Kinetics of homogeneous 5‐hydroxymethylfurfural oxidation to 2,5‐furandicarboxylic acid with Co/Mn/Br catalyst
2,5‐furandicarboxylic acid (FDCA) is a potential non‐phthalate based bio‐renewable substitute for terephthalic acid‐based plastics. Herein, we present an investigation of the oxidation rate of 5‐hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentratio...
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| Published in | AIChE journal Vol. 63; no. 1; pp. 162 - 171 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
New York
American Institute of Chemical Engineers
01.01.2017
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| Subjects | |
| Online Access | Get full text |
| ISSN | 0001-1541 1547-5905 |
| DOI | 10.1002/aic.15497 |
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| Abstract | 2,5‐furandicarboxylic acid (FDCA) is a potential non‐phthalate based bio‐renewable substitute for terephthalic acid‐based plastics. Herein, we present an investigation of the oxidation rate of 5‐hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentration profiles of the reactant (HMF), intermediates [2,5‐diformylfuran (DFF), 5‐formyl‐2‐furancarboxylic acid (FFCA)], and the desired product (FDCA) were obtained for this relatively fast reaction in a stirred semi‐batch reactor using rapid in‐line sampling. Comparison of the effective rate constants for the series oxidation steps with predicted gas–liquid mass transfer coefficients reveals that except for the FFCA → FDCA step, the first two oxidation steps are subject to gas–liquid mass transfer limitations even at high stirrer speeds. Novel reactor configurations, such as a reactor in which the reaction mixture is dispersed as fine droplets into a gas phase containing oxygen, are required to overcome oxygen starvation in the liquid phase and further intensify FDCA production. © 2016 American Institute of Chemical Engineers AIChE J, 63: 162–171, 2017 |
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| AbstractList | 2,5‐furandicarboxylic acid (FDCA) is a potential non‐phthalate based bio‐renewable substitute for terephthalic acid‐based plastics. Herein, we present an investigation of the oxidation rate of 5‐hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentration profiles of the reactant (HMF), intermediates [2,5‐diformylfuran (DFF), 5‐formyl‐2‐furancarboxylic acid (FFCA)], and the desired product (FDCA) were obtained for this relatively fast reaction in a stirred semi‐batch reactor using rapid in‐line sampling. Comparison of the effective rate constants for the series oxidation steps with predicted gas–liquid mass transfer coefficients reveals that except for the FFCA → FDCA step, the first two oxidation steps are subject to gas–liquid mass transfer limitations even at high stirrer speeds. Novel reactor configurations, such as a reactor in which the reaction mixture is dispersed as fine droplets into a gas phase containing oxygen, are required to overcome oxygen starvation in the liquid phase and further intensify FDCA production. © 2016 American Institute of Chemical Engineers
AIChE J
, 63: 162–171, 2017 2,5-furandicarboxylic acid (FDCA) is a potential non-phthalate based bio-renewable substitute for terephthalic acid-based plastics. Herein, we present an investigation of the oxidation rate of 5-hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentration profiles of the reactant (HMF), intermediates [2,5-diformylfuran (DFF), 5-formyl-2-furancarboxylic acid (FFCA)], and the desired product (FDCA) were obtained for this relatively fast reaction in a stirred semi-batch reactor using rapid in-line sampling. Comparison of the effective rate constants for the series oxidation steps with predicted gas-liquid mass transfer coefficients reveals that except for the FFCA [arrow right] FDCA step, the first two oxidation steps are subject to gas-liquid mass transfer limitations even at high stirrer speeds. Novel reactor configurations, such as a reactor in which the reaction mixture is dispersed as fine droplets into a gas phase containing oxygen, are required to overcome oxygen starvation in the liquid phase and further intensify FDCA production. © 2016 American Institute of Chemical Engineers AIChE J, 63: 162-171, 2017 2,5-furandicarboxylic