 845 Ciambelli (10.1016/j.apcatb.2021.120549_bib0100) 2005; Vol. 155 Hoffmann (10.1016/j.apcatb.2021.120549_bib0250) 2003; 50 Shpak (10.1016/j.apcatb.2021.120549_bib0190) 2007; 156-158 Cao (10.1016/j.apcatb.2021.120549_bib0005) 2018; 39 Sutthiumporn (10.1016/j.apcatb.2021.120549_bib0195) 2011; 36 Fang (10.1016/j.apcatb.2021.120549_bib0130) 2017; 5 Song (10.1016/j.apcatb.2021.120549_bib0180) 2007; 61 Almeida (10.1016/j.apcatb.2021.120549_bib0240) 2008; 112 Wang (10.1016/j.apcatb.2021.120549_bib0020) 2017; 147 Ciambelli (10.1016/j.apcatb.2021.120549_bib0105) 2009; 141 Kang (10.1016/j.apcatb.2021.120549_bib0115) 2020; 59 Jin (10.1016/j.apcatb.2021.120549_bib0205) 2012; 116 Amano (10.1016/j.apcatb.2021.120549_bib0125) 2013; 117 Yang (10.1016/j.apcatb.2021.120549_bib0085) 2019; 242 Li (10.1016/j.apcatb.2021.120549_bib0135) 2017; 139 Shiraishi (10.1016/j.apcatb.2021.120549_bib0095) 2012; 2 Wang (10.1016/j.apcatb.2021.120549_bib0225) 2017; 27 Liu (10.1016/j.apcatb.2021.120549_bib0210) 2018; 8 Geng (10.1016/j.apcatb.2021.120549_bib0045) 2021; 280 Jin (10.1016/j.apcatb.2021.120549_bib0015) 2009; 131 Payne (10.1016/j.apcatb.2021.120549_bib0155) 1992; 64 Kresse (10.1016/j.apcatb.2021.120549_bib0150) 1996; 54 Hohenberg (10.1016/j.apcatb.2021.120549_bib0145) 1964; 136 Shiraishi (10.1016/j.apcatb.2021.120549_bib0230) 2017; 7 Guo (10.1016/j.apcatb.2021.120549_bib0040) 2021; 281 Lü (10.1016/j.apcatb.2021.120549_bib0050) 2020; 279 Zheng (10.1016/j.apcatb.2021.120549_bib0185) 2011; 21 Kresse (10.1016/j.apcatb.2021.120549_bib0165) 1999; 59 Gu (10.1016/j.apcatb.2021.120549_bib0235) 2020; 274 Kohn (10.1016/j.apcatb.2021.120549_bib0160) 1965; 140 Sola (10.1016/j.apcatb.2021.120549_bib0065) 2020; 341 Contreras (10.1016/j.apcatb.2021.120549_bib0030) 2019; 251 Zhang (10.1016/j.apcatb.2021.120549_bib0200) 2016; 138 Meng (10.1016/j.apcatb.2021.120549_bib0215) 2014; 53 Feng (10.1016/j.apcatb.2021.120549_bib0025) 2010; 269 Henríquez (10.1016/j.apcatb.2021.120549_bib0035) 2017; 206 Srinivasan (10.1016/j.apcatb.2021.120549_bib0220) 2012; 116 Zhou (10.1016/j.apcatb.2021.120549_bib0060) 2018; 8 Wang (10.1016/j.apcatb.2021.120549_bib0170) 2011; 115 Thomas (10.1016/j.apcatb.2021.120549_bib0120) 1983; 84 Ueyama (10.1016/j.apcatb.2021.120549_bib0080) 2018; 44 Sannino (10.1016/j.apcatb.2021.120549_bib0075) 2013; 39 Watling (10.1016/j.apcatb.2021.120549_bib0110) 1996; 28 Zhang (10.1016/j.apcatb.2021.120549_bib0010) 2018; 10 Vaiano (10.1016/j.apcatb.2021.120549_bib0245) 2013; 3 Su (10.1016/j.apcatb.2021.120549_bib0090) 2020; 59 Dong (10.1016/j.apcatb.2021.120549_bib0140) 2016; 6 |
| References_xml | – volume: 10 start-page: 15786 year: 2018 end-page: 15792 ident: bib0010 article-title: Redox-active cobalt(II/III) metal–organic framework for selective oxidation of cyclohexene publication-title: ACS Appl. Mater. Inter. – volume: 116 start-page: 5067 year: 2012 end-page: 5075 ident: bib0205 article-title: Enhanced oxidation reactivity of WO publication-title: J. Phys. Chem. C – volume: 2 start-page: 400 year: 2012 end-page: 405 ident: bib0095 article-title: Visible light-induced partial oxidation of cyclohexane on WO publication-title: Catal. Sci. Technol. – volume: 21 start-page: 2175 year: 2011 end-page: 2196 ident: bib0185 article-title: Nanostructured tungsten oxide – properties, synthesis, and applications publication-title: Adv. Funct. Mater. – volume: 8 start-page: 11398 year: 2018 end-page: 11406 ident: bib0060 article-title: Photothermal catalysis over nonplasmonic Pt/TiO publication-title: ACS Catal. – volume: 341 start-page: 13 year: 2020 end-page: 20 ident: bib0065 article-title: Behaviour