Mechanical and Physical Changes in Bio-Polybutylene-Succinate Induced by UVC Ray Photodegradation
Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical–mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have...
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| Published in | Polymers Vol. 16; no. 9; p. 1288 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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| Abstract | Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical–mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have already evaluated the resistance of PBS to photodegradation caused by natural outdoor solar exposure (UVA-UVB), a systematic study on the resistance to degradation caused by exposure to UVC rays, which is the subject of this study, has not yet been carried out. PBS was exposed to UVC either neat or filled with 2% carbon black (CB). Mechanical and physical characterization (tensile, hardness, calorimetry, contact angle, morphology, and surface roughness analyses) indicates that the bulk and surface properties of the polymer matrix changes after exposure to UVC radiations, due to a severe degradation. However, the presence of carbon black compensates for the degradation phenomenon. Because UVC rays are used for the sterilization process, necessary in applications such as biomedical, cosmetic, pharmaceutical, food, and other products, a comparison of the protocol used in this paper with the literature’s data has been reported and discussed. |
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| AbstractList | Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical–mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have already evaluated the resistance of PBS to photodegradation caused by natural outdoor solar exposure (UVA-UVB), a systematic study on the resistance to degradation caused by exposure to UVC rays, which is the subject of this study, has not yet been carried out. PBS was exposed to UVC either neat or filled with 2% carbon black (CB). Mechanical and physical characterization (tensile, hardness, calorimetry, contact angle, morphology, and surface roughness analyses) indicates that the bulk and surface properties of the polymer matrix changes after exposure to UVC radiations, due to a severe degradation. However, the presence of carbon black compensates for the degradation phenomenon. Because UVC rays are used for the sterilization process, necessary in applications such as biomedical, cosmetic, pharmaceutical, food, and other products, a comparison of the protocol used in this paper with the literature’s data has been reported and discussed. Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical-mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have already evaluated the resistance of PBS to photodegradation caused by natural outdoor solar exposure (UVA-UVB), a systematic study on the resistance to degradation caused by exposure to UVC rays, which is the subject of this study, has not yet been carried out. PBS was exposed to UVC either neat or filled with 2% carbon black (CB). Mechanical and physical characterization (tensile, hardness, calorimetry, contact angle, morphology, and surface roughness analyses) indicates that the bulk and surface properties of the polymer matrix changes after exposure to UVC radiations, due to a severe degradation. However, the presence of carbon black compensates for the degradation phenomenon. Because UVC rays are used for the sterilization process, necessary in applications such as biomedical, cosmetic, pharmaceutical, food, and other products, a comparison of the protocol used in this paper with the literature's data has been reported and discussed.Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical-mechanical properties like traditional low-density polyethylene (LDPE). PBS is employed by many manufacturing sectors, from biomedical to agri-food and cosmetics. Although some studies have already evaluated the resistance of PBS to photodegradation caused by natural outdoor solar exposure (UVA-UVB), a systematic study on the resistance to degradation caused by exposure to UVC rays, which is the subject of this study, has not yet been carried out. PBS was exposed to UVC either neat or filled with 2% carbon black (CB). Mechanical and physical characterization (tensile, hardness, calorimetry, contact angle, morphology, and surface roughness analyses) indicates that the bulk and surface properties of the polymer matrix changes after exposure to UVC radiations, due to a severe degradation. However, the presence of carbon black compensates for the degradation phenomenon. Because UVC rays are used for the sterilization process, necessary in applications such as biomedical, cosmetic, pharmaceutical, food, and other products, a comparison of the protocol used in this paper with the literature's data has been reported and discussed. |
| Audience | Academic |
| Author | Brahimi, Salim Scolaro, Cristina Visco, Annamaria Beghetto, Valentina Falcone, Aurora |
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| Cites_doi | 10.1038/s41578-021-00407-8 10.1007/s41742-023-00507-z 10.1002/masy.202100330 10.1016/j.eurpolymj.2021.110855 10.1016/j.polymdegradstab.2012.05.024 10.3390/polym15143000 10.1016/j.watres.2020.116360 10.3390/polym14132752 10.3390/polym14040844 10.3390/polym12040978 10.1016/j.scitotenv.2018.02.079 10.1016/j.eurpolymj.2016.01.016 10.1016/j.polymdegradstab.2023.110490 10.1134/S0965545X17030051 10.1016/j.apsusc.2022.153058 10.1016/j.progpolymsci.2022.101579 10.1016/j.envpol.2023.122102 10.3389/fbioe.2022.875817 10.3390/polym15214322 10.1007/978-3-642-01999-9 10.1016/j.polymertesting.2024.108327 10.1016/j.jaap.2021.105207 10.1155/2019/3487529 10.1016/j.polymdegradstab.2003.12.005 10.1016/S0141-3910(01)00252-X 10.1002/app.52313 10.3390/polym13091436 10.1016/j.matpr.2020.06.096 10.3390/polym13244467 10.1155/2019/5036019 10.1088/1757-899X/788/1/012054 10.3390/polym15081966 10.1016/j.polymdegradstab.2016.08.004 10.1063/1.117916 10.1080/08927010802716623 10.3144/expresspolymlett.2023.2 10.1038/369064a0 10.1016/j.polymdegradstab.2008.10.013 10.1016/j.crgsc.2022.100273 10.1016/j.polymdegradstab.2021.109605 10.1016/j.polymertesting.2018.02.003 10.3390/cryst11121530 10.1038/s41598-020-79600-8 10.3390/polym13081229 |
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| Snippet | Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical–mechanical properties like traditional... Bio-polybutylene succinate (PBS) is a biodegradable polymer obtained from renewable feedstock having physical-mechanical properties like traditional... |
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| SubjectTerms | Analysis Biodegradation Bioplastics Carbon Carbon black Contact angle Cosmetics Exposure Food Humidity Low density polyethylenes Manufacturing Mechanical properties Nanoparticles Photodegradation Polybutylene Polybutylenes Polyethylene Polymers Polymers in medicine Sterilization Succinic acid Surface properties Surface roughness Ultraviolet radiation |
| Title | Mechanical and Physical Changes in Bio-Polybutylene-Succinate Induced by UVC Ray Photodegradation |
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