acid (FDCA) is a potential non-phthalate based bio-renewable substitute for terephthalic acid-based plastics. Herein, we present an investigation of the oxidation rate of 5-hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentration profiles of the reactant (HMF), intermediates [2,5-diformylfuran (DFF), 5-formyl-2-furancarboxylic acid (FFCA)], and the desired product (FDCA) were obtained for this relatively fast reaction in a stirred semi-batch reactor using rapid in-line sampling. Comparison of the effective rate constants for the series oxidation steps with predicted gas-liquid mass transfer coefficients reveals that except for the FFCA arrow right FDCA step, the first two oxidation steps are subject to gas-liquid mass transfer limitations even at high stirrer speeds. Novel reactor configurations, such as a reactor in which the reaction mixture is dispersed as fine droplets into a gas phase containing oxygen, are required to overcome oxygen starvation in the liquid phase and further intensify FDCA production. copyright 2016 American Institute of Chemical Engineers AIChE J, 63: 162-171, 2017 2,5‐furandicarboxylic acid (FDCA) is a potential non‐phthalate based bio‐renewable substitute for terephthalic acid‐based plastics. Herein, we present an investigation of the oxidation rate of 5‐hydroxymethylfurfural (HMF) to FDCA in acetic acid medium using Co/Mn/Br catalyst. Transient concentration profiles of the reactant (HMF), intermediates [2,5‐diformylfuran (DFF), 5‐formyl‐2‐furancarboxylic acid (FFCA)], and the desired product (FDCA) were obtained for this relatively fast reaction in a stirred semi‐batch reactor using rapid in‐line sampling. Comparison of the effective rate constants for the series oxidation steps with predicted gas–liquid mass transfer coefficients reveals that except for the FFCA → FDCA step, the first two oxidation steps are subject to gas–liquid mass transfer limitations even at high stirrer speeds. Novel reactor configurations, such as a reactor in which the reaction mixture is dispersed as fine droplets into a gas phase containing oxygen, are required to overcome oxygen starvation in the liquid phase and further intensify FDCA production. © 2016 American Institute of Chemical Engineers AIChE J, 63: 162–171, 2017 |
| Author | Snavely, Kirk Zhu, Hongda Subramaniam, Bala Niu, Fenghui Zuo, Xiaobin Martin, Kevin J. Chaudhari, Amit S. |
| Author_xml | – sequence: 1 givenname: Xiaobin surname: Zuo fullname: Zuo, Xiaobin organization: Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence – sequence: 2 givenname: Amit S. surname: Chaudhari fullname: Chaudhari, Amit S. organization: Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence – sequence: 3 givenname: Kirk surname: Snavely fullname: Snavely, Kirk organization: Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence – sequence: 4 givenname: Fenghui surname: Niu fullname: Niu, Fenghui organization: Center for Environmentally Beneficial Catalysis, University of Kansas, Lawrence – sequence: 5 givenname: Hongda surname: Zhu fullname: Zhu, Hongda organization: University of Kansas, Lawrence – sequence: 6 givenname: Kevin J. surname: Martin fullname: Martin, Kevin J. organization: Archer Daniels Midland (ADM) Company – sequence: 7 givenname: Bala surname: Subramaniam fullname: Subramaniam, Bala email: bsubramaniam@ku.edu organization: University of Kansas, Lawrence |
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| Snippet | 2,5‐furandicarboxylic acid (FDCA) is a potential non‐phthalate based bio‐renewable substitute for terephthalic acid‐based plastics. Herein, we present an... 2,5-furandicarboxylic acid (FDCA) is a potential non-phthalate based bio-renewable substitute for terephthalic acid-based plastics. Herein, we present an... |
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| SubjectTerms | 2,5‐furandicarboxylic acid 5‐hydroxymethylfurfural Acetic acid Batch reactors Catalysts Chemical engineering Chemical engineers Co/Mn/Br catalyst Droplets Kinetics Mass transfer Oxidation Oxygen Reactors Sampling semi‐batch reactor model |
| Title | Kinetics of homogeneous 5‐hydroxymethylfurfural oxidation to 2,5‐furandicarboxylic acid with Co/Mn/Br catalyst |
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