of Pt/TiO publication-title: Catal. Today – volume: 50 start-page: 255 year: 2003 end-page: 259 ident: bib0250 article-title: FTIR studies of tungsten carbide in bulk material and thin film samples publication-title: Mater. Charact. – volume: 242 start-page: 249 year: 2019 end-page: 257 ident: bib0085 article-title: Influence of tetraalkylammonium cations on quality of decatungstate and its photocatalytic property in visible light-triggered selective oxidation of organic compounds by dioxygens publication-title: Appl. Catal. B: Environ. – volume: 3 start-page: 467 year: 2011 end-page: 472 ident: bib0055 article-title: Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures publication-title: Nat. Chem. – volume: 206 start-page: 252 year: 2017 end-page: 262 ident: bib0035 article-title: Selective oxofunctionalization of cyclohexane over titanium dioxide–based and bismuth oxyhalide (BiOX, X=Cl publication-title: Appl. Catal. B: Environ. – volume: 116 start-page: 15421 year: 2012 end-page: 15426 ident: bib0220 article-title: Chemically stable WO publication-title: J. Phys. Chem. C – volume: 36 start-page: 14435 year: 2011 end-page: 14446 ident: bib0195 article-title: Promotional effect of alkaline earth over Ni–La publication-title: Int. J. Hydrogen Energ. – volume: 84 start-page: 275 year: 1983 end-page: 287 ident: bib0120 article-title: Characterization of silica-supported molybdenum oxide and tungsten oxide. Reducibility of the oxidic state versus hydrodesulfurization activity of the sulfided state publication-title: J. Catal. – volume: 138 start-page: 8928 year: 2016 end-page: 8935 ident: bib0200 article-title: Oxide defect engineering enables to couple solar energy into oxygen activation publication-title: J. Am. Chem. Soc. – volume: 5 start-page: 10735 year: 2017 end-page: 10743 ident: bib0130 article-title: One-step, solventless, and scalable mechanosynthesis of WO publication-title: ACS Sustain. Chem. Eng. – volume: 136 start-page: B864 year: 1964 end-page: B871 ident: bib0145 article-title: Inhomogeneous Electron gas publication-title: Phys. Rev. – volume: 112 start-page: 1552 year: 2008 end-page: 1561 ident: bib0240 article-title: In situ ATR-FTIR study on the selective photo-oxidation of cyclohexane over anatase TiO publication-title: J. Phys. Chem. C – volume: 140 start-page: A1133 year: 1965 end-page: A1138 ident: bib0160 article-title: Self-consistent equations including exchange and correlation effects publication-title: Phys. Rev. – volume: 274 year: 2020 ident: bib0235 article-title: Highly stable phosphine modified VO publication-title: Appl. Catal. B: Environ. – volume: 141 start-page: 367 year: 2009 end-page: 373 ident: bib0105 article-title: Photocatalytic cyclohexane oxidehydrogenation on sulphated MoO publication-title: Catal. Today – volume: 269 start-page: 421 year: 2010 end-page: 431 ident: bib0025 article-title: Oxidative dehydrogenation of cyclohexane over alumina-supported vanadium oxide nanoliths publication-title: J. Catal. – volume: 8 start-page: 4399 year: 2018 end-page: 4406 ident: bib0210 article-title: Surface oxygen vacancy and defect engineering of WO publication-title: Catal. Sci. Technol. – volume: 280 year: 2021 ident: bib0045 article-title: Z-scheme 2D/2D α-Fe publication-title: Appl. Catal. B: Environ. – volume: 27 year: 2017 ident: bib0225 article-title: In situ carbon homogeneous doping on ultrathin bismuth molybdate: a dual-purpose strategy for efficient molecular oxygen activation publication-title: Adv. Funct.Mater. – volume: 279 year: 2020 ident: bib0050 article-title: Anchoring Zn-phthalocyanines in the pore matrices of UiO-67 to improve highly the photocatalytic oxidation efficiency publication-title: Appl. Catal. B: Environ. – volume: 39 start-page: 4145 year: 2013 end-page: 4157 ident: bib0075 article-title: A green route for selective synthesis of styrene from ethylbenzene by means of a photocatalytic system publication-title: Res. Chem. Intermediate. – volume: Vol. 155 start-page: 179 year: 2005 end-page: 187 ident: bib0100 article-title: Cyclohexane photocatalytic oxidative dehydrogenation to benzene on sulphated titania supported MoO publication-title: Studies in Surface Science and Catalysis – volume: 59 start-page: 1758 year: 1999 end-page: 1775 ident: bib0165 article-title: From ultrasoft pseudopotentials to the projector augmented-wave method publication-title: Phys. Rev. B – volume: 9 start-page: 767 year: 1997 end-page: 808 ident: bib0175 article-title: First-principles calculations of the electronic structure and spectra of strongly correlated systems: theLDA+Umethod publication-title: J. Phys.: Condens.Mat. – volume: 59 start-page: 7520 year: 2020 end-page: 7530 ident: bib0090 article-title: Hybridizing engineering strategy of decatungstate. 2. Regulated effect of doping transition metal ions on photocatalytic oxidation performance of (nBu publication-title: Inorg. Chem. – volume: 44 start-page: 629 year: 2018 end-page: 638 ident: bib0080 article-title: Cyclohexane photooxidation under visible light irradiation by WO publication-title: Res. Chem. Intermediate. – volume: 28 start-page: 139 year: 1996 end-page: 145 ident: bib0110 article-title: Oxidative dehydrogenation of propane over niobia supported vanadium oxide catalysts publication-title: Catal. Today – volume: 845 year: 2020 ident: bib0070 article-title: Novel Pd-loaded urchin-like (NH publication-title: J. Alloys Compd. – volume: 117 start-page: 22584 year: 2013 end-page: 22590 ident: bib0125 article-title: Effect of particle size on the photocatalytic activity of WO publication-title: J. Phys. Chem. C – volume: 64 start-page: 1045 year: 1992 end-page: 1097 ident: bib0155 article-title: Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients publication-title: Rev. Mod. Phys. – volume: 251 start-page: 17 year: 2019 end-page: 24 ident: bib0030 article-title: Selective oxidation of cyclohexane to cyclohexanol by BiOI under visible light: role of the ratio (1 1 0)/(0 0 1) facet publication-title: Appl. Catal. B: Environ. – volume: 115 start-page: 8345 year: 2011 end-page: 8353 ident: bib0170 article-title: Electronic and structural properties of WO publication-title: J. Phys. Chem. C – volume: 53 start-page: 11478 year: 2014 end-page: 11482 ident: bib0215 article-title: Photothermal conversion of CO publication-title: Angew. Chem. Int. Ed. – volume: 139 start-page: 3513 year: 2017 end-page: 3521 ident: bib0135 article-title: New reaction pathway induced by plasmon for selective benzyl alcohol oxidation on BiOCl possessing oxygen vacancies publication-title: J. Am. Chem. Soc. – volume: 61 start-page: 3904 year: 2007 end-page: 3908 ident: bib0180 article-title: Large-scale hydrothermal synthesis of WO publication-title: Mater. Lett. – volume: 147 start-page: 738 year: 2017 end-page: 744 ident: bib0020 article-title: Oxidative dehydrogenation of cyclohexane and Cyclohexene over Y-doped CeO publication-title: Catal. Lett. – volume: 54 start-page: 11169 year: 1996 end-page: 11186 ident: bib0150 article-title: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set publication-title: Phys. Rev. B – volume: 59 start-page: 12909 year: 2020 end-page: 12916 ident: bib0115 article-title: Photo–thermo catalytic oxidation over a TiO publication-title: Angew. Chem. Int. Ed. – volume: 39 start-page: 899 year: 2018 end-page: 907 ident: bib0005 article-title: Recent advances on controllable and selective catalytic oxidation of cyclohexene publication-title: Chinese J. Catal. – volume: 131 start-page: 266 year: 2009 end-page: 278 ident: bib0015 article-title: Oxidative dehydrogenation of cyclohexane to cyclohexene over Mg-V-O catalysts publication-title: Catal. Lett. – volume: 6 start-page: 6511 year: 2016 end-page: 6519 ident: bib0140 article-title: Removal of nitric oxide through visible light photocatalysis by g-C publication-title: ACS Catal. – volume: 281 year: 2021 ident: bib0040 article-title: Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts: a critical review publication-title: Appl. Catal. B: Environ. – volume: 156-158 start-page: 172 year: 2007 end-page: 175 ident: bib0190 article-title: XPS studies of active elements surface of gas sensors based on WO publication-title: J. Electron Spectrosc. – volume: 3 start-page: 978 year: 2013 end-page: 997 ident: bib0245 article-title: Investigation of the deactivation phenomena occurring in the cyclohexane photocatalytic oxidative dehydrogenation on MoO publication-title: Catal – volume: 7 start-page: 293 year: 2017 end-page: 300 ident: bib0230 article-title: Titanium Dioxide/Reduced graphene oxide hybrid photocatalysts for efficient and selective partial oxidation of cyclohexane publication-title: ACS Catal. – volume: 138 start-page: 8928 issue: 28 year: 2016 ident: 10.1016/j.apcatb.2021.120549_bib0200 article-title: Oxide defect engineering enables to couple solar energy into oxygen activation publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.6b04629 – volume: 116 start-page: 15421 issue: 29 year: 2012 ident: 10.1016/j.apcatb.2021.120549_bib0220 article-title: Chemically stable WO3 based thin-film for visible-light induced oxidation and superhydrophilicity publication-title: J. Phys. Chem. C doi: 10.1021/jp303472p – volume: 10 start-page: 15786 issue: 18 year: 2018 ident: 10.1016/j.apcatb.2021.120549_bib0010 article-title: Redox-active cobalt(II/III) metal–organic framework for selective oxidation of cyclohexene publication-title: ACS Appl. Mater. Inter. doi: 10.1021/acsami.7b19323 – volume: 280 year: 2021 ident: 10.1016/j.apcatb.2021.120549_bib0045 article-title: Z-scheme 2D/2D α-Fe2O3/g-C3N4 heterojunction for photocatalytic oxidation of nitric oxide publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2020.119409 – volume: 206 start-page: 252 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0035 article-title: Selective oxofunctionalization of cyclohexane over titanium dioxide–based and bismuth oxyhalide (BiOX, X=Cl−, Br−, I−) photocatalysts by visible light irradiation publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2017.01.022 – volume: 139 start-page: 3513 issue: 9 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0135 article-title: New reaction pathway induced by plasmon for selective benzyl alcohol oxidation on BiOCl possessing oxygen vacancies publication-title: J. Am. Chem. Soc. doi: 10.1021/jacs.6b12850 – volume: 61 start-page: 3904 issue: 18 year: 2007 ident: 10.1016/j.apcatb.2021.120549_bib0180 article-title: Large-scale hydrothermal synthesis of WO3 nanowires in the presence of K2SO4 publication-title: Mater. Lett. doi: 10.1016/j.matlet.2006.12.055 – volume: 140 start-page: A1133 issue: 4A year: 1965 ident: 10.1016/j.apcatb.2021.120549_bib0160 article-title: Self-consistent equations including exchange and correlation effects publication-title: Phys. Rev. doi: 10.1103/PhysRev.140.A1133 – volume: 5 start-page: 10735 issue: 11 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0130 article-title: One-step, solventless, and scalable mechanosynthesis of WO3·2H2O ultrathin narrow nanosheets with superior UV–Vis-Light-Driven photocatalytic activity publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.7b02702 – volume: 9 start-page: 767 issue: 4 year: 1997 ident: 10.1016/j.apcatb.2021.120549_bib0175 article-title: First-principles calculations of the electronic structure and spectra of strongly correlated systems: theLDA+Umethod publication-title: J. Phys.: Condens.Mat. – volume: 269 start-page: 421 issue: 2 year: 2010 ident: 10.1016/j.apcatb.2021.120549_bib0025 article-title: Oxidative dehydrogenation of cyclohexane over alumina-supported vanadium oxide nanoliths publication-title: J. Catal. doi: 10.1016/j.jcat.2009.11.026 – volume: 50 start-page: 255 issue: 4 year: 2003 ident: 10.1016/j.apcatb.2021.120549_bib0250 article-title: FTIR studies of tungsten carbide in bulk material and thin film samples publication-title: Mater. Charact. doi: 10.1016/S1044-5803(03)00100-1 – volume: 2 start-page: 400 issue: 2 year: 2012 ident: 10.1016/j.apcatb.2021.120549_bib0095 article-title: Visible light-induced partial oxidation of cyclohexane on WO3 loaded with Pt nanoparticles publication-title: Catal. Sci. Technol. doi: 10.1039/C1CY00331C – volume: 3 start-page: 467 issue: 6 year: 2011 ident: 10.1016/j.apcatb.2021.120549_bib0055 article-title: Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures publication-title: Nat. Chem. doi: 10.1038/nchem.1032 – volume: 84 start-page: 275 issue: 2 year: 1983 ident: 10.1016/j.apcatb.2021.120549_bib0120 article-title: Characterization of silica-supported molybdenum oxide and tungsten oxide. Reducibility of the oxidic state versus hydrodesulfurization activity of the sulfided state publication-title: J. Catal. doi: 10.1016/0021-9517(83)90001-5 – volume: 39 start-page: 899 issue: 5 year: 2018 ident: 10.1016/j.apcatb.2021.120549_bib0005 article-title: Recent advances on controllable and selective catalytic oxidation of cyclohexene publication-title: Chinese J. Catal. doi: 10.1016/S1872-2067(18)63050-5 – volume: 64 start-page: 1045 issue: 4 year: 1992 ident: 10.1016/j.apcatb.2021.120549_bib0155 article-title: Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients publication-title: Rev. Mod. Phys. doi: 10.1103/RevModPhys.64.1045 – volume: 117 start-page: 22584 issue: 44 year: 2013 ident: 10.1016/j.apcatb.2021.120549_bib0125 article-title: Effect of particle size on the photocatalytic activity of WO3 particles for water oxidation publication-title: J. Phys. Chem. C doi: 10.1021/jp408446u – volume: Vol. 155 start-page: 179 year: 2005 ident: 10.1016/j.apcatb.2021.120549_bib0100 article-title: Cyclohexane photocatalytic oxidative dehydrogenation to benzene on sulphated titania supported MoOx – volume: 39 start-page: 4145 issue: 9 year: 2013 ident: 10.1016/j.apcatb.2021.120549_bib0075 article-title: A green route for selective synthesis of styrene from ethylbenzene by means of a photocatalytic system publication-title: Res. Chem. Intermediate. doi: 10.1007/s11164-012-0931-0 – volume: 279 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0050 article-title: Anchoring Zn-phthalocyanines in the pore matrices of UiO-67 to improve highly the photocatalytic oxidation efficiency publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2020.119350 – volume: 8 start-page: 11398 issue: 12 year: 2018 ident: 10.1016/j.apcatb.2021.120549_bib0060 article-title: Photothermal catalysis over nonplasmonic Pt/TiO2 studied by operando HERFD-XANES, resonant XES, and DRIFTS publication-title: ACS Catal. doi: 10.1021/acscatal.8b03724 – volume: 112 start-page: 1552 issue: 5 year: 2008 ident: 10.1016/j.apcatb.2021.120549_bib0240 article-title: In situ ATR-FTIR study on the selective photo-oxidation of cyclohexane over anatase TiO2 publication-title: J. Phys. Chem. C doi: 10.1021/jp077143t – volume: 36 start-page: 14435 issue: 22 year: 2011 ident: 10.1016/j.apcatb.2021.120549_bib0195 article-title: Promotional effect of alkaline earth over Ni–La2O3 catalyst for CO2 reforming of CH4: role of surface oxygen species on H2 production and carbon suppression publication-title: Int. J. Hydrogen Energ. doi: 10.1016/j.ijhydene.2011.08.022 – volume: 281 year: 2021 ident: 10.1016/j.apcatb.2021.120549_bib0040 article-title: Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts: a critical review publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2020.119447 – volume: 28 start-page: 139 issue: 1 year: 1996 ident: 10.1016/j.apcatb.2021.120549_bib0110 article-title: Oxidative dehydrogenation of propane over niobia supported vanadium oxide catalysts publication-title: Catal. Today doi: 10.1016/0920-5861(95)00221-9 – volume: 136 start-page: B864 issue: 3B year: 1964 ident: 10.1016/j.apcatb.2021.120549_bib0145 article-title: Inhomogeneous Electron gas publication-title: Phys. Rev. doi: 10.1103/PhysRev.136.B864 – volume: 3 start-page: 978 issue: 4 year: 2013 ident: 10.1016/j.apcatb.2021.120549_bib0245 article-title: Investigation of the deactivation phenomena occurring in the cyclohexane photocatalytic oxidative dehydrogenation on MoOx/TiO2 through gas phase and in situ DRIFTS analyses publication-title: Catal – volume: 251 start-page: 17 year: 2019 ident: 10.1016/j.apcatb.2021.120549_bib0030 article-title: Selective oxidation of cyclohexane to cyclohexanol by BiOI under visible light: role of the ratio (1 1 0)/(0 0 1) facet publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2019.03.058 – volume: 6 start-page: 6511 issue: 10 year: 2016 ident: 10.1016/j.apcatb.2021.120549_bib0140 article-title: Removal of nitric oxide through visible light photocatalysis by g-C3N4 modified with perylene imides publication-title: ACS Catal. doi: 10.1021/acscatal.6b01657 – volume: 341 start-page: 13 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0065 article-title: Behaviour of Pt/TiO2 catalysts with different morphological and structural characteristics in the photocatalytic conversion of ethanol aqueous solutions publication-title: Catal. Today doi: 10.1016/j.cattod.2018.06.017 – volume: 131 start-page: 266 issue: 1 year: 2009 ident: 10.1016/j.apcatb.2021.120549_bib0015 article-title: Oxidative dehydrogenation of cyclohexane to cyclohexene over Mg-V-O catalysts publication-title: Catal. Lett. doi: 10.1007/s10562-009-0064-2 – volume: 141 start-page: 367 issue: 3 year: 2009 ident: 10.1016/j.apcatb.2021.120549_bib0105 article-title: Photocatalytic cyclohexane oxidehydrogenation on sulphated MoOx/γ-Al2O3 catalysts publication-title: Catal. Today doi: 10.1016/j.cattod.2008.10.020 – volume: 7 start-page: 293 issue: 1 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0230 article-title: Titanium Dioxide/Reduced graphene oxide hybrid photocatalysts for efficient and selective partial oxidation of cyclohexane publication-title: ACS Catal. doi: 10.1021/acscatal.6b02611 – volume: 54 start-page: 11169 issue: 16 year: 1996 ident: 10.1016/j.apcatb.2021.120549_bib0150 article-title: Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.54.11169 – volume: 59 start-page: 12909 issue: 31 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0115 article-title: Photo–thermo catalytic oxidation over a TiO2-WO3-Supported platinum catalyst publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202001701 – volume: 59 start-page: 7520 issue: 11 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0090 article-title: Hybridizing engineering strategy of decatungstate. 2. Regulated effect of doping transition metal ions on photocatalytic oxidation performance of (nBu4N)4W10O32 publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.0c00390 – volume: 59 start-page: 1758 issue: 3 year: 1999 ident: 10.1016/j.apcatb.2021.120549_bib0165 article-title: From ultrasoft pseudopotentials to the projector augmented-wave method publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.59.1758 – volume: 21 start-page: 2175 issue: 12 year: 2011 ident: 10.1016/j.apcatb.2021.120549_bib0185 article-title: Nanostructured tungsten oxide – properties, synthesis, and applications publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201002477 – volume: 116 start-page: 5067 issue: 8 year: 2012 ident: 10.1016/j.apcatb.2021.120549_bib0205 article-title: Enhanced oxidation reactivity of WO3(001) surface through the formation of oxygen radical centers publication-title: J. Phys. Chem. C doi: 10.1021/jp210171f – volume: 242 start-page: 249 year: 2019 ident: 10.1016/j.apcatb.2021.120549_bib0085 article-title: Influence of tetraalkylammonium cations on quality of decatungstate and its photocatalytic property in visible light-triggered selective oxidation of organic compounds by dioxygens publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2018.09.099 – volume: 44 start-page: 629 issue: 1 year: 2018 ident: 10.1016/j.apcatb.2021.120549_bib0080 article-title: Cyclohexane photooxidation under visible light irradiation by WO3–TiO2 mixed catalysts publication-title: Res. Chem. Intermediate. doi: 10.1007/s11164-017-3124-z – volume: 274 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0235 article-title: Highly stable phosphine modified VOx/Al2O3 catalyst in propane dehydrogenation publication-title: Appl. Catal. B: Environ. doi: 10.1016/j.apcatb.2020.119089 – volume: 27 issue: 47 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0225 article-title: In situ carbon homogeneous doping on ultrathin bismuth molybdate: a dual-purpose strategy for efficient molecular oxygen activation publication-title: Adv. Funct.Mater. doi: 10.1002/adfm.201703923 – volume: 53 start-page: 11478 issue: 43 year: 2014 ident: 10.1016/j.apcatb.2021.120549_bib0215 article-title: Photothermal conversion of CO2 into CH4 with H2 over group VIII nanocatalysts: an alternative approach for solar fuel production publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.201404953 – volume: 115 start-page: 8345 issue: 16 year: 2011 ident: 10.1016/j.apcatb.2021.120549_bib0170 article-title: Electronic and structural properties of WO3: a systematic hybrid DFT study publication-title: J. Phys. Chem. C doi: 10.1021/jp201057m – volume: 156-158 start-page: 172 year: 2007 ident: 10.1016/j.apcatb.2021.120549_bib0190 article-title: XPS studies of active elements surface of gas sensors based on WO3−x nanoparticles publication-title: J. Electron Spectrosc. doi: 10.1016/j.elspec.2006.12.059 – volume: 8 start-page: 4399 issue: 17 year: 2018 ident: 10.1016/j.apcatb.2021.120549_bib0210 article-title: Surface oxygen vacancy and defect engineering of WO3 for improved visible light photocatalytic performance publication-title: Catal. Sci. Technol. doi: 10.1039/C8CY00994E – volume: 845 year: 2020 ident: 10.1016/j.apcatb.2021.120549_bib0070 article-title: Novel Pd-loaded urchin-like (NH4)xWO3/WO3 as an efficient visible-light-driven photocatalyst for partial conversion of benzyl alcohol publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2020.156225 – volume: 147 start-page: 738 issue: 3 year: 2017 ident: 10.1016/j.apcatb.2021.120549_bib0020 article-title: Oxidative dehydrogenation of cyclohexane and Cyclohexene over Y-doped CeO2 nanorods publication-title: Catal. Lett. doi: 10.1007/s10562-017-1974-z |
| SSID | ssj0002328 |
| Score | 2.4833407 |
| Snippet | A mild photocatalytic process with the use of tungsten trioxide has been demonstrated as a promising strategy to boost oxidative dehydrogenation of C6H12.... Oxidative dehydrogenation of cyclohexane (C6H12) to cyclohexene (C6H10) suffers from low selectivity due to its over-dehydrogenation and oxidation to other... |
| SourceID | proquest crossref elsevier |
| SourceType | Aggregation Database Enrichment Source Index Database Publisher |
| StartPage | 120549 |
| SubjectTerms | Benzene Cyclohexane Cyclohexanol Cyclohexene Dehydrogenation Hydrogen bonds Oxidation Oxidative dehydrogenation Oxygen Oxygen-deficient tungsten trioxide Photocatalysis Photocatalytic process Selective conversion of cyclohexane Selectivity Tungsten Tungsten oxides |
| Title | Photocatalytic oxidative dehydrogenation of cyclohexane to cyclohexene over oxygen-deficient tungsten trioxide |
| URI | https://dx.doi.org/10.1016/j.apcatb.2021.120549 https://www.proquest.com/docview/2582222237 |
| Volume | 298 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1La9wwEBYhPbQ9lGbb0LRp0KFXZb2SZcnHsCRsExIKbSA3I0sjdkuwl40D3Ut_e2dkO2kLJdCLQfaMbDSjb8b2PBj7JCGGDIogAJQUuY1W1NFFURoqRFtLDTVlI19eFYvr_PxG3-yw-ZgLQ2GVA_b3mJ7QejgzHVZzul6tpl-zUhZKGUpCIbeXEs3z3JCWH_98DPNAjyGhMRILoh7T51KMl1t719X4lihnxzOJ3kv5L_P0F1An63P2mr0a3EZ-0j_ZHtuBZsKez8dubRP28rfCghO2f_qYv4Zswwa-e8OaL8u2a9M3my1Oxdsfq5BKf_MAy23YtKhPSVa8jdxv_W27pAQY4F37MER05BT4icxbJBcBqAoF3ol3iByoNQ3vNiuaGd6y67PTb_OFGFouCI-buRPSIt4pp_TMI5QFQ7_hPKgAMvqgs9o6CapQ3ppoModXNRpZbagIGMRogtpnu03bwDvGMxOCdTlkscCjnbk6lBbAlc7rELQ9YGpc6coP9cipLcZtNQaefa96-VQkn6qXzwETD1zrvh7HE_RmFGL1h15VaDKe4DwcZV4N-_qukpocKnSpzPv_nvgDe0GjFBOjD9lut7mHj-jZdPVRUt0j9uzk88Xi6heBRfzs |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9QwEB6VcigcECxUFAr4AEd3s_Y6zh44oNJqSx9CopV6M4491i6qktVuqpILf4o_yDiPFpBQJaReIiX2OJZn_M04mQfAW4HBJ5h6jigFH2ch43mwgU90TESbC4V5jEY-PkmnZ-NP5-p8DX72sTDRrbLD_hbTG7Tungy71Rwu5vPhl2QiUil1DEKJZm_vWXmI9RWd21bvDz4Sk98Jsb93ujvlXWkB7khoKy4y2tfSSjVytGW9jr-bHEqPIjivkjyzAmUqXaaDTiy1KlImSsdkVxiC9pLGvQf3xwQXsWzCzo8bvxIyURr4p9nxOL0-Xq9xKrMLZ6ucjqVitDMSZC5N_qUP_9IMjbrbfwyPOjuVfWiX4gmsYTGAjd2-PNwAHv6WyXAAm3s3AXNE1iHG6ikUn2dlVTYfiWoaipXf577JNc48zmq_LEmAG-FgZWCudhflLEbcIKvK61uCYxY9TYm4pu7cY0x7QW9iFUEViWnBquU8jozP4OxOGLEJ60VZ4HNgifY-s2NMQkrXbGRzP8kQ7cQ65b3KtkD2K21clwA91uG4ML2n2zfT8sdE_piWP1vAr6kWbQKQW_rrnonmD0E2pKNuodzueW46IFkZoaIFRzacfvHfA7-Bjenp8ZE5Ojg5fAkPYkvjkKO2Yb1aXuIrMquq_HUjxgy-3vW--QVPDTkT |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Photocatalytic+oxidative+dehydrogenation+of+cyclohexane+to+cyclohexene+over+oxygen-deficient+tungsten+trioxide&rft.jtitle=Applied+catalysis.+B%2C+Environmental&rft.au=Quan%2C+Fengjiao&rft.au=Zhan%2C+Guangming&rft.au=Liu%2C+Xiufan&rft.au=Zhou%2C+Bing&rft.date=2021-12-05&rft.issn=0926-3373&rft.volume=298&rft.spage=120549&rft_id=info:doi/10.1016%2Fj.apcatb.2021.120549&rft.externalDBID=n%2Fa&rft.externalDocID=10_1016_j_apcatb_2021_120549 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0926-3373&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0926-3373&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0926-3373&client=summon |